Cap-and-trade of water rights: A sustainable way out of Australia's rural water problems?

Trading water rights is a tool for re-allocation of water resources in water-scarce regions such as Australia. Tradable water rights help farmers to act flexibly when facing high fluctuations in water availability and to use the water in a sustainable and environmentally friendly manner. A precondition is that the quantity of water rights is capped at an appropriate level. The institutional arrangements and market structures in which water-right trading is embedded are key factors for the success of such water management instruments. By analysing the structure of the water-right market and water caps as well as using results from explorative expert interviews, the article sheds light on potential problems with the Australian cap-and-trade scheme concerning sustainable water usage. It also asks whether the Australian scheme provides lessons to be learnt by other countries facing similar problems

The infuence of glycosidic linkage neighbors on disaccharide conformation in vacuum

Correct description of the free energy of conformation change of disaccharides is important in understanding a variety of biochemical processes and, ultimately, in the manufacture of better food and paper products. In this study, we determine the relative free energy of a series of 12 disaccharides in vacuum using replica exchange molecular dynamics (repMD) simulations. The chosen sugars and the novel application of this method allow the exploration of the role of glycosidic linkage neighbors in conformer stabilization. In line with expectations, we find that hydrogen bonding (and therefore energetically preferred conformations) are determined both by the nature of the glycosidic linkage (i.e., 1 f 2, 1 f 3, or 1 f 4), the C1 epimer of the of the nonreducing monosaccharide, and by the configuration of carbon atoms once removed from the glycosidic linkage. Contrary to suggestions by prior authors for repMD more generally, we also demonstrate that repMD provides enhanced sampling, relative to conventional MD simulations of equivalent length, for disaccharides in vacuum at 300 K.Fundação para a Ciência e a Tecnologia (FCT)SFRH/BPD/20555/2004/0GVLNational Science Foundation under Grant CHE-043132

The solar greenhouse : a highly insulated greenhouse design with an inflated roof system with PVDF or ETFE membranes

In a co-operation project of Wageningen University (Wageningen UR), Agrotechnology & Food Innovations B.V. (A&F), Priva Hortimation B.V. and Hyplast N.V. (Belgium) a greenhouse for the future has been developed. The project has four lines, namely 1. lowering the energy demand, 2. using solar energy for heating (greenhouse as solar collector), 3. modifying climate control and dehumidification and 4. developing of the highly insulated greenhouse. This paper deals with the development of the so-called Solar Greenhouse, the structure and cladding material and the (natural) ventilation openings. The aspects that play an important role in the process of development of the greenhouse are the strength of the structure, the light transmittance, the material consumption and the expected greenhouse climate. The high demands for energy savings lead to a greenhouse covering with a high insulation value and at the same time a high light transmittance. Advanced materials like fluor polymer films in double or more layers with the space in between inflated have these qualities. The most perspective greenhouse geometry is a saw-tooth roof structure with roof inclinations of 200 and 300, a span width of 10m and a vertical opening of 2 m for natural ventilation. The module for the greenhouse is repeatable in both directions to a big area. Caused by the asymmetric geometry of the greenhouse (openings oriented on one side) the influence of the wind and wind direction is extensiv