Half-life of the electron-capture decay of 97Ru: Precision measurement shows no temperature dependence

We have measured the half-life of the electron-capture (ec) decay of 97Ru in a metallic environment, both at low temperature (19K), and also at room temperature. We find the half-lives at both temperatures to be the same within 0.1%. This demonstrates that a recent claim that the ec decay half-life for 7Be changes by $0.9% +/- 0.2% under similar circumstances certainly cannot be generalized to other ec decays. Our results for the half-life of 97Ru, 2.8370(14)d at room temperature and 2.8382(14)d at 19K, are consistent with, but much more precise than, previous room-temperature measurements. In addition, we have also measured the half-lives of the beta-emitters 103Ru and 105Rh at both temperatures, and found them also to be unchanged.Comment: 6 pages, 6 figure

Double layer in ionic liquids: Overscreening vs. crowding

We develop a simple Landau-Ginzburg-type continuum theory of solvent-free ionic liquids and use it to predict the structure of the electrical double layer. The model captures overscreening from short-range correlations, dominant at small voltages, and steric constraints of finite ion sizes, which prevail at large voltages. Increasing the voltage gradually suppresses overscreening in favor of the crowding of counterions in a condensed inner layer near the electrode. The predicted ion profiles and capacitance-voltage relations are consistent with recent computer simulations and experiments on room-temperature ionic liquids, using a correlation length of order the ion size.Comment: 4 pages + supplementary informatio

Investigation of the magnetic field characteristics of Herbig Ae/Be stars: Discovery of the pre-main sequence progenitors of the magnetic Ap/Bp stars

We are investigating the magnetic characteristics of pre-main sequence Herbig Ae/Be stars, with the aim of (1) understanding the origin and evolution of magnetism in intermediate-mass stars, and (2) exploring the influence of magnetic fields on accretion, rotation and mass-loss at the early stages of evolution of A, B and O stars. We have begun by conducting 2 large surveys of Herbig Ae/Be stars, searching for direct evidence of photospheric magnetic fields via the longitudinal Zeeman effect. From observations obtained using FORS1 at the ESO-VLT and ESPaDOnS at the Canada-France-Hawaii Telescope, we report the confirmed detection of magnetic fields in 4 pre-main sequence A- and B-type stars, and the apparent (but as yet unconfirmed) detection of fields in 2 other such stars. We do not confirm the detection of magnetic fields in several stars reported by other authors to be magnetic: HD 139614, HD 144432 or HD 31649. One of the most evolved stars in the detected sample, HD 72106A, shows clear evidence of strong photospheric chemical peculiarity, whereas many of the other (less evolved) stars do not. The magnetic fields that we detect appear to have surface intensities of order 1 kG, seem to be structured on global scales, and appear in about 10% of the stars studied. Based on these properties, these magnetic stars appear to be pre-main sequence progenitors of the magnetic Ap/Bp stars.Comment: v2: Include comment regarding publication source To appear in the proceedings of "Solar Polarisation 4", held in Boulder, USA, Sept. 200

Revisiting the Rigidly Rotating Magnetosphere model for σ\sigma Ori E - II. Magnetic Doppler imaging, arbitrary field RRM, and light variability

The initial success of the Rigidly Rotating Magnetosphere (RRM) model application to the B2Vp star sigma OriE by Townsend, Owocki & Groote (2005) triggered a renewed era of observational monitoring of this archetypal object. We utilize high-resolution spectropolarimetry and the magnetic Doppler imaging (MDI) technique to simultaneously determine the magnetic configuration, which is predominately dipolar, with a polar strength Bd = 7.3-7.8 kG and a smaller non-axisymmetric quadrupolar contribution, as well as the surface distribution of abundance of He, Fe, C, and Si. We describe a revised RRM model that now accepts an arbitrary surface magnetic field configuration, with the field topology from the MDI models used as input. The resulting synthetic Ha emission and broadband photometric observations generally agree with observations, however, several features are poorly fit. To explore the possibility of a photospheric contribution to the observed photometric variability, the MDI abundance maps were used to compute a synthetic photospheric light curve to determine the effect of the surface inhomogeneities. Including the computed photospheric brightness modulation fails to improve the agreement between the observed and computed photometry. We conclude that the discrepancies cannot be explained as an effect of inhomogeneous surface abundance. Analysis of the UV light variability shows good agreement between observed variability and computed light curves, supporting the accuracy of the photospheric light variation calculation. We thus conclude that significant additional physics is necessary for the RRM model to acceptably reproduce observations of not only sigma Ori E, but also other similar stars with significant stellar wind-magnetic field interactions.Comment: 16 pages, 17 figures, accepted for publication in MNRA

Magnetism in pre-MS intermediate-mass stars and the fossil field hypothesis

Today, one of the greatest challenges concerning the Ap/Bp stars is to understand the origin of their slow rotation and their magnetic fields. The favoured hypothesis for the latter is the fossil field, which implies that the magnetic fields subsist throughout the different evolutionary phases, and in particular during the pre-main sequence phase. The existence of magnetic fields at the pre-main sequence phase is also required to explain the slow rotation of Ap/Bp stars. However, until recently, essentially no information was available about the magnetic properties of intermediate-mass pre-main sequence stars, the so-called Herbig Ae/Be stars. The new high-resolution spectropolarimeter ESPaDOnS, installed in 2005 at the Canada-France-Hawaii telescope, provided the capability necessary to perform surveys of the Herbig Ae/Be stars in order to investigate their magnetism and rotation. These investigations have resulted in the detection and/or confirmation of magnetic fields in 8 Herbig Ae/Be stars, ranging in mass from 2 to nearly 15 solar masses. In this contribution I will present the results of our survey, as well as their implications for the origin and evolution of the magnetic fields and rotation.Comment: Proceedings of the CP#AP Workshop held in Vienna in September 200

Electrochemical Oxidation and Sensing of Methylamine Gas in Room Temperature Ionic Liquids

The electrochemical behaviour of methylamine gas in several room temperature ionic liquids (RTILs), [C2mim][NTf2], [C4mim][NTf2], [C6mim][FAP], [C4mpyrr][NTf2], [C4mim][BF4], and [C4mim][PF6] has been investigated on a Pt microelectrode using cyclic voltammetry. A broad oxidation wave at approximately 3 V, two reduction peaks and another oxidation peak was observed. A complicated mechanism is predicted based on the voltammetry obtained, with ammonia gas as a likely by-product. The currents obtained suggest that methylamine has a high solubility in RTILs, which is important for gas sensing applications. The analytical utility of methylamine was then studied in [C4mpyrr][NTf2] and [C2mim][NTf2]. A linear calibration graph with an R2 value of 0.99 and limits of detection of 33 and 34 ppm were obtained respectively, suggesting that RTILs are favourable non-volatile solvents for the electrochemical detection of highly toxic methylamine gas

Colloquium: The transport properties of graphene: An introduction

An introduction to the transport properties of graphene combining experimental results and theoretical analysis is presented. In the theoretical description simple intuitive models are used to illustrate important points on the transport properties of graphene. The concept of chirality, stemming from the massless Dirac nature of the low energy physics of the material, is shown to be instrumental in understanding its transport properties: the conductivity minimum, the electronic mobility, the effect of strain, the weak (anti-)localization, and the optical conductivity.Comment: As publishe