Temperature correction for cylindrical cavity perturbation measurements

The need for accurate material property measurements using microwave cavities requires a form of compensation to correct for changes in temperature and other external influences. This paper details a method for temperature correcting microwave cavity perturbation measurements by monitoring two modes; one which is perturbed by the sample and one which is not (referred to as a nodal mode). The nodal modes used (TM310 and TE311 for an axial sample in a cylindrical cavity) are subject only to sample-independent influences. To demonstrate this technique, the bulk permittivity of a PTFE rod has been measured under varying temperature conditions. The results show that without correction, the measured temperature-dependent dielectric constant has large variations associated with the stepped and linear temperature ramping procedures. The corrected response mitigates systematic errors in the real part. However, the correction of the imaginary part requires careful consideration of the mode coupling strength. This paper demonstrates the importance of temperature correction in dynamic cavity perturbation experiments

Surfactant doped polyaniline coatings for functionalized gas diffusion layers in low temperature fuel cells

Gas diffusion layers (GDLs) are essential for the proper distribution of the reaction gases, the removal of excess water as well as electrical contact in polymer electrolyte fuel cells (PEFCs). The production of state-of-the-art GDLs consists of many steps such as graphitization at high temperatures and hydrophobic treatments with polytetrafluoroethylene (PTFE) which increase the cost. In this study, an electrically conductive and hydrophobic polyaniline (PANI) coating was deposited on carbon paper via dip-coating and electropolymerization to fabricate PTFE-free GDLs. As a proof-of-concept, PANI-coated GDLs were tested as a cathodic GDL in a single cell PEFC and achieved a 42% higher maximum power compared to the reference measurement with a commercial GDL. Furthermore, these PTFE-free GDLs achieved contact angles up to 144° which is in the range of commercial GDLs. The chemical composition of the PANI-coating was investigated via infrared spectroscopy and energy dispersive X-ray spectroscopy (EDX) and the morphology was examined via scanning electron microscopy (SEM). Hence, the proposed method emerges as a possible strategy to simultaneously substitute PTFE and apply a protective and durable coating.</p

Measurement technique for microwave surface resistance of additive manufactured metals

Additive manufactured (AM) metals are a subject of much interest for their performance in passive microwave applications. However, limitations could arise due to artifacts, such as surface texture and/or roughness resulting from the manufacturing process. We have, therefore, adopted a parallel plate microwave resonator for the accurate measurement of the surface resistance of flat metal plates, allowing for microwave current flow in two orthogonal directions by simply exciting a different resonant mode (at 5.3 and 6.4 GHz), without the need to remove and refix the sample. The systematic and random errors associated with the measurement of surface resistance are very small, less than 1% and 0.1%, respectively. The technique is demonstrated with measurements on a range of samples of the alloys, AlSi10Mg and Ti6Al4V, manufactured by laser powder bed fusion, in addition to traditionally machined samples of bulk metal alloys of aluminum and brass. For AM samples of AlSi10Mg, we have studied the effect on the surface resistance of directional roughness features, generated by the laser raster paths, in directions transverse or parallel to microwave current flow. Importantly for passive microwave device applications, we demonstrate that these samples exhibit no systematic anisotropy of surface resistance associated with such surface features

Study of the magnetite to maghemite transition using microwave permittivity and permeability measurements

