Black Hole Entropy as Causal Links

We model a black hole spacetime as a causal set and count, with a certain definition, the number of causal links crossing the horizon in proximity to a spacelike or null hypersurface $\Sigma$. We find that this number is proportional to the horizon's area on $\Sigma$, thus supporting the interpretation of the links as the ``horizon atoms'' that account for its entropy. The cases studied include not only equilibrium black holes but ones far from equilibrium.Comment: Latex, 20 pages, 4 postscript figures, to appear in a special issue of {\it Foundations of Physics} in honor of Jacob Bekenstein, ``Thirty years of black hole physics'', edited by L. Horwit

The Generalized Spectral Kurtosis Estimator

Due to its conceptual simplicity and its proven effectiveness in real-time detection and removal of radio frequency interference (RFI) from radio astronomy data, the Spectral Kurtosis (SK) estimator is likely to become a standard tool of a new generation of radio telescopes. However, the SK estimator in its original form must be developed from instantaneous power spectral density (PSD) estimates, and hence cannot be employed as an RFI excision tool downstream of the data pipeline in existing instruments where any time averaging is performed. In this letter, we develop a generalized estimator with wider applicability for both instantaneous and averaged spectral data, which extends its practical use to a much larger pool of radio instruments.Comment: 5 pages, 2 figures, MNRAS Letters accepte

Lead halide perovskite nanowires stabilized by block copolymers for Langmuir-Blodgett assembly

The rapid development of solar cells based on lead halide perovskites (LHPs) has prompted very active research activities in other closely-related fields. Colloidal nanostructures of such materials display superior optoelectronic properties. Especially, one-dimensional (1D) LHPs nanowires show anisotropic optical properties when they are highly oriented. However, the ionic nature makes them very sensitive to external environment, limiting their large scale practical applications. Here, we introduce an amphiphilic block copolymer, polystyrene-block-poly(4-vinylpyridine) (PS-P4VP), to chemically modify the surface of colloidal CsPbBr3 nanowires. The resulting core-shell nanowires show enhanced photoluminescent emission and good colloidal stability against water. Taking advantage of the stability enhancement, we further applied a modified Langmuir-Blodgett technique to assemble monolayers of highly aligned nanowires, and studied their anisotropic optical properties. [Figure not available: see fulltext.]

Nature of band-gap states in V-doped TiO2 revealed by resonant photoemission

Band-gap states in V-doped TiO2 have been studied by photoemission spectroscopy over a range of photon energies encompassing the Ti 3p and V 3p core thresholds. The states show resonant enhancement at photon energies significantly higher than found for Ti 3d states introduced into TiO2 by oxygen deficiency or alkalimetal adsorbates. This demonstrates that the gap states relate to electrons trapped on dopant V cations rather than host Ti cations

Importance of electronic self-consistency in the TDDFT based treatment of nonadiabatic molecular dynamics

A mixed quantum-classical approach to simulate the coupled dynamics of electrons and nuclei in nanoscale molecular systems is presented. The method relies on a second order expansion of the Lagrangian in time-dependent density functional theory (TDDFT) around a suitable reference density. We show that the inclusion of the second order term renders the method a self-consistent scheme and improves the calculated optical spectra of molecules by a proper treatment of the coupled response. In the application to ion-fullerene collisions, the inclusion of self-consistency is found to be crucial for a correct description of the charge transfer between projectile and target. For a model of the photoreceptor in retinal proteins, nonadiabatic molecular dynamics simulations are performed and reveal problems of TDDFT in the prediction of intra-molecular charge transfer excitations.Comment: 9 pages, 8 figures. Minor changes in content wrt older versio