In the Lab : Towards a Molecular Level Understanding of Electrochemical Interfaces and Electrocatalytic Reactions

Non peer reviewedPublisher PD

General non-existence theorem for phase transitions in one-dimensional systems with short range interactions, and physical examples of such transitions

We examine critically the issue of phase transitions in one-dimensional systems with short range interactions. We begin by reviewing in detail the most famous non-existence result, namely van Hove's theorem, emphasizing its hypothesis and subsequently its limited range of applicability. To further underscore this point, we present several examples of one-dimensional short ranged models that exhibit true, thermodynamic phase transitions, with increasing level of complexity and closeness to reality. Thus having made clear the necessity for a result broader than van Hove's theorem, we set out to prove such a general non-existence theorem, widening largely the class of models known to be free of phase transitions. The theorem is presented from a rigorous mathematical point of view although examples of the framework corresponding to usual physical systems are given along the way. We close the paper with a discussion in more physical terms of the implications of this non-existence theorem.Comment: Short comment on possible generalization to wider classes of systems added; accepted for publication in Journal of Statistical Physic

Atomic Ensemble Effects and Non-Covalent Interactions at the Electrode–Electrolyte Interface

Peer reviewedPublisher PD

Evolutionary game theory: Temporal and spatial effects beyond replicator dynamics

Evolutionary game dynamics is one of the most fruitful frameworks for studying evolution in different disciplines, from Biology to Economics. Within this context, the approach of choice for many researchers is the so-called replicator equation, that describes mathematically the idea that those individuals performing better have more offspring and thus their frequency in the population grows. While very many interesting results have been obtained with this equation in the three decades elapsed since it was first proposed, it is important to realize the limits of its applicability. One particularly relevant issue in this respect is that of non-mean-field effects, that may arise from temporal fluctuations or from spatial correlations, both neglected in the replicator equation. This review discusses these temporal and spatial effects focusing on the non-trivial modifications they induce when compared to the outcome of replicator dynamics. Alongside this question, the hypothesis of linearity and its relation to the choice of the rule for strategy update is also analyzed. The discussion is presented in terms of the emergence of cooperation, as one of the current key problems in Biology and in other disciplines.Comment: Review, 48 pages, 26 figure

Time Scales in Evolutionary Dynamics

Evolutionary game theory has traditionally assumed that all individuals in a population interact with each other between reproduction events. We show that eliminating this restriction by explicitly considering the time scales of interaction and selection leads to dramatic changes in the outcome of evolution. Examples include the selection of the inefficient strategy in the Harmony and Stag-Hunt games, and the disappearance of the coexistence state in the Snowdrift game. Our results hold for any population size and in the presence of a background of fitness.Comment: Final version with minor changes, accepted for publication in Physical Review Letter

Altruistic behavior pays, or the importance of fluctuations in evolutionary game theory

Human behavior is one of the main problems for evolution, as it is often the case that human actions are disadvantageous for the self and advantageous for other people. Behind this puzzle are our beliefs about rational behavior, based on game theory. Here we show that by going beyond the standard game-theoretical conventions, apparently altruistic behavior can be understood as self-interested. We discuss in detail an example related to the so called Ultimatum game and illustrate the appearance of altruistic behavior induced by fluctuations. In addition, we claim that in general settings, fluctuations play a very relevant role, and we support this claim by considering a completely different example, namely the Stag-Hunt game.Comment: For the proceedings of the 8th Granada Seminar on Computational Physics (AIP Proceedeings Series

Geometric and photometric affine invariant image registration

This thesis aims to present a solution to the correspondence problem for the registration of wide-baseline images taken from uncalibrated cameras. We propose an affine invariant descriptor that combines the geometry and photometry of the scene to find correspondences between both views. The geometric affine invariant component of the descriptor is based on the affine arc-length metric, whereas the photometry is analysed by invariant colour moments. A graph structure represents the spatial distribution of the primitive features; i.e. nodes correspond to detected high-curvature points, whereas arcs represent connectivities by extracted contours. After matching, we refine the search for correspondences by using a maximum likelihood robust algorithm. We have evaluated the system over synthetic and real data. The method is endemic to propagation of errors introduced by approximations in the system.BAE SystemsSelex Sensors and Airborne System

ATR-SEIRAS for time-resolved studies of electrode-electrolyte interfaces

Acknowledgements The support of the University of Aberdeen is gratefully acknowledgedPeer reviewedPublisher PD

Electrooxidation of C1 organic molecules on Pt electrodes

Peer reviewedPostprin