10,898 research outputs found
Titanium-Oxygen Bond Length -Bond Valence Relationship
A bond length–bond valence correlation is a simple method of checking and evaluating molecular structures and is of great interest in chemistry, biology, geology, and material science. Recently, we used quantum-mechanical arguments to derive Pauling’s bond length-valence relationship and to define the adjustable fitting parameter b in terms of atomic-orbital exponents. Improved orbital exponents were generated for elements 1-103 using published atomic radii and single-bond covalent radii as well as a continuous function for effective principal quantum number. In this study, we use orbital exponents for titanium (Ti) and oxygen (O) to generate a bond length-valence relationship for Ti-O bonds. Recent crystallographic Ti-O bond lengths from 32 environments were collected and converted to Ti-O bond valences to check the reliability of the bond length-valence relationship where Ro was found (bond length of unit valence). This relationship is expected to apply to any Ti-O bond regardless of environment, physical state, or oxidation number
Seasonal trends in response to inoculation of coast live oak with Phytophthora ramorum
We developed a branch cutting inoculation method to provide a controlled system for studying variation in response to inoculation of coast live oak (Quercus agrifolia) with Phytophthora ramorum. This method has advantages over inoculations of trees in the field, in containing the inoculum and in allowing high levels of replication and the possibility of time series of responses. We previously reported significant tree-to-tree variation, with little population variation in lesion size using this method (Dodd and others 2005). Here we report on a time series in which branch cuttings were collected from the same trees at eight dates through a full year cycle. Branch cuttings were sampled from 33 trees from two sites at China Camp in Marin County, California, including 18 trees from one site that had suffered heavy mortality from this disease (Miwok Meadows) and 15 trees from a second site that has had little infection (Chicken Coop Island)
The Southern Vilnius Photometric System. IV. The E Regions Standard Stars
This paper is the fourth in a series on the extension of the Vilnius
photometric system to the southern hemisphere. Observations were made of 60
stars in the Harvard Standard E regions to increase a set of standard stars.Comment: 6 pages, TeX, requires 2 macros (baltic2.tex, baltic4.tex) included
no figures, to be published in Baltic Astronomy, Vol 6, pp1-6 (1997
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