Modeling of secondary organic aerosol yields from laboratory chamber data

Laboratory chamber data serve as the basis for constraining models of secondary organic aerosol (SOA) formation. Current models fall into three categories: empirical two-product (Odum), product-specific, and volatility basis set. The product-specific and volatility basis set models are applied here to represent laboratory data on the ozonolysis of α-pinene under dry, dark, and low-NOx conditions in the presence of ammonium sulfate seed aerosol. Using five major identified products, the model is fit to the chamber data. From the optimal fitting, SOA oxygen-to-carbon (O/C) and hydrogen-to-carbon (H/C) ratios are modeled. The discrepancy between measured H/C ratios and those based on the oxidation products used in the model fitting suggests the potential importance of particle-phase reactions. Data fitting is also carried out using the volatility basis set, wherein oxidation products are parsed into volatility bins. The product-specific model is most likely hindered by lack of explicit inclusion of particle-phase accretion compounds. While prospects for identification of the majority of SOA products for major volatile organic compounds (VOCs) classes remain promising, for the near future empirical product or volatility basis set models remain the approaches of choice

Archetypal analysis of galaxy spectra

Archetypal analysis represents each individual member of a set of data vectors as a mixture (a constrained linear combination) of the pure types or archetypes of the data set. The archetypes are themselves required to be mixtures of the data vectors. Archetypal analysis may be particularly useful in analysing data sets comprising galaxy spectra, since each spectrum is, presumably, a superposition of the emission from the various stellar populations, nebular emissions and nuclear activity making up that galaxy, and each of these emission sources corresponds to a potential archetype of the entire data set. We demonstrate archetypal analysis using sets of composite synthetic galaxy spectra, showing that the method promises to be an effective and efficient way to classify spectra. We show that archetypal analysis is robust in the presence of various types of noise.Comment: 6 pages, 5 figures, 1 style-file. Accepted for publication by MNRA

Phase transition in the Higgs model of scalar dyons

In the present paper we investigate the phase transition "Coulomb--confinement" in the Higgs model of abelian scalar dyons -- particles having both, electric $e$ and magnetic $g$, charges. It is shown that by dual symmetry this theory is equivalent to scalar fields with the effective squared electric charge e^{*2}=e^2+g^2. But the Dirac relation distinguishes the electric and magnetic charges of dyons. The following phase transition couplings are obtained in the one--loop approximation: \alpha_{crit}=e^2_{crit}/4\pi\approx 0.19, \tilde\alpha_{crit}=g^2_{crit}/4\pi\approx 1.29 and \alpha^*_{crit}\approx 1.48.Comment: 16 pages, 2 figure

Multi-market minority game: breaking the symmetry of choice

Generalization of the minority game to more than one market is considered. At each time step every agent chooses one of its strategies and acts on the market related to this strategy. If the payoff function allows for strong fluctuation of utility then market occupancies become inhomogeneous with preference given to this market where the fluctuation occured first. There exists a critical size of agent population above which agents on bigger market behave collectively. In this regime there always exists a history of decisions for which all agents on a bigger market react identically.Comment: 15 pages, 12 figures, Accepted to 'Advances in Complex Systems

Measurement of mesoscopic High-TcT_c superconductors using Si mechanical micro-oscillators

In a superconducting mesoscopic sample, with dimensions comparable to the London penetration depth, some properties are qualitatively different to those found in the bulk material. These properties include magnetization, vortex dynamics and ordering of the vortex lattice. In order to detect the small signals produced by this kind of samples, new instruments designed for the microscale are needed. In this work we use micromechanical oscillators to study the magnetic properties of a Bi$_2$Sr$_2$CaCu$_2$O$_{8 + \delta}$ disk with a diameter of 13.5 microns and a thickness of 2.5 microns. The discussion of our results is based on the existence and contribution of inter and intra layer currents.Comment: 4 pages, 6 figure

