118 research outputs found
Magnetization of polydisperse colloidal ferrofluids: Effect of magnetostriction
We exploit magnetostriction in polydisperse ferrofluids in order to generate
nonlinear responses, and apply a thermodynamical method to derive the desired
nonlinear magnetic susceptibility. For an ideal gas, this method has been
demonstrated to be in excellent agreement with a statistical method. In the
presence of a sinusoidal ac magnetic field, the magnetization of the
polydisperse ferrofluid contains higher-order harmonics, which can be extracted
analytically by using a perturbation approach. We find that the harmonics are
sensitive to the particle distribution and the degree of field-induced
anisotropy of the system. In addition, we find that the magnetization is higher
in the polydisperse system than in the monodisperse one, as also found by a
recent Monte Carlo simulation. Thus, it seems possible to detect the size
distribution in a polydisperse ferrofluid by measuring the harmonics of the
magnetization under the influence of magnetostriction.Comment: 23 pages, 4 figures. To be accepted for publication in Phys. Rev.
Suppressing the Rayleigh-Taylor instability with a rotating magnetic field
The Rayleigh-Taylor instability of a magnetic fluid superimposed on a
non-magnetic liquid of lower density may be suppressed with the help of a
spatially homogeneous magnetic field rotating in the plane of the undisturbed
interface. Starting from the complete set of Navier-Stokes equations for both
liquids a Floquet analysis is performed which consistently takes into account
the viscosities of the fluids. Using experimentally relevant values of the
parameters we suggest to use this stabilization mechanism to provide controlled
initial conditions for an experimental investigation of the Rayleigh-Taylor
instability
Invalidation of the Kelvin Force in Ferrofluids
Direct and unambiguous experimental evidence for the magnetic force density
being of the form in a certain geometry - rather than being the
Kelvin force - is provided for the first time. (M is the
magnetization, H the field, and B the flux density.)Comment: 4 pages, 4 figure
A ferrofluid based neural network: design of an analogue associative memory
We analyse an associative memory based on a ferrofluid, consisting of a
system of magnetic nano-particles suspended in a carrier fluid of variable
viscosity subject to patterns of magnetic fields from an array of input and
output magnetic pads. The association relies on forming patterns in the
ferrofluid during a trainingdphase, in which the magnetic dipoles are free to
move and rotate to minimize the total energy of the system. Once equilibrated
in energy for a given input-output magnetic field pattern-pair the particles
are fully or partially immobilized by cooling the carrier liquid. Thus produced
particle distributions control the memory states, which are read out
magnetically using spin-valve sensors incorporated in the output pads. The
actual memory consists of spin distributions that is dynamic in nature,
realized only in response to the input patterns that the system has been
trained for. Two training algorithms for storing multiple patterns are
investigated. Using Monte Carlo simulations of the physical system we
demonstrate that the device is capable of storing and recalling two sets of
images, each with an accuracy approaching 100%.Comment: submitted to Neural Network
Magnetization of magnetoactive elastomers under the assumption of breakable adhesion at the particle/matrix interface
In this work we study the magnetization of magnetoactive elastomers (MAE) in which the interface between the matrix and magnetic particles is unstable and allows for slipping of the particles against the wall of their elastomer cavities. The estimate of the maximal angle at which each particle can decline its axis from the initial position is made based on cyclic measurement of several consecutive hysteresis loops at different maximal magnetic fields. A model of magnetization of magnetically hard multigrain particles in an elastic environment with allowance for their possible slipping is proposed. Results of modelling is in fair agreement with the experimental data obtained on MAEs whose polymeric matrix is made of polydimethylsiloxane and the magnetic filler is NdFeB spherical particles. © 2022 The Royal Society of ChemistryDeutsche Forschungsgemeinschaft, DFG: Bo 3343/3-1, Od 18/24-1; Russian Foundation for Basic Research, РФФИ: 19-52-12045The research was accomplished with the financial support by RFBR project 19-52-12045 and DFG projects Bo 3343/3-1 and Od 18/24-1
Theoretical study of the magnetization dynamics of non-dilute ferrofluids
The paper is devoted to the theoretical investigation of the magnetodipolar
interparticle interaction effect on remagnetization dynamics in moderately
concentrated ferrofluids. We consider a homogeneous (without particle
aggregates) ferrofluid consisting of identical spherical particles and employ a
rigid dipole model, where magnetic moment of a particle is fixed with respect
to the particle itself. In particular, for the magnetization relaxation after
the external field is instantly switched off, we show that the magnetodipolar
interaction leads to the increase of the initial magnetization relaxation time.
For the complex ac-susceptibility we find that the this interaction leads to an
overall increase of the imaginary susceptibility part and shifts the peak on
its frequency dependence towards lower frequencies. Comparing results obtained
with our analytical approach (second order virial expansion) to numerical
simulation data (Langevin dynamics method), we demonstrate that the employed
virial expansion approximation gives a good qualitative description of the
ferrofluid magnetization dynamics and provides a satisfactory quantitative
agreement with numerical simulations for the dc magnetization relaxation - up
to the particle volume fraction c ~ 10% and for the ac-susceptibility - up to c
~ 5 %.Comment: 12 pages, 6 figures, submitted to PR
Hydrodynamic interactions in colloidal ferrofluids: A lattice Boltzmann study
We use lattice Boltzmann simulations, in conjunction with Ewald summation
methods, to investigate the role of hydrodynamic interactions in colloidal
suspensions of dipolar particles, such as ferrofluids. Our work addresses
volume fractions of up to 0.20 and dimensionless dipolar interaction
parameters of up to 8. We compare quantitatively with Brownian
dynamics simulations, in which many-body hydrodynamic interactions are absent.
