9,799 research outputs found

    THE APPLICATION OF CIVIL RIGHTS LAWS TO HOUSING COOPERATIVES: ARE CO-OPS BASTIONS OF DISCRIMINATORY EXCLUSION OR SELF-SELECTING MODELS OF COMMUNITY-BASED LIVING?

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    Despite one of the nation\u27s broadest civil rights laws for residents of housing cooperatives, few of New York City\u27s discrimination claims in the cooperative housing market are pursued. In this article, the authors provide an overview of the cooperative housing market in New York City, including anecdotal evidence of discrimination. Next, the article discusses the legal framework of the housing cooperative before a brief analysis of city, state and federal anti-discrimination laws applicable to cooperatives. Finally, the article undertakes an analysis of cases in which antidiscrimination laws have been applied to cooperatives. The author concludes with recommendations for cooperatives and prospective applicants

    Response versus Chain Length of Alkanethiol-Capped Au Nanoparticle Chemiresistive Chemical Vapor Sensors

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    Au nanoparticles capped with a homologous series of straight chain alkanethiols (containing 4−11 carbons in length) have been investigated as chemiresistive organic vapor sensors. The series of alkanethiols was used to elucidate the mechanisms of vapor detection by such capped nanoparticle chemiresistive films and to highlight the molecular design principles that govern enhanced detection. The thiolated Au nanoparticle chemiresistors demonstrated rapid and reversible responses to a set of test vapors (n-hexane, n-heptane, n-octane, iso-octane, cyclohexane, toluene, ethyl acetate, methanol, ethanol, isopropanol, and 1-butanol) that possessed a variety of analyte physicochemical properties. The resistance sensitivity to nonpolar and aprotic polar vapors systematically increased as the chain length of the capping reagent increased. Decreases in the nanoparticle film resistances, which produced negative values of the differential resistance response, were observed upon exposure of the sensor films to alcohol vapors. The response signals became more negative with higher alcohol vapor concentrations, producing negative values of the sensor sensitivity. Sorption data measured on Au nanoparticle chemiresistor films using a quartz crystal microbalance allowed for the measurement of the partition coefficients of test vapors in the Au nanoparticle films. This measurement assumed that analyte sorption only occurred at the organic interface and not the surface of the Au core. Such an assumption produced partition coefficient values that were independent of the length of the ligand. Furthermore, the value of the partition coefficient was used to obtain the particle-to-particle interfacial effective dielectric constant of films upon exposure to analyte vapors. The values of the dielectric constant upon exposure to alcohol vapors suggested that the observed resistance response changes observed were not significantly influenced by this dielectric change, but rather were primarily influenced by morphological changes and by changes in the interparticle spacing

    Equilibration of Concentrated Hard Sphere Fluids

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    We report a systematic molecular dynamics study of the isochoric equilibration of hard-sphere fluids in their metastable regime close to the glass transition. The thermalization process starts with the system prepared in a non-equilibrium state with the desired final volume fraction {\phi} but with a prescribed non-equilibrium static structure factor S_0(k; {\phi}). The evolution of the {\alpha}- relaxation time {\tau}{\alpha} (k) and long-time self-diffusion coefficient DL as a function of the evolution time tw is then monitored for an array of volume fractions. For a given waiting time the plot of {\tau}{\alpha} (k; {\phi}, tw) as a function of {\phi} exhibits two regimes corresponding to samples that have fully equilibrated within this waiting time ({\phi} \leq {\phi}(c) (tw)), and to samples for which equilibration is not yet complete ({\phi} \geq {\phi}(c) (tw)). The crossover volume fraction {\phi}(c) (tw) increases with tw but seems to saturate to a value {\phi}(a) \equiv {\phi}(c) (tw \rightarrow \infty) \approx 0.582. We also find that the waiting time t^(eq)_w({\phi}) required to equilibrate a system grows faster than the corresponding equilibrium relaxation time, t^(eq)({\phi}) \approx 0.27 \times [{\tau}{\alpha} (k; {\phi})]^1.43, and that both characteristic times increase strongly as {\phi} approaches {\phi}^(a), thus suggesting that the measurement of equilibrium properties at and above {\phi}(a) is experimentally impossible

    Tunneling spectroscopy of the superconducting state of URu2Si2

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    We present measurements of the superconducting gap of URu2_2Si2_2 made with scanning tunneling microscopy (STM) using a superconducting tip of Al. We find tunneling conductance curves with a finite value at the Fermi level. The density of states is V shaped at low energies, and the quasiparticle peaks are located at values close to the expected superconducting gap from weak coupling BCS theory. Our results point to rather opened gap structures and gap nodes on the Fermi surface
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