Supercritical multicomponent solvent coal extraction

The yield of organic extract from the supercritical extraction of coal with larger diameter organic solvents such as toluene is increased by use of a minor amount of from 0.1 to 10% by weight of a second solvent such as methanol having a molecular diameter significantly smaller than the average pore diameter of the coal

Modeling of secondary organic aerosol yields from laboratory chamber data

Laboratory chamber data serve as the basis for constraining models of secondary organic aerosol (SOA) formation. Current models fall into three categories: empirical two-product (Odum), product-specific, and volatility basis set. The product-specific and volatility basis set models are applied here to represent laboratory data on the ozonolysis of α-pinene under dry, dark, and low-NOx conditions in the presence of ammonium sulfate seed aerosol. Using five major identified products, the model is fit to the chamber data. From the optimal fitting, SOA oxygen-to-carbon (O/C) and hydrogen-to-carbon (H/C) ratios are modeled. The discrepancy between measured H/C ratios and those based on the oxidation products used in the model fitting suggests the potential importance of particle-phase reactions. Data fitting is also carried out using the volatility basis set, wherein oxidation products are parsed into volatility bins. The product-specific model is most likely hindered by lack of explicit inclusion of particle-phase accretion compounds. While prospects for identification of the majority of SOA products for major volatile organic compounds (VOCs) classes remain promising, for the near future empirical product or volatility basis set models remain the approaches of choice

Quark Loop Contributions to Neutron, Deuteron, and Mercury EDMs from Supersymmetry without R parity

We present a detailed analysis of the neutron, deuteron and mercury electric dipole moment from supersymmetry without R parity, focusing on the quark-scalar loop contributions. Being proportional to top Yukawa and top mass, such contributions are often large. Analytical expressions illustrating the explicit role of the R-parity violating parameters are given following perturbative diagonalization of mass-squared matrices for the scalars. Dominant contributions come from the combinations $B_i \lambda^{\prime}_{ij1}$ for which we obtain robust bounds. It turns out that neutron and deuteron EDMs receive much stronger contributions than mercury EDM and any null result at the future deuteron EDM experiment or Los Alamos neutron EDM experiment can lead to extra-ordinary constraints on RPV parameter space. Even if R-parity violating couplings are real, CKM phase does induce RPV contribution and for some cases such a contribution is as strong as contribution from phases in the R-parity violating couplings.Hence, we have bounds directly on $|B_i \lambda^{\prime}_{ij1}|$ even if the RPV parameters are all real. Interestingly, even if slepton mass and/or $\mu_0$ is as high as 1 TeV, it still leads to neutron EDM that is an order of magnitude larger than the sensitivity at Los Alamos experiment. Since the results are not much sensitive to $\tan \beta$, our constraints will survive even if other observables tighten the constraints on $\tan \beta$.Comment: 16 pages, 10 figures, accepted for publication in Physical Review

Fos co-operation with PTEN loss elicits keratoacanthoma not carcinoma due to p53/p21^WAF-induced differentiation triggered by GSK3b inactivation and reduced AKT activity

To investigate gene synergism in multistage skin carcinogenesis, the RU486-inducible cre/lox system was employed to ablate PTEN function [K14.cre/D5PTENflx] in mouse epidermis expressing activated v-fos [HK1.fos]. RU486-treated HK1.fos/D5PTENflx mice exhibited hyperplasia, hyperkeratosis and tumours that progressed to highly differentiated keratoacanthomas rather than carcinomas, due to re-expression of high p53 and p21WAF levels. Despite elevated MAP kinase activity, cyclin D1/E2 over expression and increased AKT activity forming areas of highly proliferative, papillomatous keratinocytes, increasing levels of GSK3b inactivation exceeded a threshold that induced p53/p21WAF expression to halt proliferation and accelerate differentiation, giving the hallmark keratosis of keratoacanthomas. A pivotal facet to this GSK3b-triggered mechanism centred on increasing p53 expression in basal layer keratinocytes. This reduced activated AKT expression and released inhibition of p21WAF, which accelerated keratinocyte differentiation, as indicated by unique basal layer expression of differentiation-specific keratin K1, alongside premature filaggrin and loricrin expression. Thus, fos synergism with PTEN loss elicited a benign tumour context where GSK3b-induced, p53/p21WAF expression continually switched AKT-associated proliferation into one of differentiation, preventing further progression. This putative compensatory mechanism required the critical availability of normal p53 and/or p21WAF otherwise deregulated fos, Akt and GSK3b associate with malignant progression

