Platinum/ceria/alumina catalysts on microstructures for carbon monoxide conversion

Platinum/ceria/alumina catalysts have been prepared by a sol–gel method and coated in the microchannels of stainless steel platelets. These catalysts are very active for the water-gas shift reaction between 300 and 400°C. Moreover, they are non-pyrophoric and thus well suited for the purification of hydrogen for PEM fuel cells. The obtained coatings show good adherence and catalytic activity. The influence of the amount of platinum and ceria as well as the effect of a binder on the catalytic performance has been investigated. The samples have been characterized before reaction by XRD, SEM and by N2 adsorption measurements. The kinetics, free from internal diffusion limitations, over these thin films have been described by a power law rate equation. An activation energy of 86 kJ/mol has been found and at 260 °C the TOF corresponds to 0.6 ± 0.1 s−1 for all investigated samples. The superior activity of the platelets compared to the powder samples is attributed to the diffusion limitations inside the powder pellets. Thus catalysts deposited on microstructured platelets lead to a better platinum utilization

Properties of simulated Milky Way-mass galaxies in loose group and field environments

We test the validity of comparing simulated field disk galaxies with the empirical properties of systems situated within environments more comparable to loose groups, including the Milky Way's Local Group. Cosmological simulations of Milky Way-mass galaxies have been realised in two different environment samples: in the field and in environments with similar properties to the Local Group. Apart from the environments of the galaxies, the samples are kept as homogeneous as possible with equivalent ranges in last major merger time, halo mass and halo spin. Comparison of these two samples allow for systematic differences in the simulations to be identified. Metallicity gradients, disk scale lengths, colours, magnitudes and age-velocity dispersion relations are studied for each galaxy in the suite and the strength of the link between these and environment of the galaxies is studied. The bulge-to-disk ratio of the galaxies show that these galaxies are less spheroid dominated than many other simulated galaxies in literature with the majority of both samples being disk dominated. We find that secular evolution and mergers dominate the spread of morphologies and metallicity gradients with no visible differences between the two environment samples. In contrast with this consistency in the two samples there is tentative evidence for a systematic difference in the velocity dispersion-age relations of galaxies in the different environments. Loose group galaxies appear to have more discrete steps in their velocity dispersion-age relations. We conclude that at the current resolution of cosmological galaxy simulations field environment galaxies are sufficiently similar to those in loose groups to be acceptable proxies for comparison with the Milky Way provided that a similar assembly history is considered.Comment: 16 pages, 11 figures, abstract abridged for arXiv. Accepted for publication in Astronomy & Astrophysic

Commissioning of the CMS Cryogenic System After Final Installation in the Underground Cavern

After having served for the surface tests of the Compact Muon Solenoid (CMS) magnet, the cold box and ancillaries of the CMS helium refrigerator have been dismantled, moved and re-installed in the USC55 cavern in 2007. The full re-commissioning in the cavern has been followed by several tests of the refrigerator to confirm its nominal performance before it was used for the magnet and detector tests in 2008. During these tests the safety modes of the refrigeration system have been tested and improved. After a nine-year project both, the magnet and the refrigeration system are now ready for the CMS operation

Star formation efficiency and host galaxies of Gamma-Ray Bursts

Gamma-ray bursts are likely to be associated with regions of active star formation and may therefore be useful as cosmological tracers of galaxy formation. Using hydrodynamical/N-body simulations the cosmological properties of host galaxies are investigated. Assuming the hosts to be efficient star-forming objects, i.e. with high specific star formation rates, the majority of the candidate hosts are found to below mass, young galaxies with a moderate star formation rate. This picture, consistent with most observations of GRB host galaxies, corroborates the idea that gamma-ray bursts do not follow the cosmic star formation rate. More importantly the hosts should contribute to unveil the faint end of the galaxy luminosity function

Quantum fluctuations for drag free geodesic motion

The drag free technique is used to force a proof mass to follow a geodesic motion. The mass is protected from perturbations by a cage, and the motion of the latter is actively controlled to follow the motion of the proof mass. We present a theoretical analysis of the effects of quantum fluctuations for this technique. We show that a perfect drag free operation is in principle possible at the quantum level, in spite of the back action exerted on the mass by the position sensor.Comment: 4 pages, 1 figure, RevTeX, minor change

Chirality transfer and stereo-selectivity of imprinted cholesteric networks

Imprinting of cholesteric textures in a polymer network is a method of preserving a macroscopically chiral phase in a system with no molecular chirality. By modifying the elastics properties of the network, the resulting stored helical twist can be manipulated within a wide range since the imprinting efficiency depends on the balance between the elastics constants and twisting power at network formation. One spectacular property of phase chirality imprinting is the created ability of the network to adsorb preferentially one stereo-component from a racemic mixture. In this paper we explore this property of chirality transfer from a macroscopic to the molecular scale. In particular, we focus on the competition between the phase chirality and the local nematic order. We demonstrate that it is possible to control the subsequent release of chiral solvent component from the imprinting network and the reversibility of the stereo-selective swelling by racemic solvents

Beating quantum limits in interferometers with quantum locking of mirrors

The sensitivity in interferometric measurements such as gravitational-wave detectors is ultimately limited by quantum noise of light. We discuss the use of feedback mechanisms to reduce the quantum effects of radiation pressure. Recent experiments have shown that it is possible to reduce the thermal motion of a mirror by cold damping. The mirror motion is measured with an optomechanical sensor based on a high-finesse cavity, and reduced by a feedback loop. We show that this technique can be extended to lock the mirror at the quantum level. In gravitational-waves interferometers with Fabry-Perot cavities in each arms, it is even possible to use a single feedback mechanism to lock one cavity mirror on the other. This quantum locking greatly improves the sensitivity of the interferometric measurement. It is furthermore insensitive to imperfections such as losses in the interferometer

Stereo-selective swelling of imprinted cholesteric networks

Molecular chirality, and the chiral symmetry breaking of resulting macroscopic phases, can be topologically imprinted and manipulated by crosslinking and swelling of polymer networks. We present a new experimental approach to stereo-specific separation of chiral isomers by using a cholesteric elastomer in which a helical director distribution has been topological imprinted by crosslinking. This makes the material unusual in that is has a strong phase chirality, but no molecular chirality at all; we study the nature and parameters controlling the twist-untwist transition. Adding a racemic mixture to the imprinted network results in selective swelling by only the component of ``correct'' handedness. We investigate the capacity of demixing in a racemic environment, which depends on network parameters and the underlying nematic order

Pioneer 10 data analysis: Investigation on periodic anomalies

International audienceThe Pioneer Anomaly refers to the difference between the expected theoretical tra jectory of the Pioneer 10 and 11 spacecrafts and the observed tra jectory through Doppler measurements. It has been interpreted by the Jet Propulsion Laboratory (JPL) as a constant anomalous acceleration (Anderson et al. 2002). For this analysis, the Groupe Anomalie Pioneer (GAP) composed of several french laboratories has developped a specific tra jectography software, ODYSSEY, which enables to test different anomaly models. The paper will present, after a brief description of the software and the implemented models, the last results obtained: in addition to the constant anomaly, time dependent signatures of the anomaly have been noticed which can be described geometrically. The fit of the Pioneer 10 data with these new models yields a reduction of the standard deviation of the residual by a factor 2 with respect to the simple constant anomaly