Effect of dairy effluents pre-treatment on N2O emissions and N-organic degradation after soil application

Nitrous oxide (N2O) is a potent greenhouse gas that plays a key role in climatic forcing contributing to the greenhouse effect by about 4 %, and also contributes to stratospheric ozone depletion. Cattle slurries are commonly applied to agricultural soils, inducing an increase of soil nitrous oxide emissions. Therefore, many procedures were developed for slurry pre-treatment in order to improve soil slurry application and reduce nitrogen losses, namely N2O emissions. The aim of this work was to compare N2O emissions and the kinetic of N organic degradation from treated and untreated cattle-slurry after its incorporation in agricultural soils

Separação de sólidos e nutrientes com PAM e bentonite em chorumes bovinos

A separação de sólidos do chorume e a aplicação de agentes floculantes à fracção líquida obtida constituem processos de tratamento deste efluente pecuário que permitem a obtenção de materiais com características distintas que ampliam as opções de utilização e de gestão do chorume. A redução do teor de sólidos e nutrientes na fracção sobrenadante apresenta vantagens em termos de odores, armazenamento, tratamento, aplicação aos solos e irrigação. Este trabalho teve como objectivo avaliar a utilização dos agentes floculantes poliacrilamida (PAM) e bentonite na remoção de sólidos e nutrientes da fracção líquida do chorume de explorações de bovinicultura leiteira. O trabalho experimental decorreu em Vila do Conde durante 2004, numa exploração de bovinicultura leiteira intensiva. O chorume bruto foi sujeito a separação mecânica de sólidos. Posteriormente a fracção líquida obtida foi bombeada para recipientes, e definiram-se 3 tratamentos com 2 repetições: controlo, adição de 200 mg L -1 de PAM e adição de 2 g L -1 de bentonite. Após a aplicação dos floculantes foram recolhidas amostras às fracções sobrenadante e sedimentada nos tempos 0, 2, 4, 20 e 30 horas. Essas amostras foram analisadas relativamente à concentração de N Kjeldahl, P e K totais, N-NH4 + , P solúvel em água, C orgânico solúvel em água, valor de pH e %MS. A separação mecânica do chorume bruto conduziu a uma eficiência de remoção pela fracção sólida obtida de 22, 25, 44 e 21%, respectivamente, dos teores de N Kjeldahl, P total, P solúvel em água e MS. Quanto à capacidade de remoção dos floculantes, a aplicação de PAM conduziu à eficiência de remoção da fracção sobrenadante de 46, 40, 65, 57 e 40%, respectivamente para o N Kjeldahl, P e K totais, P solúvel em água e MS; e a aplicação de bentonite a remoções de 19, 21, 11, 16 e 12%

Impact of cattle slurry treatment by separation and acidification on gaseous emissions after soil application

Objectives: Cattle-slurry management became a priority in many livestock farms and slurry treatment is used to increase the fertilizer value of slurry and/or minimize its environmental impact. Indeed, significant emissions of ammonia (NH3) and greenhouse gases (GHG) as nitrous oxide (N2O), carbon dioxide (CO2) and methane (CH4) can occur during and after slurry application to soil. Application of acidified slurry or liquid fraction (LF) obtained by solid-liquid separation are two alternatives to raw slurry application that have proven to be efficient to minimize ammonia emissions. However, few is known about its effect on GHG emissions. The aim of the present work was to assess the efficiency of cattle slurry treatment by acidification and/or solid liquid separation to mitigate ammonia (NH3) and greenhouse gases (GHG) emissions following surface application to a sandy loam soil

Development of weft-knitted and braided polypropylene stents for arterial implant

Textile biomedical materials have been used for various applications contributing considerably in improving quality of life. The current study aims at improving polypropylene fibre stents which may replace metallic ones. In order to produce the stents, weft-knitting and braiding technologies were used. In the braiding technique, by varying the takeup ratio (using gears with the appropriate number of teeth in the braiding machine), it was possible to manufacture regular braids with angles of 65 ° , 70 ° and 75 ° in order to obtain different covers. In the knitting technique, a circular machine was used and the tightness of the structure was adjusted by varying the loop length and thus the fabric loop density, resulting in variations of the sample diameter. The knitting machine had negative feed, and so loop length variations were achieved by varying the yarn input tension, the stitch cam settings and the fabric take-down tension. The samples were heat set. Yarns were contracted by setting at 130 ° C and 140 ° C, and this led to increasing the loop density and the flexural rigidity of the samples. A high cover of the samples resulted in a greater stiffness of the structures. The stents were evaluated by undertaking the tests required for arterial support: rigidity to radial compression, resistance to tensile forces and bending rigidity. The best results were obtained with braided structures. Future work may concentrate in improving the stent design and using new biocompatible fibres.The authors wish to thank the European Commission for awarding research funds under the EU Asia-link programme and the University of Minho (Portugal) and Donghua University (People's Republic of China) for providing research facilities

