1,620 research outputs found
Reaction-Diffusion Process Driven by a Localized Source: First Passage Properties
We study a reaction-diffusion process that involves two species of atoms,
immobile and diffusing. We assume that initially only immobile atoms, uniformly
distributed throughout the entire space, are present. Diffusing atoms are
injected at the origin by a source which is turned on at time t=0. When a
diffusing atom collides with an immobile atom, the two atoms form an immobile
stable molecule. The region occupied by molecules is asymptotically spherical
with radius growing as t^{1/d} in d>=2 dimensions. We investigate the survival
probability that a diffusing atom has not become a part of a molecule during
the time interval t after its injection and the probability density of such a
particle. We show that asymptotically the survival probability (i) saturates in
one dimension, (ii) vanishes algebraically with time in two dimensions (with
exponent being a function of the dimensionless flux and determined as a zero of
a confluent hypergeometric function), and (iii) exhibits a stretched
exponential decay in three dimensions.Comment: 7 pages; version 2: section IV is re-written, references added, 8
pages (final version
Locating a weak change using diffuse waves (LOCADIFF) : theoretical approach and inversion procedure
We describe a time-resolved monitoring technique for heterogeneous media. Our
approach is based on the spatial variations of the cross-coherence of coda
waveforms acquired at fixed positions but at different dates. To locate and
characterize a weak change that occurred between successive acquisitions, we
use a maximum likelihood approach combined with a diffusive propagation model.
We illustrate this technique, called LOCADIFF, with numerical simulations. In
several illustrative examples, we show that the change can be located with a
precision of a few wavelengths and its effective scattering cross-section can
be retrieved. The precision of the method depending on the number of source
receiver pairs, time window in the coda, and errors in the propagation model is
investigated. Limits of applications of the technique to real-world experiments
are discussed.Comment: 11 pages, 14 figures, 1 tabl
2D pattern evolution constrained by complex network dynamics
Complex networks have established themselves along the last years as being
particularly suitable and flexible for representing and modeling several
complex natural and human-made systems. At the same time in which the
structural intricacies of such networks are being revealed and understood,
efforts have also been directed at investigating how such connectivity
properties define and constrain the dynamics of systems unfolding on such
structures. However, lesser attention has been focused on hybrid systems,
\textit{i.e.} involving more than one type of network and/or dynamics. Because
several real systems present such an organization (\textit{e.g.} the dynamics
of a disease coexisting with the dynamics of the immune system), it becomes
important to address such hybrid systems. The current paper investigates a
specific system involving a diffusive (linear and non-linear) dynamics taking
place in a regular network while interacting with a complex network of
defensive agents following Erd\"os-R\'enyi and Barab\'asi-Albert graph models,
whose nodes can be displaced spatially. More specifically, the complex network
is expected to control, and if possible to extinguish, the diffusion of some
given unwanted process (\textit{e.g.} fire, oil spilling, pest dissemination,
and virus or bacteria reproduction during an infection). Two types of pattern
evolution are considered: Fick and Gray-Scott. The nodes of the defensive
network then interact with the diffusing patterns and communicate between
themselves in order to control the spreading. The main findings include the
identification of higher efficiency for the Barab\'asi-Albert control networks.Comment: 18 pages, 32 figures. A working manuscript, comments are welcome
Macroscopic models for superconductivity
This paper reviews the derivation of some macroscopic models for superconductivity and also some of the mathematical challenges posed by these models. The paper begins by exploring certain analogies between phase changes in superconductors and those in solidification and melting. However, it is soon found that there are severe limitations on the range of validity of these analogies and outside this range many interesting open questions can be posed about the solutions to the macroscopic models
A microscopic model for thin film spreading
A microscopic, driven lattice gas model is proposed for the dynamics and
spatio-temporal fluctuations of the precursor film observed in spreading
experiments. Matter is transported both by holes and particles, and the
distribution of each can be described by driven diffusion with a moving
boundary. This picture leads to a stochastic partial differential equation for
the shape of the boundary, which agrees with the simulations of the lattice
gas. Preliminary results for flow in a thermal gradient are discussed.Comment: 4 pages, 3 figures. Submitte
Interfacial layering in a three-component polymer system
We study theoretically the temporal evolution and the spatial structure of
the interface between two polymer melts involving three different species (A,
A* and B). The first melt is composed of two different polymer species A and A*
which are fairly indifferent to one another (Flory parameter chi_AA* ~ 0). The
second melt is made of a pure polymer B which is strongly attracted to species
A (chi_AB 0). We then show
that, due to these contradictory tendencies, interesting properties arise
during the evolution of the interface after the melts are put into contact: as
diffusion proceeds, the interface structures into several adjacent
"compartments", or layers, of differing chemical compositions, and in addition,
the central mixing layer grows in a very asymmetric fashion. Such unusual
behaviour might lead to interesting mechanical properties, and demonstrates on
a specific case the potential richness of multi-component polymer interfaces
(as compared to conventional two-component interfaces) for various
applications.Comment: Revised version, to appear in Macromolecule
Electron correlation effects in electron-hole recombination in organic light-emitting diodes
We develop a general theory of electron--hole recombination in organic light
emitting diodes that leads to formation of emissive singlet excitons and
nonemissive triplet excitons. We briefly review other existing theories and
show how our approach is substantively different from these theories. Using an
exact time-dependent approach to the interchain/intermolecular charge-transfer
within a long-range interacting model we find that, (i) the relative yield of
the singlet exciton in polymers is considerably larger than the 25% predicted
from statistical considerations, (ii) the singlet exciton yield increases with
chain length in oligomers, and, (iii) in small molecules containing nitrogen
heteroatoms, the relative yield of the singlet exciton is considerably smaller
and may be even close to 25%. The above results are independent of whether or
not the bond-charge repulsion, X_perp, is included in the interchain part of
the Hamiltonian for the two-chain system. The larger (smaller) yield of the
singlet (triplet) exciton in carbon-based long-chain polymers is a consequence
of both its ionic (covalent) nature and smaller (larger) binding energy. In
nitrogen containing monomers, wavefunctions are closer to the noninteracting
limit, and this decreases (increases) the relative yield of the singlet
(triplet) exciton. Our results are in qualitative agreement with
electroluminescence experiments involving both molecular and polymeric light
emitters. The time-dependent approach developed here for describing
intermolecular charge-transfer processes is completely general and may be
applied to many other such processes.Comment: 19 pages, 11 figure
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