An Independent Calibration of Stellar Ages: HST Observations of White Dwarfs at V=25

The white dwarf luminosity function of a stellar cluster will have a sharp truncation at a luminosity which is determined by the time since formation of the first white dwarfs in that cluster. Calculation of the dependence of this limiting luminosity on age requires relatively well-understood physics and is independent of stellar evolutionary models. Thus, measurement of the termination of the white dwarf luminosity function provides an independent method to determine the age of a cluster, and thereby to calibrate stellar evolutionary ages. We have obtained HST WFPC2 data in two open clusters, identified the white dwarf sequence, and proved the feasibility of this approach, by detecting white dwarfs to V=25. Much deeper data are feasible. From our present limited data, we show that degenerate cooling ages are not consistent with some published isochrone ages for clusters with ages of order 1Gyr.Comment: 5 pages plus 3 figures ps format, paper in press in MNRAS: previous attempt lost the tex

Low-Metallicity Gas Clouds in a Galaxy Proto-Cluster at Redshift 2.38

We present high resolution spectroscopy of a QSO whose sight-line passes through the halo of a pair of elliptical galaxies at redshift 2.38. This pair of galaxies probably lies at the center of a galaxy proto-cluster, and is embedded in a luminous extended Ly-alpha nebula. The QSO sight-line intersects two small gas clouds within this halo. These clouds have properties similar to those of high velocity clouds (HVCs) seen in the halo of the Milky Way. The gas is in a cool (< 2 x 10^4 K) and at least 20% neutral phase, with metallicities in the range -3.0 < [Fe/H] < -1.1 and neutral hydrogen column densities of ~10^19.5 /cm^2. The origin of these clouds is unclear. The presence of low metallicity gas within this possible proto-cluster implies either that the intra-cluster medium has not been enriched with metals at this redshift, or the clouds are embedded within a hot, ionized, metal-rich gas phase.Comment: Accepted to appear in ApJ Letter

The Fluctuating Intergalactic Radiation Field at Redshifts z = 2.3-2.9 from He II and H I Absorption towards HE 2347-4342

We provide an in-depth analysis of the He II and H I absorption in the intergalactic medium (IGM) at redshifts z = 2.3-2.9 toward HE 2347-4342, using spectra from the Far Ultraviolet Spectroscopic Explorer (FUSE) and the Ultraviolet-Visual Echelle Spectrograph (UVES) on the VLT telescope. Following up on our earlier study (Kriss et al. 2001, Science, 293, 1112), we focus here on two major topics: (1) small-scale variability (Delta z = 10^-3) in the ratio eta = N(He II)/N(H I); and (2) an observed correlation of high-eta absorbers (soft radiation fields) with voids in the (H I) Ly-alpha distribution. These effects may reflect fluctuations in the ionizing sources on scales of 1 Mpc, together with radiative transfer through a filamentary IGM whose opacity variations control the penetration of 1-5 ryd radiation over 30-40 Mpc distances. Owing to photon statistics and backgrounds, we can measure optical depths over the ranges 0.1 < tau(HeII) < 2.3 and 0.02 < tau(HI) < 3.9, and reliably determine values of eta = 4 tau(HeII)/tau(HI) over the range 0.1 to 460. Values of eta = 20-200 are consistent with models of photoionization by quasars with observed spectral indices alpha_s = 0-3. Values of eta > 200 may require additional contributions from starburst galaxies, heavily filtered quasar radiation, or density variations. Regions with eta < 30 may indicate the presence of local hard sources. We find that eta is higher in "void" regions, where H I is weak or undetected and 80% of the path length has eta > 100. These voids may be ionized by soft sources (dwarf starbursts) or by QSO radiation softened by escape from the AGN cores or transfer through the "cosmic web". The apparent differences in ionizing spectra may help to explain the 1.45 Gyr lag between the reionization epochs, z(HI) = 6.2 +/-0.2 and z(HeII) = 2.8 +/-0.2.Comment: 27 pages, 7 figures, to appear in Ap

Immaculateness and Research Practice

Notions of purity, perfection, or immaculateness have powered our imagination over the ages. Various images of perfection have held sway in their hallowed times, providing secure streams for channelling human energy. Unfortunately, with the unfolding of the human drama on the world stage, all the images of perfection have suffered damage, epoch on epoch. Different responses have emerged to attempt a restoration. Revival of some of the old images is one such response. Production of new images to serve as worthwhile anchors of value and meaning is another common response. For reasons possibly known only to philosophers and historians, the enterprise called modern science has got thickly embroiled in this civilisational process--first, as the culprit behind the decline of some of the established images, then as the producer of new images, and now, perhaps, as a constant reminder of the perpetual lack of purity and immaculateness in all things human

Self-Suppression of Signal-Signal Beating Interference using a Split-Carrier Transmitter

A transmitter-side carrier tone is applied to suppress SSBI in a 112 Gb/s double sideband IM/DD system using a split-carrier transmitter. This novel, low-complexity approach achieves comparable performance to a computationally-intensive linearised receiver without any additional opto-electronic hardware or linearisation DSP

Enhanced catalytic activity of high index faceted palladium nanoparticles in Suzuki-Miyaura coupling due to efficient leaching mechanism

The structure-property relationship of palladium (Pd) catalysts in Suzuki-Miyaura cross-coupling reactions was investigated using Pd nanocrystals of uniform size and shape. Superior catalytic reactivity was observed for Pd nanoparticles with high-index {730} surface facets compared to low-index {100} facets. Although the nanocrystal morphologies were maintained during the reaction, the presence of Pd clusters, identified by high-resolution transmission electron microscopy (TEM), indicates a leaching mechanism. The nature of the surface facets on the nanoparticles was observed to influence the rate of Pd leaching during the Suzuki coupling reaction. The enhanced reactivity observed for the high-index facet catalysts stems from the greater number of leachable atoms of low abstraction energy available on high-index planes

The origin of shape sensitivity in palladium-catalyzed Suzuki–Miyaura cross coupling reactions

The shape sensitivity of Pd catalysts in Suzuki–Miyaura coupling reactions is studied using nanocrystals enclosed by well-defined surface facets. The catalytic performance of Pd nanocrystals with cubic, cuboctahedral and octahedral morphologies are compared. Superior catalytic reactivity is observed for Pd NCs with {100} surface facets compared to {111} facets. The origin of the enhanced reactivity associated with a cubic morphology is related to the leaching susceptibility of the nanocrystals. Molecular oxygen plays a key role in facilitating the leaching of Pd atoms from the surface of the nanocrystals. The interaction of O2 with Pd is itself facet-dependent, which in turn gives rise to more efficient leaching from {100} facets, compared to {111} facets under the reaction conditions