2,359 research outputs found
Charged Vacuum Bubble Stability
A type of scenario is considered where electrically charged vacuum bubbles,
formed from degenerate or nearly degenerate vacuua separated by a thin domain
wall, are cosmologically produced due to the breaking of a discrete symmetry,
with the bubble charge arising from fermions residing within the domain wall.
Stability issues associated with wall tension, fermion gas, and Coulombic
effects for such configurations are examined. The stability of a bubble depends
upon parameters such as the symmetry breaking scale and the fermion coupling. A
dominance of either the Fermi gas or the Coulomb contribution may be realized
under certain conditions, depending upon parameter values.Comment: 16 pages,revtex; accepted for publication in Phys.Rev.
Measuring molecular abundances in comet C/2014 Q2 (Lovejoy) using the APEX telescope
Comet composition provides critical information on the chemical and physical
processes that took place during the formation of the Solar system. We report
here on millimetre spectroscopic observations of the long-period bright comet
C/2014 Q2 (Lovejoy) using the Atacama Pathfinder Experiment (APEX) band 1
receiver between 2015 January UT 16.948 to 18.120, when the comet was at
heliocentric distance of 1.30 AU and geocentric distance of 0.53 AU. Bright
comets allow for sensitive observations of gaseous volatiles that sublimate in
their coma. These observations allowed us to detect HCN, CH3OH (multiple
transitions), H2CO and CO, and to measure precise molecular production rates.
Additionally, sensitive upper limits were derived on the complex molecules
acetaldehyde (CH3CHO) and formamide (NH2CHO) based on the average of the
strongest lines in the targeted spectral range to improve the signal-to-noise
ratio. Gas production rates are derived using a non-LTE molecular excitation
calculation involving collisions with H2O and radiative pumping that becomes
important in the outer coma due to solar radiation. We find a depletion of CO
in C/2014 Q2 (Lovejoy) with a production rate relative to water of 2 per cent,
and relatively low abundances of Q(HCN)/Q(H2O), 0.1 per cent, and
Q(H2CO)/Q(H2O), 0.2 per cent. In contrast the CH3OH relative abundance
Q(CH3OH)/Q(H2O), 2.2 per cent, is close to the mean value observed in other
comets. The measured production rates are consistent with values derived for
this object from other facilities at similar wavelengths taking into account
the difference in the fields of view. Based on the observed mixing ratios of
organic molecules in four bright comets including C/2014 Q2, we find some
support for atom addition reactions on cold dust being the origin of some of
the molecules.Comment: 10 pages, 7 figures, to be published in MNRA
Magnetic properties of 3d-impurities substituted in GaAs
We have calculated the magnetic properties of substituted 3d-impurities
(Cr-Ni) in a GaAs host by means of first principles electronic structure
calculations. We provide a novel model explaining the ferromagnetic long rang
order of III-V dilute magnetic semiconductors. The origin of the ferromagnetism
is shown to be due to delocalized spin-uncompensated As dangling bond
electrons. Besides the quantitative prediction of the magnetic moments, our
model provides an understanding of the halfmetallicity, and the raise of the
critical temperature with the impurity concentration
Carbon nitride as a ligand: edge-site coordination of ReCl(CO)(3)-fragments to g-C3N4
IR spectroscopy and model structural studies show binding of ReCl(CO)3-fragments to carbon nitride (g-C3N4) occurs via κ2 N,N′ bidentate coordination
Light-Induced Activation of a Molybdenum Oxotransferase Model within a Ru(II)-Mo(VI) Dyad
Nature uses molybdenum-containing enzymes to catalyze oxygen atom transfer (OAT) from water to organic substrates. In these enzymes, the two electrons that are released during the reaction are rapidly removed, one at a time, by spatially separated electron transfer units. Inspired by this design, a Ru(II)-Mo(VI) dyad was synthesized and characterized, with the aim of accelerating the rate-determining step in the cis-dioxo molybdenum-catalyzed OAT cycle, the transfer of an oxo ligand to triphenyl phosphine, via a photo-oxidation process. The dyad consists of a photoactive bis(bipyridyl)-phenanthroline ruthenium moiety that is covalently linked to a bioinspired cis-dioxo molybdenum thiosemicarbazone complex. The quantum yield and luminescence lifetimes of the dyad [Ru(bpy)2(L(2))MoO2(solv)](2+) were determined. The major component of the luminescence decay in MeCN solution (τ = 1149 ± 2 ns, 67%) corresponds closely to the lifetime of excited [Ru(bpy)2(phen-NH2)](2+), while the minor component (τ = 320 ± 1 ns, 31%) matches that of [Ru(bpy)2(H2-L(2))](2+). In addition, the (spectro)electrochemical properties of the system were investigated. Catalytic tests showed that the dyad-catalyzed OAT from dimethyl sulfoxide to triphenyl phosphine proceeds significantly faster upon irradiation with visible light than in the dark. Methylviologen acts as a mediator in the photoredox cycle, but it is regenerated and hence only required in stoichiometric amounts with respect to the catalyst rather than sacrificial amounts. It is proposed that oxidative quenching of the photoexcited Ru unit, followed by intramolecular electron transfer, leads to the production of a reactive one-electron oxidized catalyst, which is not accessible by electrochemical methods. A significant, but less pronounced, rate enhancement was observed when an analogous bimolecular system was tested, indicating that intramolecular electron transfer between the photosensitizer and the catalytic center is more efficient than intermolecular electron transfer between the separate components
