Cluster approximation solution of a two species annihilation model

A two species reaction-diffusion model, in which particles diffuse on a one-dimensional lattice and annihilate when meeting each other, has been investigated. Mean field equations for general choice of reaction rates have been solved exactly. Cluster mean field approximation of the model is also studied. It is shown that, the general form of large time behavior of one- and two-point functions of the number operators, are determined by the diffusion rates of the two type of species, and is independent of annihilation rates.Comment: 9 pages, 7 figure

Exponents appearing in heterogeneous reaction-diffusion models in one dimension

We study the following 1D two-species reaction diffusion model : there is a small concentration of B-particles with diffusion constant $D_B$ in an homogenous background of W-particles with diffusion constant $D_W$; two W-particles of the majority species either coagulate ($W+W \longrightarrow W$) or annihilate ($W+W \longrightarrow \emptyset$) with the respective probabilities $p_c=(q-2)/(q-1)$ and $p_a=1/(q-1)$; a B-particle and a W-particle annihilate ($W+B \longrightarrow \emptyset$) with probability 1. The exponent $\theta(q,\lambda=D_B/D_W)$ describing the asymptotic time decay of the minority B-species concentration can be viewed as a generalization of the exponent of persistent spins in the zero-temperature Glauber dynamics of the 1D $q$-state Potts model starting from a random initial condition : the W-particles represent domain walls, and the exponent $\theta(q,\lambda)$ characterizes the time decay of the probability that a diffusive "spectator" does not meet a domain wall up to time $t$. We extend the methods introduced by Derrida, Hakim and Pasquier ({\em Phys. Rev. Lett.} {\bf 75} 751 (1995); Saclay preprint T96/013, to appear in {\em J. Stat. Phys.} (1996)) for the problem of persistent spins, to compute the exponent $\theta(q,\lambda)$ in perturbation at first order in $(q-1)$ for arbitrary $\lambda$ and at first order in $\lambda$ for arbitrary $q$.Comment: 29 pages. The three figures are not included, but are available upon reques

Autonomous models solvable through the full interval method

The most general exclusion single species one dimensional reaction-diffusion models with nearest-neighbor interactions which are both autonomous and can be solved exactly through full interval method are introduced. Using a generating function method, the general solution for, $F_n$, the probability that $n$ consecutive sites be full, is obtained. Some other correlation functions of number operators at nonadjacent sites are also explicitly obtained. It is shown that for a special choice of initial conditions some correlation functions of number operators called full intervals remain uncorrelated

Reaction Kinetics of Clustered Impurities

We study the density of clustered immobile reactants in the diffusion-controlled single species annihilation. An initial state in which these impurities occupy a subspace of codimension d' leads to a substantial enhancement of their survival probability. The Smoluchowski rate theory suggests that the codimensionality plays a crucial role in determining the long time behavior. The system undergoes a transition at d'=2. For d'<2, a finite fraction of the impurities survive: ni(t) ~ ni(infinity)+const x log(t)/t^{1/2} for d=2 and ni(t) ~ ni(infinity)+const/t^{1/2} for d>2. Above this critical codimension, d'>=2, the subspace decays indefinitely. At the critical codimension, inverse logarithmic decay occurs, ni(t) ~ log(t)^{-a(d,d')}. Above the critical codimension, the decay is algebraic ni(t) ~ t^{-a(d,d')}. In general, the exponents governing the long time behavior depend on the dimension as well as the codimension.Comment: 10 pages, late

Coherent State path-integral simulation of many particle systems

The coherent state path integral formulation of certain many particle systems allows for their non perturbative study by the techniques of lattice field theory. In this paper we exploit this strategy by simulating the explicit example of the diffusion controlled reaction $A+A\to 0$. Our results are consistent with some renormalization group-based predictions thus clarifying the continuum limit of the action of the problem.Comment: 20 pages, 4 figures. Minor corrections. Acknowledgement and reference correcte

Exactly solvable models through the empty interval method

The most general one dimensional reaction-diffusion model with nearest-neighbor interactions, which is exactly-solvable through the empty interval method, has been introduced. Assuming translationally-invariant initial conditions, the probability that $n$ consecutive sites are empty ($E_n$), has been exactly obtained. In the thermodynamic limit, the large-time behavior of the system has also been investigated. Releasing the translational invariance of the initial conditions, the evolution equation for the probability that $n$ consecutive sites, starting from the site $k$, are empty ($E_{k,n}$) is obtained. In the thermodynamic limit, the large time behavior of the system is also considered. Finally, the continuum limit of the model is considered, and the empty-interval probability function is obtained.Comment: 12 pages, LaTeX2

A Method of Intervals for the Study of Diffusion-Limited Annihilation, A + A --> 0

We introduce a method of intervals for the analysis of diffusion-limited annihilation, A+A -> 0, on the line. The method leads to manageable diffusion equations whose interpretation is intuitively clear. As an example, we treat the following cases: (a) annihilation in the infinite line and in infinite (discrete) chains; (b) annihilation with input of single particles, adjacent particle pairs, and particle pairs separated by a given distance; (c) annihilation, A+A -> 0, along with the birth reaction A -> 3A, on finite rings, with and without diffusion.Comment: RevTeX, 13 pages, 4 figures, 1 table. References Added, and some other minor changes, to conform with final for

The Swift Surge of Perovskite Photovoltaics

The breakthrough early 1990s dye sensitization of mesoscopic TiO2 films along with a regenerative iodide redox couple led to the explosive growth of dye-sensitized solar cell (DSC) research. The pioneering work of Grätzel and colleagues also made it possible to develop a solid-state DSSC with spiro-oMETAD as the hole conductor and thus replace the liquid electrolyte in the cell. Research efforts of Konenkamp and others further initiated the search for the “extremely thin absorber” (ETA) nanostructured solar cell, using TiO2 as the electron conductor, an inorganic absorber, and a hole conductor. Another major research thrust was by Weller, Kamat, Zaban, Nozik, Hodes, and others, who employed inorganic quantum dots (e.g., CdS and CdSe) as sensitizers. While discussing developments in sensitized solar cells, it is important to note the contributions of early visionaries like Gerischer, Sutin, and Bard, who were first to establish the concepts of sensitization using dye molecules and semiconductor nanostructures

Subdiffusion-limited reactions

We consider the coagulation dynamics A+A -> A and A+A A and the annihilation dynamics A+A -> 0 for particles moving subdiffusively in one dimension. This scenario combines the "anomalous kinetics" and "anomalous diffusion" problems, each of which leads to interesting dynamics separately and to even more interesting dynamics in combination. Our analysis is based on the fractional diffusion equation

Solution of a one-dimensional stochastic model with branching and coagulation reactions

We solve an one-dimensional stochastic model of interacting particles on a chain. Particles can have branching and coagulation reactions, they can also appear on an empty site and disappear spontaneously. This model which can be viewed as an epidemic model and/or as a generalization of the {\it voter} model, is treated analytically beyond the {\it conventional} solvable situations. With help of a suitably chosen {\it string function}, which is simply related to the density and the non-instantaneous two-point correlation functions of the particles, exact expressions of the density and of the non-instantaneous two-point correlation functions, as well as the relaxation spectrum are obtained on a finite and periodic lattice.Comment: 5 pages, no figure. To appear as a Rapid Communication in Physical Review E (September 2001