33 research outputs found

    Orange-Reddish Light Emitting Phosphor GdVO 4 :Sm 3+ Prepared by Solution Combustion Synthesis

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    The gadolinium vanadate doped with samarium (GdVO 4 :Sm 3+ ) nanopowder was prepared by the solution combustion synthesis (SCS) method. After synthesis, in order to achieve the full crystallinity, the material was annealed in air atmosphere at 900°C. Phase identification in the postannealed powder samples was performed by X-ray diffraction, and morphology was investigated by high-resolution scanning electron microscopy (SEM). Photoluminescence characterization of the emission spectrum and time-resolved analysis have been performed using the tunable laser optical parametric oscillator excitation and the streak camera. Several strong emission bands in the Sm 3+ emission spectrum were observed, located at 567 nm ( 4 G 5/2 – 6 H 5/2 ), 604 nm ( 4 G 5/2 – 6 H 7/2 ), and 646 (654) nm ( 4 G 5/2 – 6 H 9/2 ), respectively. The weak emission bands at 533 nm ( 4 F 3/2 – 6 H 5/2 ) and 706 nm ( 4 G 5/2 – 6 H 11/2 ) and a weak broad luminescence emission band of VO 4 3− were also observed by the detection system. We analyzed the possibility of using the host luminescence for two-color temperature sensing. The proposed method is improved by introducing the temporal dependence in the line intensity ratio measurements

    Quantitative-genetic analysis of intensity growth of gilts fertile breed and their hybrids in the nucleus farm

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    The paper analyzes the 2760 gilts four different genotypes, two of which are pure bred Landrace (429 gilts) and Yorkshire (421 gilts) and two hybrid F1(YxL) (999 gilts) and F1(LxY) (911 gilts), tested in the period from 2010 to 2011.Analyzed by the following traits of intensity growth: weight at weaning (WW), daily gain at suckling (DGS), weight in rearing (WR), daily gain at rearing (DGR), weight in test (WT), daily gain on test (DGT), weight of gilts (WG) and life gain (LG). Due to the manifestation of heterosis effect, hybrid gilts in rearing made any higher body weight of about 3 kg, while the age of 160 days on average had a higher body weight by 7.0 kg compared to the pure breed gilts, which resulted in higher daily gain in different phases of rearing. Degree of heritability for analysis traits of intensity growth is of medium to high. Heritability (h2) for daily gains were larger (0.640 for DGS, 0.858 for DGR and 0.859 for DGT) in relation to the heritability for achieved body weight (0.584 for WW, 0.558 for WR and 0.816 for WT) in different phases of rearing. Between the most observed traits were found positive genetic and phenotypic correlations. The negative correlation found between WR, DGR and WT, DGT (rg= -0.055 to -0.108; rp = -0.010 to - 0.033), between WW, DGS and DGR (rg= -0.301 respectively -0.466; rp = -0.234 respectively -0.271)

    Polymer composite films and nanofibers doped with core-shell quantum dots

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    Processing and characterization of polymer nanocomposites based on poly(methyl methacrylate) (PMMA) matrix with embedded core-shell CdSe/ZnS quantum dots were investigated. Nanocomposites were obtained via solution casting and electrospinning. FESEM analysis revealed that the processing with electrospinning enables better dispersion of quantum dots. Time-resolved laser induced fluorescence measurements confirmed uniform size of QDs in fibers with the emission at only one wavelength. Oxidation effects in quantum dots were removed with the use of PMMA as a host, and the core remained active, which was confirmed with FTIR analysis and time-resolved laser induced fluorescence measurements

    Elastic scattering of electrons from alanine

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    Differential cross sections (DCSs) for elastic scattering of electrons from alanine, have been measured using a crossed beam system for incident energies between 20 and 80 eV and scattering angles from 10° to 150°. The experimental data were placed upon an absolute scale by normalisation to calculated absolute integral cross sections obtained using the corrected independent-atom method incorporating an improved quasifree absorption model. The calculated data-set includes DCSs and integral elastic and inelastic cross sections in the incident energy range between 1 and 10,000 eV. These theoretical results are found to agree very well with the experimental data both in the shape and magnitude of DCSs except at the smallest scattering angles

    Transport of electrons and propagation of the negative ionisation fronts in indium vapour

