B\,^1\Sigma^{+}_{u} and EF\,^{1}\Sigma^{+}_{g} level energies of D2_{2}

Accurate absolute level energies of the B\,^1\Sigma^{+}_{u}, $v=0-8, N$ and EF\,^{1}\Sigma^{+}_{g}, $v=0-21, N$ rovibrational quantum states of molecular deuterium are derived by combining results from a Doppler-free two-photon laser excitation study on several lines in the $EF\,{}^{1}\Sigma_{g}^{+}-X\,{}^{1}\Sigma_{g}^{+}$ (0,0) band, with results from a Fourier-transform spectroscopic emission study on a low-pressure hydrogen discharge. Level energy uncertainties as low as 0.0005 cm$^{-1}$ are obtained for some low-lying E\,^{1}\Sigma^{+}_{g} inner-well rovibrational levels, while uncertainties for higher-lying rovibrational levels and those of the F\,^{1}\Sigma^{+}_{g} outer-well states are nominally 0.005 cm$^{-1}$. Level energies of B\,^1\Sigma^{+}_{u} rovibrational levels, for $v \leq 8$ and $N \leq 10$ are determined at an accuracy of 0.001 cm$^{-1}$. Computed wavelengths of D$_2$ Lyman transitions in the B\,^1\Sigma^{+}_{u}-X\,^{1}\Sigma^{+}_{g} ($v,0$) bands are also tabulated for future applications.Comment: appears in Journal of Molecular Spectroscopy (2014

Mesoscale modeling of the rheology of pressure sensitive adhesives through inclusion of transient forces

For optimal application, pressure-sensitive adhesives must have rheological properties in between those of a viscoplastic solid and those of a viscoelastic liquid. Such adhesives can be produced by emulsion polymerisation, resulting in latex particles which are dispersed in water and contain long-chain acrylic polymers. When the emulsion is dried, the latex particles coalesce and an adhesive film is formed. The rheological properties of the dried samples are believed to be dominated by the interface regions between the original latex particles, but the relation between rheology and latex particle properties is poorly understood. In this paper we show that it is possible to describe the bulk rheology of a pressure-sensitive adhesive by means of a mesoscale simulation model. To reach experimental time and length scales, each latex particle is represented by just one simulated particle. The model is subjected to oscillatory shear flow and extensional flow. Simple order of magnitude estimates of the model parameters already lead to semi-quantitative agreement with experimental results. We show that inclusion of transient forces in the model, i.e. forces with memory of previous configurations, is essential to correctly predict the linear and nonlinear properties.Comment: 29 pages, 8 figure

Protention and retention in biological systems

This paper proposes an abstract mathematical frame for describing some features of cognitive and biological time. We focus here on the so called "extended present" as a result of protentional and retentional activities (memory and anticipation). Memory, as retention, is treated in some physical theories (relaxation phenomena, which will inspire our approach), while protention (or anticipation) seems outside the scope of physics. We then suggest a simple functional representation of biological protention. This allows us to introduce the abstract notion of "biological inertia".Comment: This paper was made possible only as part of an extended collaboration with Francis Bailly (see references), a dear friend and "ma\^itre \'a penser", who contributed to the key ideas. Francis passed away in february 2008: we continue here our inspiring discussions and joint wor

Social behavior modeling based on Incremental Discrete Hidden Markov Models

12 pagesInternational audienceModeling multimodal face-to-face interaction is a crucial step in the process of building social robots or users-aware Embodied Conversational Agents (ECA). In this context, we present a novel approach for human behavior analysis and generation based on what we called "Incremental Discrete Hidden Markov Model" (IDHMM). Joint multimodal activities of interlocutors are first modeled by a set of DHMMs that are specific to supposed joint cognitive states of the interlocutors. Respecting a task-specific syntax, the IDHMM is then built from these DHMMs and split into i) a recognition model that will determine the most likely sequence of cognitive states given the multimodal activity of the in- terlocutor, and ii) a generative model that will compute the most likely activity of the speaker given this estimated sequence of cognitive states. Short-Term Viterbi (STV) decoding is used to incrementally recognize and generate behav- ior. The proposed model is applied to parallel speech and gaze data of interact- ing dyads

Accurate level energies in the EF1S+g, GK1S+g, H1S+g, B1S+u, C1Pu, B'1S+u, D1Pu, I1Pg, J1Dg states of H2

International audienceBy combining results from a Doppler-free two-photon laser excitation study on several lines in the EF1g+ - X1g+ (0,0) band of H2 with results from a Fourier-transform spectroscopic study on a low-pressure discharge in hydrogen, absolute level energies, with respect to the X1g+, v=0, N=0 ground level, could be determined for 547 rovibronically excited states in H2. While for some of the levels in the EF1g+ and B1u+ states the uncertainties are as low as 0.0001 cm-1, the accuracy of other levels is less accurate. The general improvement on the accuracy for the comprehensive data set of level energies is by an order of magnitude with respect to previous measurements. An updated listing of transition wavelengths of the spectral lines in the Lyman and Werner bands is presented, based on combination differences between the presently obtained B1u+ and C1u level energies and those in the X1g+ ground state

Towards a first observation of magneto-electric directional anisotropy and linear birefringence in gases

In this contribution to PSAS'2010 we report on recent progress on an experiment aimed at measuring small optical directional anisotropies by frequency metrology in a high finesse ring cavity. We focus on our first experimental goal, the measurement of magneto-electric effects in gases. After a review of the expected effects in our set-up, we present the apparatus and the measurement procedure, showing that we already have the necessary sensitivity to start novel experiments.Comment: Proceedings of PSAS'2010, to be published in Canadian Journal of Physics, 2011 Ja

Analyzing powers in inclusive pion production at high energy and the nucleon spin structure

Analyzing powers in inclusive pion production in high energy transversely polarized proton-proton collisions are studied theoretically in the framework of the quark recombination model. Calculations by assuming the SU(6) spin-flavor symmetry for the nucleon structure disagree with the experiments. We solve this difficulty by taking into account the %We overcome this difficulty by taking into account the realistic spin distribution functions of the nucleon, which differs from the SU(6) expectation at large $x$, %but coincides with a perturbative QCD constraint on the ratio of the unpolarized valence distributions, $u/d \to 5$ as $x \to 1$. We also discuss the kaon spin asymmetry and find $A_N(K^+) = -A_N(K^0)$ in the polarized proton-proton collisions at large $x_F$.Comment: 13 pages, 4 figures, late