Study of the potential employment of Malvaceae Species in composites materials

The employ of vegetal fibers for textiles and composites represents a great potential in economic and social sustainable development. Some Malvaceae species are considered tropical cosmopolitans, such as from Sida genus. Several species of this genus provide excellent textile bast fibers, which are very similar in qualities to the jute textile fiber. The objective of the present study is present the physicochemical characterization of six Brazilian vegetal fibers: Sida rhombifolia L.; Sida carpinifolia L. f.; Sidastrum paniculatum (L.) Fryxell; Sida cordifolia L.; Malvastrum coromandelianum (L.) Gurck; Wissadula subpeltata (Kuntze) R.E.Fries. Respectively the two first species are from Brazilian Atlantic Forest biome and the four remaining from Brazilian Cerrado biome, despite of present in other regions of the planet. The stems of these species were retted in water at 37oC for 20 days. The fibers were tested in order to determine tensile rupture strength, tenacity, elongation, Young’s modulus, cross microscopic structure, Scanning Electronic Microscopy (SEM), regain, combustion, acid, alkali, organic solvent and cellulase effects, pH of the aqueous extract, Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TGA). The obtained values were compared with those from fibers of recognized applicability in the textile industry including hemp. The results are promising in terms of their employment in thermoset and thermoplastic medium resistance composites.FAPESP (“Fundação de Amparo à Pesquisa do Estado de São Paulo”), CAPES (Coordenação de Aperfeiçoamento de Pessoal de Nível Superior) and CNPq (“Conselho Nacional de Desenvolvimento Científico e Tecnológico”) are gratefully acknowledged. The authors would also like to thank Mr. Ervin Sriubas Jr. and Kellinton José Mendonça Francisco for their technical support

Effect of the pig slurry separation techniques on the characteristics and potential availability of N to plants in the resulting liquid and solid fractions

Solid-liquid separation of slurry is used to obtain a solid (SF) and liquid fraction (LF), both used as organic fertilisers. Previous works showed that the separation technique used influences the composition of the resulting SF but no data are available relative to the LF. Four commonly used separation processes were considered e centrifugation, sieving, enhanced settling by the addition of cationic polyacrylamide (PAM-), and sediment settling as well as a recent sequential process e sieving followed by PAM addition to the resulting LF. The resulting LFs and SFs were comprehensively characterised and the amount of N potentially available for plants after incorporation to soil was also evaluated. Except for slurry that was only sieved which was very similar in composition to whole slurry (WS), the SFs and LFs had, respectively, higher and lower, concentrations of nutrients and organic matter (OM) than the WS. The ratio of ammoniacal to total N in the LFs varied from 0.33 to 0.92 whereas the values in the SFs varied between 0.16 and 0.31. The N:P:K ratio was also significantly influenced by the separation technique. Less than 10% of the total N applied in the WS, SFs or LFs was found to be potentially available for plants and, in some LFs, N immobilisation occurred after soil application. Since separation technique strongly influences nutrient distribution between LF and SF, as well as N speciation, the choice of the technique has to consider the final use of the resulting fractions as well as acquisition and operating costs

Quantification of priming and CO2 emission sources following the application of different slurry particle size fractions to a grassland soil

The highest emissions of CO2 from soils and most pronounced priming effect (PE) from soils generally occur immediately after slurry application. However, the influence of different particle size slurry fractions on net soil C respiration dynamics and PE has not been studied. Therefore, a slurry separation technique based on particle sizes was used in the present study. Six distinct fractions (>2000, 425–2000, 250–425, 150–250, 45–150, 250 μm fractions. The overall contribution of slurry C to total CO2 emissions was higher in smaller slurry particle size treatments in the first days after application. The addition of the various slurry fractions to soil caused both significant positive and negative PEs on the soil organic matter mineralization. The timing and type (positive or negative) of PE depended on the slurry particle size. Clearly, farm based separation pre-treatment leading to two or more fractions with different particle sizes has also the potential to reduce or modify short-term CO2 emissions immediately after slurry application to soil

Assessment of CO2 emissions during acidification, storage and after incorporation to soil of pig slurry

