Transport efficiency and dynamics of hydraulic fracture networks

Acknowledgments This study is carried out within the framework of DGMK (German Society for Petroleum and Coal Science and Technology) research project 718 “Mineral Vein Dynamics Modeling,” which is funded by the companies ExxonMobil Production Deutschland GmbH, GDF SUEZ E&P Deutschland GmbH, RWE Dea AG and Wintershall Holding GmbH, within the basic research programme of the WEG Wirtschaftsverband Erdöl- und Erdgasgewinnung e.V. We thank the companies for their financial support and their permission to publish our results. We further acknowledge support by Deutsche Forschungsgemeinschaft and Open Access Publishing Fund of University of Tübingen.Peer reviewedPublisher PD

An Investigation into the Use of a Movement Assessment Protocol for Under-14 Rugby League Players in a Talent Development Environment

This study investigated the use of a movement assessment protocol for under-14 rugby league players by evaluating the relationships between chronological age, maturation, and anthropometry, and fitness and qualitative movement assessments (QMA) of 84 rugby league players within a talent development environment. A one-way ANOVA showed Quartile 1 players were more mature, taller (173.0±7.4 vs 165.0±8.0 cm) and heavier (72.5 vs 58.7 kg) than Quartile 4 players, with no difference evident for fitness or QMA measures. Earlier maturing players had significantly greater upper body power (5.39±0.46 vs 4.42±0.68 m), 20m speed (3.48±0.14 vs 3.65±0.19s) and power pass QMA (13.88±2.18 vs 12.00±1.98) than later maturing players. Body mass was positively related to power pass fitness (r=0.50) and QMA (r=0.22) scores, with negative relationships found for vertical jump performance (r=-0.24), sprint QMA (r=-.29) and turn off either foot QMA (r=-0.26). There is a need to educate coaches about the use of both fitness testing and qualitative movement assessments to identify talented U14 rugby league players, which potentially reduces relative age and maturational biases

Structural analysis of the GH43 enzyme Xsa43E from Butyrivibrio proteoclasticus

The rumen of dairy cattle can be thought of as a large, stable fermentation vat and as such it houses a large and diverse community of microorganisms. The bacterium Butyrivibrio proteoclasticus is a representative of a significant component of this microbial community. It is a xylan-degrading organism whose genome encodes a large number of open reading frames annotated as fibre-degrading enzymes. This suite of enzymes is essential for the organism to utilize the plant material within the rumen as a fuel source, facilitating its survival in this competitive environment. Xsa43E, a GH43 enzyme from B. proteoclasticus, has been structurally and functionally characterized. Here, the structure of selenomethionine-derived Xsa43E determined to 1.3 Å resolution using single-wavelength anomalous diffraction is reported. Xsa43E possesses the characteristic five-bladed β-propeller domain seen in all GH43 enzymes. GH43 enzymes can have a range of functions, and the functional characterization of Xsa43E shows it to be an arabinofuranosidase capable of cleaving arabinose side chains from short segments of xylan. Full functional and structural characterization of xylan-degrading enzymes will aid in creating an enzyme cocktail that can be used to completely degrade plant material into simple sugars. These molecules have a range of applications as starting materials for many industrial processes, including renewable alternatives to fossil fuels

International Family Migration and the Dual-Earner Model

Gender differences in labor force participation are exceptionally small in Nordic countries. We investigate how couples emigrating from Denmark self-select and sort into different destinations and whether couples pursue the dual-earner model, in which both partners work, when abroad. Female labor force participation is slightly lower among couples that later emigrate, and drops considerably after migration outside the Nordic countries. Pre-migration differences between couples subsequently migrating to different destinations are small. Our survey reveals that couple migration is usually driven by the male’s job opportunities. The results suggest that increasing international migration may reduce women’s career investments

Differences in the Movement Skills and Physical Qualities of Elite Senior & Academy Rugby League Players.

The aim of the present study was to investigate (a) the differences in the movement skills and physical qualities between academy and senior rugby league players, and (b) the relationships between movement skills and physical qualities. Fifty-five male rugby league players (Senior, n=18; Under 19 n=23; Under 16, n=14) undertook a physical testing battery including anthropometric (stature & body mass), strength (isometric mid-thigh pull; IMTP) and power (countermovement jump; CMJ) qualities, alongside the athletic ability assessment (AAA; comprised of overhead squat, double lunge, single-leg Romanian deadlift, press-up and pull-up exercises). Univariate analysis of variance demonstrated significant (p<0.001) differences in body mass, IMTP peak force, CMJ mean power, and AAA movement skills between groups. The greatest observed differences for total movement skills, peak force and mean power were identified between Under 16 and 19 academy age groups. Spearman's rank correlation coefficients demonstrated a significant moderate (r=0.31) relationship between peak force and total movement skill. Furthermore, trivial (r=0.01) and small (r=0.13; r=0.22) relationships were observed between power qualities and total movement skill. These findings highlight that both movement skills and physical qualities differentiate between academy age groups, and provides comparative data for English senior and academy rugby league players

The Use of Microtechnology to Quantify the Peak Match Demands of the Football Codes: A Systematic Review.

BACKGROUND: Quantifying the peak match demands within the football codes is useful for the appropriate prescription of external training load. Wearable microtechnology devices can be used to identify the peak match demands, although various methodologies exist at present. OBJECTIVES: This systematic review aimed to identify the methodologies and microtechnology-derived variables used to determine the peak match demands, and to summarise current data on the peak match demands in the football codes. METHODS: A systematic search of electronic databases was performed from earliest record to May 2018; keywords relating to microtechnology, peak match demands and football codes were used. RESULTS: Twenty-seven studies met the eligibility criteria. Six football codes were reported: rugby league (n = 7), rugby union (n = 5), rugby sevens (n = 4), soccer (n = 6), Australian Football (n = 2) and Gaelic Football (n = 3). Three methodologies were identified: moving averages, segmental and 'ball in play'. The moving averages is the most commonly used (63%) and superior method, identifying higher peak demands than other methods. The most commonly used variables were relative distance covered (63%) and external load in specified speed zones (57%). CONCLUSION: This systematic review has identified moving averages to be the most appropriate method for identifying the peak match demands in the football codes. Practitioners and researchers should choose the most relevant duration-specific period and microtechnology-derived variable for their specific needs. The code specific peak match demands revealed can be used for the prescription of conditioning drills and training intensity

Ab initio calculations of edge-functionalized armchair graphene nanoribbons: Structural, electronic, and vibrational effects

We present a theoretical study on narrow armchair graphene nanoribbons (AGNRs) with hydroxyl functionalized edges. Although this kind of passivation strongly affects the structure of the ribbon, a high degree of edge functionalization proves to be particularly stable. An important consequence of the geometric deviations is a severe reduction of the band-gap of the investigated 7-AGNR. This shift follows a linear dependence on the number of added hydroxyl groups per unit cell and thus offers the prospect of a tunable band-gap by edge functionalization. We furthermore cover the behavior of characteristic phonons for the ribbon itself as well as fingerprint modes of the hydroxyl groups. A large down-shift of prominent Raman active modes allows the experimental determination of the degree of edge functionalization.Comment: 6 pages, 9 figure