Parameters affecting ion intensities in transmission-mode Direct Analysis in Real-Time mass spectrometry

A survey of the effect of temperature, transmission module material and analysis time on ion intensities in transmission mode direct analysis in real time mass spectrometry is presented. Ion intensity profiles obtained for two related compounds are similar when analysed separately but are very different when analysed as a mixture

Plasma Jet-Substrate Interaction in Low Pressure Plasma Spray-CVD Processes

Conventional equipment for plasma spraying can be adapted for operation at low pressure so that PECVD-like processing can be performed. The plasma jet generated by the torch is characterized by a high convective velocity and a high gas temperature. The influence of these properties on a deposition process are investigated in the framework of simple theoretical considerations and illustrated by various experimental results obtained with SiO x deposition. A conclusion of this study is that the deposition process is dominated by diffusion effects on the substrate surface: the deposition profiles and the deposition rates are determined by the precursor density and by the gas temperature on the substrate surface. The high velocity of the jet does not play a direct role in the deposition mechanism. On the other hand it strongly increases the precursor density available for the deposition since it efficiently transports the precursor up to the substrat

FIREBALL: Instrument pointing and aspect reconstruction

The Faint Intergalactic Redshifted Emission Balloon (FIREBALL) had its first scientific flight in June 2009. The instrument is a 1 meter class balloon-borne telescope equipped with a vacuum-ultraviolet integral field spectrograph intended to detect emission from the inter-galactic medium at redshifts 0.3 < z < 1.0. The scientific goals and the challenging environment place strict constraints on the pointing and tracking systems of the gondola. In this manuscript we briefly review our pointing requirements, discuss the methods and solutions used to meet those requirements, and present the aspect reconstruction results from the first successful scientific flight

Fireball Multi Object Spectrograph: As-built optic performances

Fireball (Faint Intergalactic Redshifted Emission Balloon) is a NASA/CNES balloon-borne experiment to study the faint diffuse circumgalactic medium from the line emissions in the ultraviolet (200 nm) above 37 km flight altitude. Fireball relies on a Multi Object Spectrograph (MOS) that takes full advantage of the new high QE, low noise 13 μm pixels UV EMCCD. The MOS is fed by a 1 meter diameter parabola with an extended field (1000 arcmin2) using a highly aspherized two mirror corrector. All the optical train is working at F/2.5 to maintain a high signal to noise ratio. The spectrograph (R~ 2200 and 1.5 arcsec FWHM) is based on two identical Schmidt systems acting as collimator and camera sharing a 2400 g/mm aspherized reflective Schmidt grating. This grating is manufactured from active optics methods by double replication technique of a metal deformable matrix whose active clear aperture is built-in to a rigid elliptical contour. The payload and gondola are presently under integration at LAM. We will present the alignment procedure and the as-built optic performances of the Fireball instrument

Fission widths of hot nuclei from Langevin dynamics

Fission dynamics of excited nuclei is studied in the framework of Langevin equation. The one body wall-and-window friction is used as the dissipative force in the Langevin equation. In addition to the usual wall formula friction, the chaos weighted wall formula developed earlier to account for nonintegrability of single-particle motion within the nuclear volume is also considered here. The fission rate calculated with the chaos weighted wall formula is found to be faster by about a factor of two than that obtained with the usual wall friction. The systematic dependence of fission width on temperature and spin of the fissioning nucleus is investigated and a simple parametric form of fission width is obtained.Comment: RevTex, 12 pages including 9 Postscript figure

Modeling of mode-locking in a laser with spatially separate gain media

We present a novel laser mode-locking scheme and discuss its unusual properties and feasibility using a theoretical model. A large set of single-frequency continuous-wave lasers oscillate by amplification in spatially separated gain media. They are mutually phase-locked by nonlinear feedback from a common saturable absorber. As a result, ultra short pulses are generated. The new scheme offers three significant benefits: the light that is amplified in each medium is continuous wave, thereby avoiding issues related to group velocity dispersion and nonlinear effects that can perturb the pulse shape. The set of frequencies on which the laser oscillates, and therefore the pulse repetition rate, is controlled by the geometry of resonator-internal optical elements, not by the cavity length. Finally, the bandwidth of the laser can be controlled by switching gain modules on and off. This scheme offers a route to mode-locked lasers with high average output power, repetition rates that can be scaled into the THz range, and a bandwidth that can be dynamically controlled. The approach is particularly suited for implementation using semiconductor diode laser arrays.Comment: 13 pages, 5 figures, submitted to Optics Expres

The Nature and Purpose of Acute Psychiatric Wards: The Tompkins Acute Ward Study

Background: Acute inpatient care in the UK is being subjected to increasing critical scrutiny, highlighting concerns about content and quality. There is an absence of clarity and consensus on what acute inpatient care is for, adding to difficulties in developing this service sector. Aim: To define the function of acute psychiatric wards. Methods: Interviews were conducted with multidisciplinary staff (13 Ward Managers, 14 F Grade nurses, 11 Occupational Therapists and 9 Consultant Psychiatrists), on rationales for admission, their care and treatment philosophy, and the roles of different professionals. Results: Patients are admitted because they appear likely to harm themselves or others, and because they are suffering from a severe mental illness, and/or because they or their family/community require respite, and/or because they have insufficient support and supervision available to them in the community. The tasks of acute inpatient care are to keep patients safe, assess their problems, treat their mental illness, meet their basic care needs and provide physical healthcare. These tasks are completed via containment, 24-hour staff presence, treatment provision, and complex organisation and management. Conclusions: Professional education, audit, research and the structuring of services all need to be oriented towards these tasks. Declaration of interest: This study was funded by the Tompkins Foundation and the Department of Health Nursing Quality initiative

Towards wafer-scale integration of high repetition rate passively mode-locked surface-emitting semiconductor lasers

One of the most application-relevant milestones that remain to be achieved in the field of passively mode-locked surface-emitting semiconductor lasers is the integration of the semiconductor absorber into the gain structure, enabling the realization of ultra-compact high-repetition-rate laser devices suitable for wafer-scale integration. We have recently succeeded in fabricating the key element in this concept, a quantum-dot-based saturable absorber with a very low saturation fluence, which for the first time allows stable mode locking of surface-emitting semiconductor lasers with the same mode areas on gain and absorber. Experimental results at high repetition rates of up to 30GHz are show

Supersymmetric D-branes and calibrations on general N=1 backgrounds

We study the conditions to have supersymmetric D-branes on general {\cal N}=1 backgrounds with Ramond-Ramond fluxes. These conditions can be written in terms of the two pure spinors associated to the SU(3)\times SU(3) structure on T_M\oplus T^\star_M, and can be split into two parts each involving a different pure spinor. The first involves the integrable pure spinor and requires the D-brane to wrap a generalised complex submanifold with respect to the generalised complex structure associated to it. The second contains the non-integrable pure spinor and is related to the stability of the brane. The two conditions can be rephrased as a generalised calibration condition for the brane. The results preserve the generalised mirror symmetry relating the type IIA and IIB backgrounds considered, giving further evidence for this duality.Comment: 23 pages. Some improvements and clarifications, typos corrected and references added. v3: Version published in JHE