RAMIRAN International ConferenceLarge amounts of pig slurry are produced each year in Portugal leading to environmental problems such as water and air pollution. Previous studies have reported that livestock production is the main source of anthropogenic ammonia (NH3) emissions in Europe (Kai et al., 2008) and an important source of greenhouse gases (Weiske and Petersen, 2006). Effluent treatment has been promoted to improve slurry management and to reduce its environmental impact (Sommer and Hutchings, 2001, Fangueiro et al., 2008a). Solid-liquid separation of slurry is a useful tool at the farm level producing valuable fractions, a liquid that can be used for direct fertilisation and a solid fraction that can be composted (Fangueiro et al., 2008b). Alternatively, acidification of slurry has been proposed to reduce ammonia (NH3) emissions during storage and field application (Kai et al., 2008). Previous works (Misselbrook et al., 2005; Fangueiro et al., 2008a) reported that higher NH3 emissions occurred during storage of liquid fraction of slurry or manure with low dry matter content, probably due to a reduced crust formation that decreases NH3 emissions. Hence, acidification of the liquid fraction of slurry is strongly recommended. Slurry acidification is common practice in The Netherlands and Denmark (Schils et al., 1999; Eriksen et al., 2008) but this technology still needs to be improved to avoid hazards. It is expected that this technology will be used in more countries since the European Directive (2001/81/CE) demands a decrease of atmospheric pollutants such as NH3: targets for lower NH3 emissions have been already set in Spain (Castrillon et al., 2009). Nevertheless, the acidification process leads to significant carbon dioxide (CO2) emissions (Vandré and Clemens, 1997). Such CO2 release is problematic when a closed system of slurry acidification is used (when acidified slurry is flushed back to pig houses) since it may lead to foam formation (Vandré and Clemens, 1997; Borst, 2001). Nevertheless, Fangueiro et al. (2010) reported that acidification of slurry or derived fractions led to a decrease in CO2 emissions following soil addition relative to non acidified materials. The aim of the present work was to measure the CO2 emissions during the acidification process of the liquid fraction of pig slurry and its subsequent impact during storage and after soil incorporation

Carbon and nitrogen mineralization of organic wastes from sugarcane distilleries: vinasse and yeast waste

RAMIRAN International ConferenceIn Madeira Island (Portugal) significant amounts of wastes are generated in sugarcane distilleries, namely vinasse (the remaining fermented must after distillation) and yeast waste (the yeast surplus produced during the alcoholic fermentation). These wastes have high organic loads and low pH, leading to serious environmental problems when released directly into natural watercourses or when poorly managed (Hati et al., 2007). As a solution to avoid expensive treatments, both wastes have been used as soil amendment, since they contain important amounts of plant nutrients and organic matter (Resende et al., 2006; Parnaudeau et al., 2008). Indeed, application to soils of vinasse is a common practice in sugarcane cultivated areas and can fully substitute K and partially P on crops fertilization. Nevertheless, additional mineral nitrogen fertilization is needed when vinasse is spread in the soils (Junior et al., 2007; Oliveira et al., 2009). On the other hand, yeast waste has been considered as an excellent potential source of nitrogen for plant nutrition when applied to soils (Rezende et al., 2004). Thus, combined application of both wastes should ensure a more balanced supply of nutrients to plants. However, scarce information is available on the combine use of both wastes as fertilizer. The main objective of this study is to assess the effect of the combined application to soil of both organic materials (vinasse and yeast waste), and to evaluate its subsequent effects on nitrogen mineralization/immobilization process to supply nitrogen to crops and to preserve/restore soil carbon

Influence of two nitrification inhibitors (DCD and DMPP) on annual ryegrass yield and soil mineral N dynamics after incorporation with cattle slurry

Nitrogen (N) losses through nitrate leaching, occurring after slurry spreading, can be reduced by the use of nitrification inhibitors (NIs) such as dicyandiamide (DCD) and 3,4-dimethyl pyrazole phosphate (DMPP). In the present work, the effects of DCD and DMPP, applied at two rates with cattle slurry, on soil mineral N profiles, annual ryegrass yield, and N uptake were compared under similar pedoclimatic conditions. Both NIs delayed the nitrate formation in soil; however, DMPP ensured that the soil mineral N was predominantly in the ammonium form rather than in the nitrate form for about 100 days, whereas with DCD such effect was observed only during the first 40 days after sowing. Furthermore, the use of NIs led to an increase of the drymatter (DM) yields in a range of 32–54% and of the forage N removal in a range of 34–68% relative to the slurry-only (SO) treatment (without NIs). A DM yield of 8698 kg ha21 was obtained with the DMPP applied at the greater rate against only 7444 kg ha21 obtained with the greater rate of DCD (4767 kg ha21 in the SO treatment). Therefore, it can be concluded that DMPP is more efficient as an NI than DCD when combined with cattle slurr