2,262 research outputs found
EUV spectroscopy of Sn5+-Sn(10+)ions in an electron beam ion trap and laser-produced plasmas
Emission spectra from multiply-charged Sn5+ –Sn10+ions are recorded from an electron beam ion trap (EBIT) and from laser-produced plasma (LPP) in the extreme ultraviolet range relevant for nanolithographic applications. Features in the wavelength regime between 12.6 and 20.8 nm are studied. Using the Cowan code, emission line features of the charge-state-resolved Sn ion spectra obtained from the EBIT are identified. Emission features from tin LPP either from a liquid micro-droplet or planar solid target are subsequently identified and assigned to specific charge states using the EBIT data. For the planar solid tin target, the 4d–5p transitions of Sn8+ –Sn10+ions are shown to dominate the long-wavelength part of the measured spectrum and transitions of type 4d–4f + 4p–4d are visible in absorption. For the droplet target case, a clear increase in the charge state distribution with increasing laser intensity is observed. This qualitatively demonstrates the potential of using long-wavelength out-of-band emission features to probe the charge states contributing to the strong unresolved transition array at 13.5 nm relevant for nanolithography
Detection of the 5p-4f orbital crossing and its optical clock transition in Pr9+
Recent theoretical works have proposed atomic clocks based on narrow optical transitions in highly charged ions. The most interesting candidates for searches of new physics are those which occur at rare orbital crossings where the shell structure of the periodic table is reordered. There are only three such crossings expected to be accessible in highly charged ions, and hitherto none have been observed as both experiment and theory have proven difficult. In this work we observe an orbital crossing in highly charged ions for the first time, in a system chosen to be tractable from both sides: Pr9+. We present electron beam ion trap measurements of its spectra, including the inter-configuration lines that reveal the sought-after crossing. The proposed nHz-wide clock line, found to be at 452.334(1) nm, proceeds through hyperfine admixture of its upper state with an E2-decaying level. With state-of-the-art calculations we show that it has a very high sensitivity to new physics and extremely low sensitivity to external perturbations, making it a unique candidate for proposed precision studies
Differential-Algebraic Integrability Analysis of the Generalized Riemann Type and Korteweg-de Vries Hydrodynamical Equations
A differential-algebraic approach to studying the Lax type integrability of
the generalized Riemann type hydrodynamic equations at N = 3; 4 is devised. The
approach is also applied to studying the Lax type integrability of the well
known Korteweg-de Vries dynamical system.Comment: 11 page
Vacancy ordering and electronic structure of gamma-Fe2O3 (maghemite): a theoretical investigation
The crystal structure of the iron oxide gamma-Fe2O3 is usually reported in
either the cubic system (space group P4332) with partial Fe vacancy disorder or
in the tetragonal system (space group P41212) with full site ordering and
c/a\approx 3. Using a supercell of the cubic structure, we obtain the spectrum
of energies of all the ordered configurations which contribute to the partially
disordered P4332 cubic structure. Our results show that the configuration with
space group P41212 is indeed much more stable than the others, and that this
stability arises from a favourable electrostatic contribution, as this
configuration exhibits the maximum possible homogeneity in the distribution of
iron cations and vacancies. Maghemite is therefore expected to be fully ordered
in equilibrium, and deviations from this behaviour should be associated with
metastable growth, extended anti-site defects and surface effects in the case
of small nanoparticles. The confirmation of the ordered tetragonal structure
allows us to investigate the electronic structure of the material using density
functional theory (DFT) calculations. The inclusion of a Hubbard (DFT+U)
correction allows the calculation of a band gap in good agreement with
experiment. The value of the gap is dependent on the electron spin, which is
the basis for the spin-filtering properties of maghemite.Comment: 19 pages, 2 tables, 5 figures. To appear in the Journal of Physics -
Condensed Matter (2010)
Instabilities of Higher-Order Parametric Solitons. Filamentation versus Coalescence
We investigate stability and dynamics of higher-order solitary waves in
quadratic media, which have a central peak and one or more surrounding rings.
We show existence of two qualitatively different behaviours. For positive phase
mismatch the rings break up into filaments which move radially to initial ring.
For sufficient negative mismatches rings are found to coalesce with central
peak, forming a single oscillating filament.Comment: 5 pages, 7 figure
Rotaxane Co-II Complexes as Field-Induced Single-Ion Magnets
Mechanically chelating ligands have untapped potential for the engineering of metal ion properties. Here we demonstrate this principle in the context of CoII-based single-ion magnets. Using multi-frequency EPR, susceptibility and magnetization measurements we found that these complexes show some of the highest zero field splittings reported for five-coordinate CoII complexes to date. The predictable coordination behaviour of the interlocked ligands allowed the magnetic properties of their CoII complexes to be evaluated computationally a priori and our combined experimental and theoretical approach enabled us to rationalize the observed trends. The predictable magnetic behaviour of the rotaxane CoII complexes demonstrates that interlocked ligands offer a new strategy to design metal complexes with interesting functionality
X-ray resonant photoexcitation: line widths and energies of K{\alpha} transitions in highly charged Fe ions
Photoabsorption by and fluorescence of the K{\alpha} transitions in highly
charged iron ions are essential mechanisms for X-ray radiation transfer in
astrophysical environments. We study photoabsorption due to the main K{\alpha}
transitions in highly charged iron ions from heliumlike to fluorinelike (Fe
24+...17+) using monochromatic X-rays around 6.6 keV at the PETRA III
synchrotron photon source. Natural linewidths were determined with hitherto
unattained accuracy. The observed transitions are of particular interest for
the understanding of photoexcited plasmas found in X-ray binaries and active
galactic nuclei.Comment: Revised versio
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