Two-photon diffraction and quantum lithography

We report a proof-of-principle experimental demonstration of quantum lithography. Utilizing the entangled nature of a two-photon state, the experimental results have bettered the classical diffraction limit by a factor of two. This is a quantum mechanical two-photon phenomenon but not a violation of the uncertainty principle.Comment: 5 pages, 5 figures Submitted to Physical Review Letter

On Preparing Entangled Pairs of Polarization Qubits in the Frequency Non-Degenerate Regime

The problems associated with practical implementation of the scheme proposed for preparation of arbitrary states of polarization ququarts based on biphotons are discussed. The influence of frequency dispersion effects are considered, and the necessity of group velocities dispersion compensation in the frequency non-degenerate case even for continuous pumping is demonstrated. A method for this compensation is proposed and implemented experimentally. Physical restrictions on the quality of prepared two-photon states are revealed.Comment: 9 pages, 6 figure

Pattern formation and localization in the forced-damped FPU lattice

We study spatial pattern formation and energy localization in the dynamics of an anharmonic chain with quadratic and quartic intersite potential subject to an optical, sinusoidally oscillating field and a weak damping. The zone-boundary mode is stable and locked to the driving field below a critical forcing that we determine analytically using an approximate model which describes mode interactions. Above such a forcing, a standing modulated wave forms for driving frequencies below the band-edge, while a ``multibreather'' state develops at higher frequencies. Of the former, we give an explicit approximate analytical expression which compares well with numerical data. At higher forcing space-time chaotic patterns are observed.Comment: submitted to Phys.Rev.

Two-Photon Interferometry for High-Resolution Imaging

We discuss advantages of using non-classical states of light for two aspects of optical imaging: creating of miniature images on photosensitive substrates, which constitutes the foundation for optical lithography, and imaging of micro objects. In both cases, the classical resolution limit given by the Rayleigh criterion is approximately a half of the optical wavelength. It has been shown, however, that by using multi-photon quantum states of the light field, and multi-photon sensitive material or detector, this limit can be surpassed. We give a rigorous quantum mechanical treatment of this problem, address some particularly widespread misconceptions and discuss the requirements for turning the research on quantum imaging into a practical technology.Comment: Presented at PQE 2001. To appear in Special Issue of Journal of Modern Optic

Interferometric Bell-state preparation using femtosecond-pulse-pumped Spontaneous Parametric Down-Conversion

We present theoretical and experimental study of preparing maximally entangled two-photon polarization states, or Bell states, using femtosecond pulse pumped spontaneous parametric down-conversion (SPDC). First, we show how the inherent distinguishability in femtosecond pulse pumped type-II SPDC can be removed by using an interferometric technique without spectral and amplitude post-selection. We then analyze the recently introduced Bell state preparation scheme using type-I SPDC. Theoretically, both methods offer the same results, however, type-I SPDC provides experimentally superior methods of preparing Bell states in femtosecond pulse pumped SPDC. Such a pulsed source of highly entangled photon pairs is useful in quantum communications, quantum cryptography, quantum teleportation, etc.Comment: 11 pages, two-column format, to appear in PR

Structure and time-dependence of quantum breathers

Quantum states of a discrete breather are studied in two ways. One method involves numerical diagonalization of the Hamiltonian, the other uses the path integral to examine correlations in the eigenstates. In both cases only the central nonlinearity is retained. To reduce truncation effects in the numerical diagonalization, a basis is used that involves a quadratic local mode. A similar device is used in the path integral method for deducing localization. Both approaches lead to the conclusion that aside from quantum tunneling the quantized discrete breather is stable.Comment: 33 pages, 20 figures, to appear in J. Chem. Phy

Entanglement, local measurements, and symmetry

A definition of entanglement in terms of local measurements is discussed. Viz, the maximum entanglement corresponds to the states that cause the highest level of quantum fluctuations in all local measurements determined by the dynamic symmetry group of the system. A number of examples illustrating this definition is considered.Comment: 10 pages. to be published in Journal of Optics

The reductive activation of CO2 across a Ti═Ti double bond: synthetic, structural, and mechanistic studies

[Image: see text] The reactivity of the bis(pentalene)dititanium double-sandwich compound Ti(2)Pn(†)(2) (1) (Pn(†) = 1,4-{Si(i)Pr(3)}(2)C(8)H(4)) with CO(2) is investigated in detail using spectroscopic, X-ray crystallographic, and computational studies. When the CO(2) reaction is performed at −78 °C, the 1:1 adduct 4 is formed, and low-temperature spectroscopic measurements are consistent with a CO(2) molecule bound symmetrically to the two Ti centers in a μ:η(2),η(2) binding mode, a structure also indicated by theory. Upon warming to room temperature the coordinated CO(2) is quantitatively reduced over a period of minutes to give the bis(oxo)-bridged dimer 2 and the dicarbonyl complex 3. In situ NMR studies indicated that this decomposition proceeds in a stepwise process via monooxo (5) and monocarbonyl (7) double-sandwich complexes, which have been independently synthesized and structurally characterized. 5 is thermally unstable with respect to a μ-O dimer in which the Ti–Ti bond has been cleaved and one pentalene ligand binds in an η(8) fashion to each of the formally Ti(III) centers. The molecular structure of 7 shows a “side-on” bound carbonyl ligand. Bonding of the double-sandwich species Ti(2)Pn(2) (Pn = C(8)H(6)) to other fragments has been investigated by density functional theory calculations and fragment analysis, providing insight into the CO(2) reaction pathway consistent with the experimentally observed intermediates. A key step in the proposed mechanism is disproportionation of a mono(oxo) di-Ti(III) species to yield di-Ti(II) and di-Ti(IV) products. 1 forms a structurally characterized, thermally stable CS(2) adduct 8 that shows symmetrical binding to the Ti(2) unit and supports the formulation of 4. The reaction of 1 with COS forms a thermally unstable complex 9 that undergoes scission to give mono(μ-S) mono(CO) species 10. Ph(3)PS is an effective sulfur transfer agent for 1, enabling the synthesis of mono(μ-S) complex 11 with a double-sandwich structure and bis(μ-S) dimer 12 in which the Ti–Ti bond has been cleaved

A Mach-Zehnder Interferometer for a Two-Photon Wave Packet

We propose an experiment that permits observation of the de Broglie two-photon wave packet behavior for a pair of photons, using a Mach-Zehnder interferometer. It is based on the use of pulsed lasers to generate pairs of photons via spontaneous parametric down-conversion and the post-selection of events. It differs from previous realizations by the use of a third time-correlated photon to engineer the state of the photons. The same technique can give us which-path information via an ``interaction-free'' experiment and can be used in other experiments on the foundations of quantum mechanics related to wave-particle duality and to nonlocality.Comment: Submmited for publication in Physical Review

Entangled-Photon Generation from Parametric Down-Conversion in Media with Inhomogeneous Nonlinearity

We develop and experimentally verify a theory of Type-II spontaneous parametric down-conversion (SPDC) in media with inhomogeneous distributions of second-order nonlinearity. As a special case, we explore interference effects from SPDC generated in a cascade of two bulk crystals separated by an air gap. The polarization quantum-interference pattern is found to vary strongly with the spacing between the two crystals. This is found to be a cooperative effect due to two mechanisms: the chromatic dispersion of the medium separating the crystals and spatiotemporal effects which arise from the inclusion of transverse wave vectors. These effects provide two concomitant avenues for controlling the quantum state generated in SPDC. We expect these results to be of interest for the development of quantum technologies and the generation of SPDC in periodically varying nonlinear materials.Comment: submitted to Physical Review