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    22 pags., 23 figs.We study the transport of electrons and propagation of the negative ionisation fronts in indium vapour. Electron swarm transport properties are calculated using a Monte Carlo simulation technique over a wide range of reduced electric fields E/N (where E is the electric field and N is the gas number density) and indium vapour temperatures in hydrodynamic conditions, and under non-hydrodynamic conditions in an idealised steady-state Townsend (SST) setup. As many indium atoms are in the first metastable state at vapour temperatures of a few thousand Kelvin, the initial Monte Carlo code was extended and generalized to consider the spatial relaxation and the transport of electrons in an idealised SST experiment, in the presence of thermal motion of the host-gas atoms and superelastic collisions. We observe a significant sensitivity of the spatial relaxation of the electrons on the indium vapour temperature and the initial conditions used to release electrons from the cathode into the space between the electrodes. The calculated electron transport coefficients are used as input for the classical fluid model, to investigate the inception and propagation of negative ionisation fronts in indium vapour at various E/N and vapour temperatures. We calculate the electron density, electric field, and velocity of ionisation fronts as a function of E/N and indium vapour temperature. The presence of indium atoms in the first metastable state significantly affects the characteristics of the negative ionisation fronts. The transition from an avalanche into a negative ionisation front occurs faster with increasing indium vapour temperature, due to enhanced ionisation and more efficient production of electrons at higher vapour temperatures. For lower values of E/N, the electron density behind the streamer front, where the electric field is screened, does not decay as one might expect for atomic gases, but it could be increased due to the accumulation of low-energy electrons that are capable of initiating ionisation in the streamer interior.The work of SD, JA, DB, MSR, DS, and BPM was sup- ˇported by the Ministry of Education, Science and Technological Development of the Republic of Serbia, and the Institute of Physics (Belgrade). The work of KRH, OZ, and KB was supported by the United States National Science Foundation under Grant Nos. OAC-1834740, PHY-1803844, and PHY-2110023, and by the XSEDE supercomputer Allocation No. PHY-090031. The work of DVF and IB, was supported by the Australian Research Council and resources provided by the Pawsey Supercomputing Centre with funding from the Australian Government and the Government of Western Australia. FB and GG acknowledge partial financial support from the Spanish Ministry MICIU (Project Nos. FIS2016-80440 and PID2019-104727-RB-C21) and CSIC (Project No. LINKA20085). This work was also financially supported by the Australian Research Council (Project No. DP180101655).Peer reviewe

    Recommended Cross Sections for Electron-Indium Scattering

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    20 pags., 7 figs., 6 tabs.We report, over an extended energy range, recommended angle-integrated cross sections for elastic scattering, discrete inelastic scattering processes, and the total ionization cross section for electron scattering from atomic indium. In addition, from those angle-integrated cross sections, a grand total cross section is subsequently derived. To construct those recommended cross-section databases, results from original B-spline R-matrix, relativistic convergent close-coupling, and relativistic optical-potential computations are also presented here. Electron transport coefficients are subsequently calculated, using our recommended database, for reduced electric fields ranging from 0.01 Td to 10 000 Td using a multiterm solution of Boltzmann's equation. To facilitate those simulations, a recommended elastic momentum transfer cross-section set is also constructed and presented here.The work of K.R.H., O.Z., and K.B. was supported by the United States National Science Foundation under Grant Nos. OAC-1834740 and PHY-1803844 and by the XSEDE supercomputer Allocation No. PHY-090031. The (D)BSR calculations were carried out on Stampede2 at the Texas Advanced Computing Center. The work of D.V.F. and I.B. was supported by the Australian Research Council and resources provided by the Pawsey Supercomputing Centre with funding from the Australian Government and the Government of Western Australia. F.B. and G.G. acknowledge partial financial support from the Spanish Ministry MICIU (Project Nos. FIS2016- 80440 and PID2019-104727-RB-C21) and CSIC (Project No. LINKA20085). This work was also financially supported, in part, by the Australian Research Council (Project No. DP180101655), the Ministry of Education, Science and Technological Development of the Republic of Serbia, and the Institute of Physics (Belgrade).Peer reviewe

    Excitations of 1P levels of zinc by electron impact on the ground state

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    We present results of a joint theoretical and experimental investigation of electron scattering from the 4s2 1S ground state of zinc. The 4s4p 1Po and 4s5p 1Po differential cross sections were measured at scattering angles between 10° and 150° and electron-energies of 15, 20, 25, 40, and 60 eV. Corresponding convergent close-coupling calculations have been performed and are compared with experiment

    Emerging Markets: Preferences, R isks, Performance...

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    The paper surveys the most important literature on emerging markets and their performance. Emerging market countries are defined here as the countries with low intuitional capacity in general, rather than the countries with particular economic characteristics and per capita income; although the latter is the predominant view in the current literature. The paper places particular importance on the legal system and legal order (compliance) in the transitional economies, stressing the importance of adequate regulation where even more advanced regulatory models, like market regulation, should not be totally excluded. Despite many common characteristics, emerging markets differ significantly one from another and it is very difficult, if really not impossible, to create one ‘general theory of emerging markets’ and its financial behaviour. Finally, the practice in the last decade or so, has proven that emerging markets are somewhat unpredictable and difficult to model. Copyright Springer 2005emerging markets, Financial Reform, Market Performance, Transition Social Transition, P5, P2, G1, G2, G3,

    Annealed nanopowder GdVO4 :Sm3+ prepared by solution combustion synthesis

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    The gadolinium vanadate doped with samarium (GdVO4 :Sm3+) nanopowder was prepared by the solution combustion synthesis (SCS) method. After synthesis, in order to achieve the full crystallinity, the material was annealed in air atmosphere at 1300 °C. Phase identification in the post-annealed powder samples were performed by X-ray diffraction, and morphology was investigated by high resolution scanning electron microscope (SEM). Photoluminescence characterization including excitation and emission spectra and lifetime analysis has been done using tunable laser optical parametric oscillator excitation and streak camera. Several strong emission bands in Sm3+ emission spectrum were observed, located at 563 nm (4 G5/2 – 6 H5/2), 600 nm (4 G5/2 – 6 H7/2,), and 644 (653) nm (4 G5/2 – 6 H9/2,), respectively. The weak emission at 700-710 nm (4 G5/2 – 6 H11/2) was also observed by detection system.V Serbian Ceramic Society Conference - Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts; September 21-23, 2016; Belgrad
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