The microwave cavity perturbation (MCP) technique is used to identify the transition from magnetite (Fe3O4) to the meta-stable form of maghemite (γ-Fe2O3). In this study Fe3O4 was annealed at temperatures from 60 to 300 °C to vary the oxidation. Subsequent to annealing, the complex permittivity and magnetic permeability of the iron oxide powders were measured. The transition to γ-Fe2O3 was corroborated with x-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS) and vibrating sample magnetometry (VSM). XRD, XPS and VSM implied that the starting powder was consistent with Fe3O4 and the powders annealed at more than 200 °C were transitioning to γ-Fe2O3. The MCP measurements gave large differences in both complex permittivity and magnetic permeability of the two phases in the frequency range of 2.5–10.2 GHz. Magnetic permeability decreased with annealing temperature, though magnetic losses showed frequency dependent behaviour. Complex permittivity measurements showed a large decrease in both dielectric constant and losses at all measurement frequencies, as well as a prominent loss peak centred around the phase transition temperatures. We interpret the loss peak as being a consequence of field effects due to an intermediate multi-phase mixture. Additionally, almost no frequency dependence was observed. The reduction in complex permittivity implies that the $\text{Fe}_{\text{oct}}^{2+}$ cations in the lattice provide a significant contribution to polarization at microwave frequencies and the effects of $\text{Fe}_{\text{oct}}^{3+}$ are nominal in comparison. The change in loss can be explained as a combination of the differences in the effective conductivity of the two phases (i.e. Fe3O4 exhibits electron-hopping conduction whereas the presence of vacancies in γ-Fe2O3 nullifies this). This shows that the non-invasive MCP measurements serve as a highly sensitive and versatile method for looking at this phase transition in iron and potentially the effects of oxidation states on the polarization in other iron oxides

Superconducting boron doped nanocrystalline diamond microwave coplanar resonator

A superconducting boron doped nanocrystalline diamond (B-NCD) coplanar waveguide resonator (CPR) is presented for kinetic inductance ($L_k$) and penetration depth ($\lambda_{\rm{L}}$) measurements at microwave frequencies of 0.4 to 1.2 GHz and at temperatures below 3 K. Using a simplified effective medium CPR approach, this work demonstrates that thin granular B-NCD films ($t\approx$ 500 nm) on Si have a large penetration depth ($\lambda_{\rm{L}}\approx 4.3$ to 4.4 $\mu$m), and therefore an associated high kinetic inductance ($L_{k,\square} \approx$ 670 to 690 pH/$\square$). These values are much larger than those typically obtained for films on single crystal diamond which is likely due to the significant granularity of the nanocrystalline films. Based on the measured Q factors of the structure, the calculated surface resistance in this frequency range is found to be as low as $\approx$ 2 to 4 $\mu\Omega$ at $T<2$ K, demonstrating the potential for granular B-NCD for high quality factor superconducting microwave resonators and highly sensitive kinetic inductance detectors.Comment: First draf

Microwave Permittivity of Trace sp² Carbon Impurities in Sub-Micron Diamond Powders

Microwave dielectric loss tangent measurements are demonstrated as a method for quantifying trace sp2-hybridized carbon impurities in sub-micron diamond powders. Appropriate test samples are prepared by vacuum annealing at temperatures from 600 to 1200 °C to vary the sp2/sp3 carbon ratio through partial surface graphitization. Microwave permittivity measurements are compared with those obtained using X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, and electron energy loss spectroscopy (EELS). The average particle size remains constant (verified by scanning electron microscopy) to decouple any geometric dielectric effects from the microwave measurements. After annealing, a small increase in sp2 carbon was identified from the XPS C 1s and Auger spectra, the EELS σ* peak in the C 1s spectra, and the D and G bands in Raman spectroscopy, although a quantifiable diamond to G-band peak ratio was unobtainable. Surface hydrogenation was also evidenced in the Raman and XPS O 1s data. Microwave cavity perturbation measurements show that the dielectric loss tangent increases with increasing sp2 bonding, with the most pertinent finding being that these values correlate with other measurements and that trace concentrations of sp2 carbon as small as 5% can be detected

Capacidad anatioxidante durante la maduración de arazá (eugenia stipitata mc vaugh)

Con el propósito de conocer la evolución de algunos componentes antioxidantes de la pulpa de arazá durante el almacenamiento de los frutos, éstos se cosecharon en su madurez fisiológica y se almacenaron durante seis días a 25 ºC. Se encontróque los frutos presentan su máximo climatérico luego de dos días de almacenamiento y, al llegar al sexto día, sus características sensoriales están marcadamente deterioradas. Los contenidos de ácido ascórbico y fenólicos disminuyeron durante el almacenamiento. Los niveles encontrados de ácido ascórbico, compuestos fenólicos y la actividad anti-oxidante muestran que la contribución de la pulpa de arazá al potencial antioxidante, cuando se compara con otros alimentos, en la dieta humana es buena