Energetic Components of Cooperative Protein Folding

A new lattice protein model with a four-helix bundle ground state is analyzed by a parameter-space Monte Carlo histogram technique to evaluate the effects of an extensive variety of model potentials on folding thermodynamics. Cooperative helical formation and contact energies based on a 5-letter alphabet are found to be insufficient to satisfy calorimetric and other experimental criteria for two-state folding. Such proteinlike behaviors are predicted, however, by models with polypeptide-like local conformational restrictions and environment-dependent hydrogen bonding-like interactions.Comment: 11 pages, 4 postscripts figures, Phys. Rev. Lett. (in press

Supercritical multicomponent solvent coal extraction

The yield of organic extract from the supercritical extraction of coal with larger diameter organic solvents such as toluene is increased by use of a minor amount of from 0.1 to 10% by weight of a second solvent such as methanol having a molecular diameter significantly smaller than the average pore diameter of the coal

Topological Bose-Mott Insulators in a One-Dimensional Optical Superlattice

We study topological properties of the Bose-Hubbard model with repulsive interactions in a one-dimensional optical superlattice. We find that the Mott insulator states of the single-component (two-component) Bose-Hubbard model under fractional fillings are topological insulators characterized by a nonzero charge (or spin) Chern number with nontrivial edge states. For ultracold atomic experiments, we show that the topological Chern number can be detected through measuring the density profiles of the bosonic atoms in a harmonic trap.Comment: 5 pages, published versio

Role of aldehyde chemistry and NO_x concentrations in secondary organic aerosol formation

Aldehydes are an important class of products from atmospheric oxidation of hydrocarbons. Isoprene (2-methyl-1,3-butadiene), the most abundantly emitted atmospheric non-methane hydrocarbon, produces a significant amount of secondary organic aerosol (SOA) via methacrolein (a C_4-unsaturated aldehyde) under urban high-NO_x conditions. Previously, we have identified peroxy methacryloyl nitrate (MPAN) as the important intermediate to isoprene and methacrolein SOA in this NO_x regime. Here we show that as a result of this chemistry, NO_2 enhances SOA formation from methacrolein and two other α, β-unsaturated aldehydes, specifically acrolein and crotonaldehyde, a NO_x effect on SOA formation previously unrecognized. Oligoesters of dihydroxycarboxylic acids and hydroxynitrooxycarboxylic acids are observed to increase with increasing NO_2/NO ratio, and previous characterizations are confirmed by both online and offline high-resolution mass spectrometry techniques. Molecular structure also determines the amount of SOA formation, as the SOA mass yields are the highest for aldehydes that are α, β-unsaturated and contain an additional methyl group on the α-carbon. Aerosol formation from 2-methyl-3-buten-2-ol (MBO232) is insignificant, even under high-NO_2 conditions, as PAN (peroxy acyl nitrate, RC(O)OONO_2) formation is structurally unfavorable. At atmospherically relevant NO_2/NO ratios (3–8), the SOA yields from isoprene high-NO_x photooxidation are 3 times greater than previously measured at lower NO_2/NO ratios. At sufficiently high NO_2 concentrations, in systems of α, β-unsaturated aldehydes, SOA formation from subsequent oxidation of products from acyl peroxyl radicals+NO_2 can exceed that from RO_2+HO_2 reactions under the same inorganic seed conditions, making RO_2+NO_2 an important channel for SOA formation

The Dynamics of Charges Induced by a Charged Particle Traversing a Dielectric Slab

We studied the dynamics of surfacea and wake charges induced by a charged particle traversing a dielectric slab. It is shown that after the crossing of the slab first boundary, the induced on the slab surface charge (image charge) is transformed into the wake charge, which overflows to the second boundary when the particle crosses it. It is also shown, that the polarization of the slab is of an oscillatory nature, and the net induced charge in a slab remains zero at all stages of the motion.Comment: 12 pages, 1 figur