Thermal to Nonthermal Energy Partition at the Early Rise Phase of Solar Flares

In some flares the thermal component appears much earlier than the nonthermal component in X-ray range. Using sensitive microwave observations we revisit this finding made by Battaglia et al. (2009) based on RHESSI data analysis. We have found that nonthermal microwave emission produced by accelerated electrons with energy of at least several hundred keV, appears as early as the thermal soft X-ray emission indicative that the electron acceleration takes place at the very early flare phase. The non-detection of the hard X-rays at that early stage of the flares is, thus, an artifact of a limited RHESSI sensitivity. In all considered events, the microwave emission intensity increases at the early flare phase. We found that either thermal or nonthermal gyrosynchrotron emission can dominate the low-frequency part of the microwave spectrum below the spectral peak occurring at 3-10 GHz. In contrast, the high-frequency optically thin part of the spectrum is always formed by the nonthermal, accelerated electron component, whose power-law energy spectrum can extend up to a few MeV at this early flare stage. This means that even though the total number of accelerated electrons is small at this stage, their nonthermal spectrum is fully developed. This implies that an acceleration process of available seed particles is fully operational. While, creation of this seed population (the process commonly called `injection' of the particles from the thermal pool into acceleration) has a rather low efficiency at this stage, although, the plasma heating efficiency is high. This imbalance between the heating and acceleration (in favor of the heating) is difficult to reconcile within most of available flare energization models. Being reminiscent of the tradeoff between the Joule heating and runaway electron acceleration, it puts additional constraints on the electron injection into the acceleration process.Comment: 11 pages, 12 figures, accepted for Ap

Modeling heat transfer from quench protection heaters to superconducting cables in Nb3Sn magnets

We use a recently developed quench protection heater modeling tool for an analysis of heater delays in superconducting high-field Nb3Sn accelerator magnets. The results suggest that the calculated delays are consistent with experimental data, and show how the heater delay depends on the main heater design parameters.Comment: 8 pages, Contribution to WAMSDO 2013: Workshop on Accelerator Magnet, Superconductor, Design and Optimization; 15 - 16 Jan 2013, CERN, Geneva, Switzerlan

Heterogeneous Reductive Isomerization Reaction Using Catalytic Pd/C and H_2

A highly selective catalytic reductive isomerization reaction is described. The extremely mild and neutral reaction conditions (10% Pd/C, H_2, and MeOH at 0 °C) tolerate a wide range of functional groups and generally result in excellent yields. Mechanistic studies suggest that this reaction does not proceed via a stepwise reduction/elimination sequence or a π-allylpalladium intermediate

The Total Synthesis of (+)-Dragmacidin F

The first total synthesis of (+)-dragmacidin F has been accomplished, establishing the absolute configuration of this biologically important, antiviral marine alkaloid. The convergent route described features a palladium-mediated oxidative pyrrole carbocylization reaction to construct the [3.3.1] bicycle, as well as a highly selective Suzuki coupling to build the carbon skeleton of the natural product. A late-stage Neber rearrangement allows for the facile installation of the aminoimidazole moiety to provide (+)-dragmacidin F

Development of an Enantiodivergent Strategy for the Total Synthesis of (+)- and (−)-Dragmacidin F from a Single Enantiomer of Quinic Acid

An enantiodivergent strategy for the total chemical synthesis of both (+)- and (−)-dragmacidin F beginning from a single enantiomer of quinic acid has been developed and successfully implemented. Although unique, the synthetic routes to these antipodes share a number of key features, including novel reductive isomerization reactions, Pd(II)-mediated oxidative carbocyclization reactions, halogen-selective Suzuki couplings, and high-yielding late-stage Neber rearrangements

The normalization of sibling violence: Does gender and personal experience of violence influence perceptions of physical assault against siblings?

Despite its pervasive and detrimental nature, sibling violence (SV) remains marginalized as a harmless and inconsequential form of familial aggression. The present study investigates the extent to which perceptions of SV differ from those of other types of interpersonal violence. A total of 605 respondents (197 males, 408 females) read one of four hypothetical physical assault scenarios that varied according to perpetrator–victim relationship type (i.e., sibling vs. dating partner vs. peer vs. stranger) before completing a series of 24 attribution items. Respondents also reported on their own experiences of interpersonal violence during childhood. Exploratory factor analysis reduced 23 attribution items to three internally reliable factors reflecting perceived assault severity, victim culpability, and victim resistance ratings. A 4 × 2 MANCOVA—controlling for respondent age—revealed several significant effects. Overall, males deemed the assault less severe and the victim more culpable than did females. In addition, the sibling assault was deemed less severe compared to assault on either a dating partner or a stranger, with the victim of SV rated just as culpable as the victim of dating, peer, or stranger-perpetrated violence. Finally, respondents with more (frequent) experiences of childhood SV victimization perceived the hypothetical SV assault as being less severe, and victim more culpable, than respondents with no SV victimization. Results are discussed in the context of SV normalization. Methodological limitations and applications for current findings are also outlined