Monte Carlo data are also used to check the accuracy of static properties
measured with the lattice Boltzmann technique. At equilibrium, hydrodynamic
interactions slow down both the long-time and the short-time decays of the
intermediate scattering function , for wavevectors close to the peak of
the static structure factor , by a factor of roughly two. The long-time
slowing is diminished at high interaction strengths whereas the short-time
slowing (quantified via the hydrodynamic factor ) is less affected by the
dipolar interactions, despite their strong effect on the pair distribution
function arising from cluster formation. Cluster formation is also studied in
transient data following a quench from ; hydrodynamic interactions
slow the formation rate, again by a factor of roughly two
Magnetism, FeS colloids, and Origins of Life
A number of features of living systems: reversible interactions and weak
bonds underlying motor-dynamics; gel-sol transitions; cellular connected
fractal organization; asymmetry in interactions and organization; quantum
coherent phenomena; to name some, can have a natural accounting via
interactions, which we therefore seek to incorporate by expanding the horizons
of `chemistry-only' approaches to the origins of life. It is suggested that the
magnetic 'face' of the minerals from the inorganic world, recognized to have
played a pivotal role in initiating Life, may throw light on some of these
issues. A magnetic environment in the form of rocks in the Hadean Ocean could
have enabled the accretion and therefore an ordered confinement of
super-paramagnetic colloids within a structured phase. A moderate H-field can
help magnetic nano-particles to not only overcome thermal fluctuations but also
harness them. Such controlled dynamics brings in the possibility of accessing
quantum effects, which together with frustrations in magnetic ordering and
hysteresis (a natural mechanism for a primitive memory) could throw light on
the birth of biological information which, as Abel argues, requires a
combination of order and complexity. This scenario gains strength from
observations of scale-free framboidal forms of the greigite mineral, with a
magnetic basis of assembly. And greigite's metabolic potential plays a key role
in the mound scenario of Russell and coworkers-an expansion of which is
suggested for including magnetism.Comment: 42 pages, 5 figures, to be published in A.R. Memorial volume, Ed
Krishnaswami Alladi, Springer 201
CRISPR-Cas9 ribonucleoprotein-mediated co-editing and counterselection in the rice blast fungus
The rice blast fungus Magnaporthe oryzae is the most serious pathogen of cultivated rice and a significant threat to global food security. To accelerate targeted mutation and specific genome editing in this species, we have developed a rapid plasmid-free CRISPR-Cas9-based genome editing method. We show that stable expression of Cas9 is highly toxic to M. oryzae. However efficient gene editing can be achieved by transient introduction of purified Cas9 pre-complexed to RNA guides to form ribonucleoproteins (RNPs). When used in combination with oligonucleotide or PCR-generated donor DNAs, generation of strains with specific base pair edits, in-locus gene replacements, or multiple gene edits, is very rapid and straightforward. We demonstrate a co-editing strategy for the creation of single nucleotide changes at specific loci. Additionally, we report a novel counterselection strategy which allows creation of precisely edited fungal strains that contain no foreign DNA and are completely isogenic to the wild type. Together, these developments represent a scalable improvement in the precision and speed of genetic manipulation in M. oryzae and are likely to be broadly applicable to other fungal species
Rac1 Is Required for Pathogenicity and Chm1-Dependent Conidiogenesis in Rice Fungal Pathogen Magnaporthe grisea
Rac1 is a small GTPase involved in actin cytoskeleton organization and polarized cell growth in many organisms. In this study, we investigate the biological function of MgRac1, a Rac1 homolog in Magnaporthe grisea. The Mgrac1 deletion mutants are defective in conidial production. Among the few conidia generated, they are malformed and defective in appressorial formation and consequently lose pathogenicity. Genetic complementation with native MgRac1 fully recovers all these defective phenotypes. Consistently, expression of a dominant negative allele of MgRac1 exhibits the same defect as the deletion mutants, while expression of a constitutively active allele of MgRac1 can induce abnormally large conidia with defects in infection-related growth. Furthermore, we show the interactions between MgRac1 and its effectors, including the PAK kinase Chm1 and NADPH oxidases (Nox1 and Nox2), by the yeast two-hybrid assay. While the Nox proteins are important for pathogenicity, the MgRac1-Chm1 interaction is responsible for conidiogenesis. A constitutively active chm1 mutant, in which the Rac1-binding PBD domain is removed, fully restores conidiation of the Mgrac1 deletion mutants, but these conidia do not develop appressoria normally and are not pathogenic to rice plants. Our data suggest that the MgRac1-Chm1 pathway is responsible for conidiogenesis, but additional pathways, including the Nox pathway, are necessary for appressorial formation and pathogenicity
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