Ariel - Volume 6 Number 1

Editors John Lammie Curt Cummings Frank Chervenak J.D. Kanofsky Mark Dembert Entertainment Robert Breckenridge Joe Conti Gary Kaskey Photographer Larry Glazerman Overseas Editor Mike Sinason Circulation Jay Amsterdam Humorist Jim McCann Staff Ken Jaffe Bob Sklaroff Halley Faus

Ariel - Volume 6 Number 3

Editors Mark Dembert J.D. Kanofsky Frank Chervenak John Lammie Curt Cummings Staff Ken Jaffe Bob Sklaroff Halley Faust Jim Burke Nancy Redfern Hans Weltin Photographer Larry Glazerman Overseas Editor Mike Sinason Humorist Jim McCan

Ariel - Volume 6 Number 2

Editors Mark Dembert J.D. Kanofsky Frank Chervenak John Lammie Curt Cummings Entertainment Robert Breckenridge Joe Conti Gary Kaskey Photographer Larry Glazerman Overseas Editor Mike Sinason Humorist Jim McCann Staff Ken Jaffe Bob Skarloff Halley Faust Jim Burk

Ariel - Volume 6 Number 4

Editors Mark Dembert J.D. Kanofsky Frank Chervenak John Lammie Curt Cummings Entertainment Robert Breckenridge Joe Conti Gary Kaskey Photographer Larry Glazerman Overseas Editor Mike Sinason Humorist Jim McCann Staff Ken Jaffe Bob Sklaroff Halley Faust Jim Burk

Ariel - Volume 6 Number 4 (Alternate Version)

Editors Mark Dembert J.D. Kanofsky Frank Chervenak John Lammie Curt Cummings Entertainment Robert Breckenridge Joe Conti Gary Kaskey Photographer Larry Glazerman Overseas Editor Mike Sinason Humorist Jim McCann Staff Kenn Jaffe Bob Sklaroff Halley Faust Jim Burke Jay Amsterdam Morton A. Klein Nancy Redfer

Attachment of a Diruthenium Compound to Au and SiO₂/Si Surfaces by “Click” Chemistry

Fabrication of electrodes with functionalized properties is of interest in many electronic applications with the surface impacting the electrical and electronic properties of devices. We report the formation of molecular monolayers containing a redox-active diruthenium­(II,III) compound to gold and silicon surfaces via “click” chemistry. The use of Cu-catalyzed azide–alkyne cycloaddition enables modular design of molecular surfaces and interfaces and allows for a variety of substrates to be functionalized. Attachment of the diruthenium compound is monitored by using infrared and photoelectron spectroscopies. The highest occupied molecular (or system) orbital of the “clicked-on” diruthenium is clearly seen in the photoemission measurements and is mainly attributed to the presence of the Ru atoms. The “click” attachment is robust and provides a route to investigate the evolution of the electronic structure and properties of novel molecules attached to a variety of electrodes. The ability to attach this redox-active Ru molecule onto SiO₂ and Au surfaces is important for the development of functional molecular devices such as charge-based memory devices