72 research outputs found
Evaluation of the creep behaviour of the carbon fibre in an unidirectional pultruded reinforced composite using nano-indentation technique
Innovative Data Management in advanced characterization: Implications for materials design
Abstract This paper describes a novel methodology of data documentation in materials characterization, which has as starting point the creation and usage of any Data Management Plan (DMP) for scientific data in the field of materials science and engineering, followed by the development and exploitation of ontologies for the harnessing of data created through experimental techniques. The case study that is discussed here is nanoindentation, a widely used method for the experimental assessment of mechanical properties on a small scale. The new documentation structure for characterization data (CHADA) is based on the definition of (i) sample, (ii) method, (iii) raw data and (iv) data analysis as the main component of the metadata associated to any characterization experiment. In this way, the relevant information can be stored inside the metadata associated to the experiment. The same methodology can be applicable to a large number of techniques that produce big amount of raw data, while at the same time it can be invaluable tool for big data analysis and for the creation of an open innovation environment, where data can be accessed freely and efficiently. Other fundamental aspects are reviewed in the paper, including the taxonomy and curation of data, the creation of ontology and classification of characterization techniques, the harnessing of data in open innovation environments via database construction along with the retrieval of information via algorithms. The issues of harmonization and standardization of such novel approaches are also critically discussed. Finally, the possible implications for nanomaterial design and the potential industrial impact of the new approach are described and a critical outlook is given
Nanomaterial-Enhanced Sizings:Design and Optimisation of a Pilot-Scale Fibre Sizing Line
This study focuses on the development of a pilot-scale sizing line, including its initial design and installation, operational phases, and optimization of key process parameters. The primary objective is the identification of critical parameters for achieving a uniform sizing onto the fibres and the determination of optimal conditions for maximum production efficiency. This investigation focused on adjusting the furnace desizing temperature for the removal of commercial sizing, adjusting the drying temperature, as well as optimizing the corresponding residence time of carbon fibres passing through the furnaces. The highest production rate, reaching 1 m sized carbon fibres per minute, was achieved by employing a desizing temperature of 550 °C, a drying temperature of 250 °C, and a residence time of 1 min. Furthermore, a range of sizing solutions was investigated and formulated, exploring carbon-based nanomaterial types with different surface functionalizations and concentrations, to evaluate their impact on the surface morphology and mechanical properties of carbon fibres. In-depth analyses, including scanning electron microscopy and contact angle goniometry, revealed the achievement of a uniform coating on the carbon fibre surface, leading to an enhanced affinity between fibres and the polymeric epoxy matrix. The incorporation of nanomaterials, specifically N2-plasma-functionalized carbon nanotubes and few-layer graphene, demonstrated notable improvements in the interfacial shear properties (90% increase), verified by mechanical and push-out tests
Mesoscopic modeling and experimental validation of thermal and mechanical properties of polypropylene nanocomposites reinforced by graphene-based fillers
The development of nanocomposites relies on structure-property relations,
which necessitate multiscale modeling approaches. This study presents a
modelling framework that exploits mesoscopic models to predict the thermal and
mechanical properties of nanocomposites starting from their molecular
structure. In detail, mesoscopic models of polypropylene (PP) and graphene
based nanofillers (Graphene (Gr), Graphene Oxide (GO), and reduced Graphene
Oxide (rGO)) are considered. The newly developed mesoscopic model for the PP/Gr
nanocomposite provides mechanistic information on the thermal and mechanical
properties at the filler-matrix interface, which can be then exploited to
enhance the prediction accuracy of traditional continuum simulations by
calibrating the thermal and mechanical properties of the filler-matrix
interface. Once validated through a dedicated experimental campaign, this
multiscale model demonstrates that with the modest addition of nanofillers (up
to 2 wt.%), the Young's modulus and thermal conductivity show up to 35% and 25%
enhancement, respectively, while the Poisson's ratio slightly decreases. Among
the different combinations tested, PP/Gr nanocomposite shows the best
mechanical properties, whereas PP/rGO demonstrates the best thermal
conductivity. This validated mesoscopic model can contribute to the development
of smart materials with enhanced mechanical and thermal properties based on
polypropylene, especially for mechanical, energy storage, and sensing
applications.Comment: Manuscript (37 pages) and Supplementary Information (8 pages
Mesoscopic Modeling and Experimental Validation of Thermal and Mechanical Properties of Polypropylene Nanocomposites Reinforced By Graphene-Based Fillers
