Tuneable photoconductivity and mobility enhancement in printed MoS 2 /graphene composites

This is the author accepted manuscript. The final version is available from IOP Publishing via the DOI in this record.With the aim of increasing carrier mobility in nanosheet-network devices, we have investigated MoS2–graphene composites as active regions in printed photodetectors. Combining liquid exfoliation and inkjet-printing, we fabricated all-printed photodetectors with graphene electrodes and MoS2–graphene composite channels with various graphene mass fractions (0  ≤  M f  ≤  16 wt%). The increase in channel dark conductivity with M f was consistent with percolation theory for composites below the percolation threshold. While the photoconductivity increased with graphene content, it did so more slowly than the dark conductivity, such that the fractional photoconductivity decayed rapidly with increasing M f. We propose that both mobility and dark carrier density increase with graphene content according to percolation-like scaling laws, while photo-induced carrier density is essentially independent of graphene loading. This leads to percolation-like scaling laws for both photoconductivity and fractional photoconductivity—in excellent agreement with the data. These results imply that channel mobility and carrier density increase up to 100-fold with the addition of 16 wt% graphene.We acknowledge the Science Foundation Ireland (SFI/12/RC/2278), the European Commission (n° 696656, Graphene Flagship) and the European Research Council (FUTURE-PRINT)

Magnetic fabrics and microstructures of the Jurassic Shah-Kuh granite pluton (Lut Block, Eastern Iran) and geodynamic inference

International audienceThe Jurassic Shah-Kuh granite pluton was emplaced in the northeastern part of the Lut Block (Eastern Iran) while this block was a part of the active margin under which the Tethys ocean, that separated Arabia from Central Iran, was subducting. Since this time, the Lut Block has rotated and migrated northward up to its present position. This structural study of the Shah-Kuh aims at strengthening the evidence of its original geodynamical location. Thanks to a systematic collection of oriented samples in the field, well-defined fabric and microstructural patterns were deduced from magnetic fabric measurements and optical microscopy observations. The overall magnetic fabric of the pluton yields vertical, north south striking foliations and shallow lineations plunging to the north. The corresponding microstructures attest to their formation in the magmatic stage, i.e. during emplacement. Subsequent deformation, characterized by (sub)mylonitic microstructures, has modified the original fabric into a northwest and locally a west northwest trend inside a two kilometre-wide corridor. This corridor reflects the trace of a sinistral shear zone that offsets the previous north south magmatic pattern of the pluton. The latter magmatic pattern is proposed to result from the shear component of strain that was parallel to the ancient active margin during pluton emplacement, as a result of strain partitioning, a situation frequently documented at convergent margins. Sinistral shear along an ? E W directed south-facing active margin, assuming a northeastward slip vector for the Tethys ocean during the Jurassic, and accepting a ? 150° counterclockwise rotation of the Lut Block after emplacement of the Shah-Kuh pluton, best explains both the magmatic and the solid-state lineation patterns

Petrology of the Jurassic Shah-Kuh granite (eastern Iran), with reference to tin mineralization

The Shah-Kuh granitic pluton of eastern Central Iran was emplaced 165 Ma ago, in an active continental margin setting. It is made of two main units: a granodioritic unit (SiO2=63–71 wt%) to the north–west and a syenogranitic unit (SiO2=73–77 wt%) to the south–east. The former unit displays seriate medium-grained textures and contains locally abundant mafic enclaves. The latter unit is medium- to coarse-grained and porphyritic, with 0.5–3 cm long K-feldspar megacrysts. Fine-grained granitic bodies are present in both units. The rocks are metaluminous to slightly peraluminous (I-type) and peraluminous (S-type) and belong to the ilmenite-series granites. Fractional crystallization appears to have been a very effective differentiation process in both units, and the fractionated mineral assemblages are determined by mass balance calculations. Isotopic data (Sri=0.7065 and εNdt=−2.5) are consistent with a young upper crustal protolith. Tin mineralization in sheeted quartz-tourmaline (-cassiterite) veins is spatially associated with the granodioritic unit. The veins formed by hydraulic fracturing when the granodioritic to monzogranitic magma became water-saturated and exsolved a fluid phase during crystallization. The reduced nature of this magma is responsible for the incompatible behaviour of Sn, likely to favour Sn concentration in the residual melt and then in the exsolved fluid. Another fluid phase was exsolved by the syenogranitic magma and was responsible for local greisenized granites, characterized by high Y and HREE-contents and non-fractionated REE distribution patterns. Field and mineralogical data show that the (B, Sn) vein-forming fluid was different from the (F, Li) greisen-forming fluid

Historical tsunami in the Makran Subduction Zone off the southern coasts of Iran and Pakistan and results of numerical modeling

Tsunami hazard in the Makran Subduction Zone (MSZ), off the southern coasts of Iran and Pakistan, was studied by numerical modeling of historical tsunami in this region. Although the MSZ triggered the second deadliest tsunami in the Indian Ocean, among those known, the tsunami hazard in this region has yet to be analyzed in detail. This paper reports the results of a risk analysis using five scenario events based on the historic records, and identifies a seismic gap area in western Makran off the southern coast of Iran. This is a possible site for a future large earthquake and tsunami. In addition, we performed numerical modeling to explain some ambiguities in the historical reports. Based on the modeling results, we conclude that either the extreme run-up of 12-15 m assigned for the 1945 Makran tsunami in the historical record was produced by a submarine landslide triggered by the parent earthquake, or that these reports are exaggerated. The other possibility could be the generation of the huge run-up heights by large displacements on splay faults. The results of run-up modeling reveal that a large earthquake and tsunami in the MSZ is capable of producing considerable run-up heights in the far field. Therefore, it is possible that the MSZ was the source of the tsunami encountered by a Portuguese fleet in Dabhul in 1524