The Interoperability of Things: Interoperable solutions as an enabler for IoT and Web 3.0

This paper presents an overview of the interoperability concepts along with the challenges for the IoT domain and the upcoming Web 3.0. We identify four levels of interoperability and the relevant solutions for accomplishing vertical and horizontal compatibility between the various layers of a modern IoT ecosystem, referred to as: technological, syntactic, semantic, and organizational interoperability. The goal is to achieve cross-domain interaction and facilitate the proper usage and management of the provided IoT services and applications. An interoperability framework is also proposed where the involved system components can cooperate and offer the seamless operation from the device to the backend framework. This by-design end-to-end interoperation enables the interplay of several complex service composition settings and the management of the system via patterns. The overall proposal is adopted by the EU funded project SEMIoTICS as an enabler towards the IoT and Web 3.0, even when products from different vendors are utilized

Estimation of ecological exergy using weighing parameters determined from DNA contents of organisms – a case study

We studied the changes of exergy and specific exergy with data of benthic macrofauna communities, periodically sampled along an estuarine gradient of eutrophication in the Mondego estuary (Western Portugal). Exergy estimates were calculated from organism biomass, based on weighing factors for the relative content of exergy per unit of biomass determined from DNA contents of organisms. Results were discussed in terms of both the macrofauna biomass production and the structural organisation of the system. Estimates for the exergy indices provided useful indications for the evaluation of environmental impact due to the eutrophication process. Different average values for the indices of exergy and specific exergy were estimated relatively to areas with different levels of eutrophication, in the ‘spatial’ gradient of eutrophication. Higher exergy levels and lower exergy content per unit of biomass (specific exergy) were associated to populations more stabilized or areas less perturbed. Additionally, the index of specific exergy seemed capable of providing indications for the qualitative alterations in the communities (in temporal and spatial terms) that go in the direction of the observations made in this ecosystem

Isoporphycene: The fourth constitutional isomer of porphyrin with an N-4 core - Occurrence of E/Z isomerism

Liberation of the ligand from the nickel complex 1 obtained by template synthesis yielded isoporphycene (as the octaethyl derivative 2), the first constitutional isomer of porphyrin with an N4 core for which E/Z isomerism is involved: Compound 2 is present as the E isomer, which is in rapid, presumably acid-catalyzed equilibrium with a small amount (2 %) of the Z isomer. The remaining unknown constitutional isomers of porphyrin are considerably higher in energy than the already rather labile isoporphycene, so that the latter should mark the border of existence for this type of structural variant of porphyrin