Cosmic Strings in an Open Universe with Baryonic and Non-Baryonic Dark Matter
We study the effects of cosmic strings on structure formation in open
universes. We calculate the power spectrum of density perturbations for two
class of models: one in which all the dark matter is non baryonic (CDM) and one
in which it is all baryonic (BDM). Our results are compared to the 1 in 6 IRAS
QDOT power spectrum. The best candidates are then used to estimate , the
energy per unit length of the string network. Some comments are made on
mechanisms by which structures are formed in the two theories.Comment: uu-encoded compressed tar of postscript files, Imperial/TP/94-95/0
Symmetry Breaking of Relativistic Multiconfiguration Methods in the Nonrelativistic Limit
The multiconfiguration Dirac-Fock method allows to calculate the state of
relativistic electrons in atoms or molecules. This method has been known for a
long time to provide certain wrong predictions in the nonrelativistic limit. We
study in full mathematical details the nonlinear model obtained in the
nonrelativistic limit for Be-like atoms. We show that the method with sp+pd
configurations in the J=1 sector leads to a symmetry breaking phenomenon in the
sense that the ground state is never an eigenvector of L^2 or S^2. We thereby
complement and clarify some previous studies.Comment: Final version, to appear in Nonlinearity. Nonlinearity (2010) in
pres
Aeroservoelastic Testing of a Sidewall Mounted Free Flying Wind-Tunnel Model
A team comprised of the Air Force Research Laboratory (AFRL), Northrop Grumman, Lockheed Martin, and the NASA Langley Research Center conducted three j wind-tunnel tests in the Transonic Dynamics Tunnel to demonstrate active control technologies relevant to large, exible vehicles. In the rst of these three tests, a semispan, aeroelastically scaled, wind-tunnel model of a ying wing SensorCraft vehi- cle was mounted to a force balance to demonstrate gust load alleviation. In the second and third tests, the same wing was mated to a new, multi-degree-of-freedom, sidewall mount. This mount allowed the half-span model to translate vertically and pitch at the wing root, allowing better simulation of the full span vehicle's rigid-body modes. Gust Load Alleviation (GLA) and Body Freedom Flutter (BFF) suppression were successfully demonstrated. The rigid body degrees-of-freedom required that the model be own in the wind tunnel using an active control system. This risky mode of testing necessitated that a model arrestment system be integrated into the new mount. The safe and successful completion of these free-flying tests required the development and integration of custom hardware and software. This paper describes the many systems, software, and procedures that were developed as part of this effort
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A functional genomic analysis of cell morphology using RNA interference
BACKGROUND: The diversity of metazoan cell shapes is influenced by the dynamic cytoskeletal network. With the advent of RNA-interference (RNAi) technology, it is now possible to screen systematically for genes controlling specific cell-biological processes, including those required to generate distinct morphologies. RESULTS: We adapted existing RNAi technology in Drosophila cell culture for use in high-throughput screens to enable a comprehensive genetic dissection of cell morphogenesis. To identify genes responsible for the characteristic shape of two morphologically distinct cell lines, we performed RNAi screens in each line with a set of double-stranded RNAs (dsRNAs) targeting 994 predicted cell shape regulators. Using automated fluorescence microscopy to visualize actin filaments, microtubules and DNA, we detected morphological phenotypes for 160 genes, one-third of which have not been previously characterized in vivo. Genes with similar phenotypes corresponded to known components of pathways controlling cytoskeletal organization and cell shape, leading us to propose similar functions for previously uncharacterized genes. Furthermore, we were able to uncover genes acting within a specific pathway using a co-RNAi screen to identify dsRNA suppressors of a cell shape change induced by Pten dsRNA. CONCLUSIONS: Using RNAi, we identified genes that influence cytoskeletal organization and morphology in two distinct cell types. Some genes exhibited similar RNAi phenotypes in both cell types, while others appeared to have cell-type-specific functions, in part reflecting the different mechanisms used to generate a round or a flat cell morphology
Ab initio calculations of the hydrogen bond
Recent x-ray Compton scattering experiments in ice have provided useful
information about the quantum nature of the interaction between HO
monomers. The hydrogen bond is characterized by a certain amount of charge
transfer which could be determined in a Compton experiment. We use ab-initio
simulations to investigate the hydrogen bond in HO structures by
calculating the Compton profile and related quantities in three different
systems, namely the water dimer, a cluster containing 12 water molecules and
the ice crystal. We show how to extract estimates of the charge transfer from
the Compton profiles.Comment: 16 pages, 7 figures, to appear in Phys. Rev.
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