Piezoelectric copolymer hydrophones for ultrasonic field characterization

Hydrophones to be used in the characterization of medical ultrasonic transducers have been fabricated using a new polyvinylidene fluoride/trifluoroethylene (VF2/VF3) copolymer. The copolymer has an advantage over VF2 in that it does not require prestretching before poling. Thin copolymer films can be cast from solution and then poled using the corona discharge method. As there is a need for small‐diameter hydrophones to provide good spatial resolution in measuring highly focused ultrasonic beams, hydrophones with diameter as small as 0.1 mm have been made. Both needle‐type and line hydrophones have been tested and their performance reported. In the case of line hydrophones, the output signal is proportional to the line integral of the acoustic pressure and a computer tomographic technique has been used to reconstruct the beam profiles

Public Bikesharing in North America During a Period of Rapid Expansion: Understanding Business Models, Industry Trends & User Impacts, MTI Report 12-29

Public bikesharing—the shared use of a bicycle fleet—is an innovative transportation strategy that has recently emerged in major cities around the world, including North America. Information technology (IT)-based bikesharing systems typically position bicycles throughout an urban environment, among a network of docking stations, for immediate access. Trips can be one-way, round-trip, or both, depending on the operator. Bikesharing can serve as a first-and-last mile connector to other modes, as well as for both short and long distance destinations. In 2012, 22 IT-based public bikesharing systems were operating in the United States, with a total of 884,442 users and 7,549 bicycles. Four IT-based programs in Canada had a total of 197,419 users and 6,115 bicycles. Two IT-based programs in Mexico had a total of 71,611 users and 3,680 bicycles. (Membership numbers reflect the total number of short- and long-term users.) This study evaluates public bikesharing in North America, reviewing the change in travel behavior exhibited by members of different programs in the context of their business models and operational environment. This Phase II research builds on data collected during our Phase I research conducted in 2012. During the 2012 research (Phase I), researchers conducted 14 expert interviews with industry experts and public officials in the United States and Canada, as well as 19 interviews with the manager and/or key staff of IT-based bikesharing organizations. For more information on the Phase I research, please see the Shaheen et al., 2012 report Public Bikesharing in North America: Early Operator and User Understanding. For this Phase II study, an additional 23 interviews were conducted with IT-based bikesharing organizations in the United States, Canada, and Mexico in Spring 2013. Notable developments during this period include the ongoing expansion of public bikesharing in North America, including the recent launches of multiple large bikesharing programs in the United States (i.e., Citi Bike in New York City, Divvy in Chicago, and Bay Area Bike Share in the San Francisco Bay Area). In addition to expert interviews, the authors conducted two kinds of surveys with bikesharing users. One was the online member survey. This survey was sent to all people for whom the operator had an email address.The population of this survey was mainly annual members of the bikesharing system, and the members took the survey via a URL link sent to them from the operator. The second survey was an on-street survey. This survey was designed for anyone, including casual users (i.e., those who are not members of the system and use it on a short-term basis), to take “on-street” via a smartphone. The member survey was deployed in five cities: Montreal, Toronto, Salt Lake City, Minneapolis-Saint Paul, and Mexico City. The on-street survey was implemented in three cities: Boston, Salt Lake City, and San Antonio

Structure determination of the reconstructed Au(110) surface

The LEED pattern of the Au(110) surface shows a (1 × 2) and also a (1× 3) superstructure. The (1 × 2) superstructure has been determined by comparison of LEED intensities with model calculations. The missing row model is the most probable model. A minimum of the averaged r-factor, , has been found for 15% contraction of the first layer spacing without atomic displacements in the second layer

Development of a CCD for ultraviolet imaging using a CCD photocathode combination

CCD in the electron-in mode, coupled with a bi-alkali photocathode to produce UV photon conversion, provides the following desirable features: (1) high UV response of the bi-alkali photocathode; (2) excellent imaging quality of a CCD area array; and (3) high signal-to-noise ratio due to the EBS (electron bombarded silicon) gain of the CCD operating in a tube configuration. This paper describes the rationale and progress made in developing a CCD for use as an UV imager

Quantum field and uniformly accelerated oscillator

We present an exact treatment of the influences on a quantum scalar field in its Minkowski vacuum state induced by coupling of the field to a uniformly accelerated harmonic oscillator. We show that there are no radiation from the oscillator in the point of view of a uniformly accelerating observer. On the other hand, there are radiations in the point of view of an inertial observer. It is shown that Einstein-Podolsky-Rosen (EPR) like correlations of Rindler particles in Minkowski vacuum states are modified by a phase factor in front of the momentum-symmetric Rindler operators. The exact quantization of a time-dependent oscillator coupled to a massless scalar field was given.Comment: 28 pages, LaTe