The development of nanocomposites relies on structure-property relations, which necessitate multiscale modeling approaches. This study presents a modeling framework that exploits mesoscopic models to predict the thermal and mechanical properties of nanocomposites starting from their molecular structure. In detail, mesoscopic models of polypropylene (PP)- and graphene-based nanofillers (graphene (Gr), graphene oxide (GO), and reduced graphene oxide (rGO)) are considered. The newly developed mesoscopic model for the PP/Gr nanocomposite provides mechanistic information on the thermal and mechanical properties at the filler-matrix interface, which can then be exploited to enhance the prediction accuracy of traditional continuum simulations by calibrating the thermal and mechanical properties of the filler-matrix interface. Once validated through a dedicated experimental campaign, this multiscale model demonstrates that with the modest addition of nanofillers (up to 2 wt %), the Young’s modulus and thermal conductivity show up to 35 and 25% enhancement, respectively, whereas the Poisson’s ratio slightly decreases. Among the different combinations tested, the PP/Gr nanocomposite shows the best mechanical properties, whereas PP/rGO demonstrates the best thermal conductivity. This validated mesoscopic model can contribute to the development of smart materials with enhanced mechanical and thermal properties based on polypropylene, especially for mechanical, energy storage, and sensing applications
Towards a holistic environmental impact assessment of carbon nanotube growth through chemical vapour deposition
Comparative Physical–Mechanical Properties Assessment of Tailored Surface-Treated Carbon Fibres
Carbon Fibres (CFs) are widely used in textile-reinforced composites for the construction
of lightweight, durable structures. Since their inert surface does not allow effective bonding with
the matrix material, the surface treatment of fibres is suggested to improve the adhesion between
the two. In the present study, different surface modifications are compared in terms of the
mechanical enhancement that they can offer to the fibres. Two main advanced technologies have
been investigated; namely, plasma treatment and electrochemical treatment. Specifically, active
screen plasma and low-pressure plasma were compared. Regarding the electrochemical
modification, electrochemical oxidation and electropolymerisation of monomer solutions of acrylic
and methacrylic acids, acrylonitrile and N-vinyl pyrrolidine were tested for HTA-40 CFs. In order
to assess the effects of the surface treatments, the morphology, the physicochemical properties, as
well as the mechanical integrity of the fibres were investigated. The CF surface and polymeric matrix
interphase adhesion in composites were also analysed. The improvement of the carbon fibre’s
physical–mechanical properties was evident for the case of the active screen plasma treatment and
the electrochemical oxidation
Metadata stewardship in nanosafety research: learning from the past, preparing for an "on-the-fly" FAIR future
Introduction: Significant progress has been made in terms of best practice in research data management for nanosafety. Some of the underlying approaches to date are, however, overly focussed on the needs of specific research projects or aligned to a single data repository, and this “silo” approach is hampering their general adoption by the broader research community and individual labs.
Methods: State-of-the-art data/knowledge collection, curation management FAIRification, and sharing solutions applied in the nanosafety field are reviewed focusing on unique features, which should be generalised and integrated into a functional FAIRification ecosystem that addresses the needs of both data generators and data (re)users.
Results: The development of data capture templates has focussed on standardised single-endpoint Test Guidelines, which does not reflect the complexity of real laboratory processes, where multiple assays are interlinked into an overall study, and where non-standardised assays are developed to address novel research questions and probe mechanistic processes to generate the basis for read-across from one nanomaterial to another. By focussing on the needs of data providers and data users, we identify how existing tools and approaches can be re-framed to enable “on-the-fly” (meta) data definition, data capture, curation and FAIRification, that are sufficiently flexible to address the complexity in nanosafety research, yet harmonised enough to facilitate integration of datasets from different sources generated for different research purposes. By mapping the available tools for nanomaterials safety research (including nanomaterials characterisation, non-standard (mechanistic-focussed) methods, measurement principles and experimental setup, environmental fate and requirements from new research foci such as safe and sustainable by design), a strategy for integration and bridging between silos is presented. The NanoCommons KnowledgeBase has shown how data from different sources can be integrated into a one-stop shop for searching, browsing and accessing data (without copying), and thus how to break the boundaries between data silos.
Discussion: The next steps are to generalise the approach by defining a process to build consensus (meta)data standards, develop solutions to make (meta)data more machine actionable (on the fly ontology development) and establish a distributed FAIR data ecosystem maintained by the community beyond specific projects. Since other multidisciplinary domains might also struggle with data silofication, the learnings presented here may be transferable to facilitate data sharing within other communities and support harmonization of approaches across disciplines to prepare the ground for cross-domain interoperability.
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WorldFAIR is funded by the EC HORIZON-WIDERA-2021-ERA-01-41 Coordination and Support Action under Grant Agreement No. 101058393
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