2,035 research outputs found
Cross-sectional analysis of lithium ion electrodes using spatial autocorrelation techniques.
Join counting, a standard technique in spatial autocorrelation analysis, has been used to quantify the clustering of carbon, fluorine and sodium in cross-sectioned anode and cathode samples. The sample preparation and EDS mapping steps are sufficiently fast for every coating from two Design of Experiment (DoE) test matrices to be characterised. The results show two types of heterogeneity in material distribution; gradients across the coating from the current collector to the surface, and clustering. In the cathode samples, the carbon is more clustered than the fluorine, implying that the conductive carbon component is less well distributed than the binder. The results are correlated with input parameters systematically varied in the DoE coating blade gap, coating speed, and other output parameters coat weight, and electrochemical resistance
A new species of Pachycara Zugmayer, 1911 (Teleostei: Zoarcidae) from deep-sea chemosynthetic environments in the Caribbean Sea.
The 28th species of the eelpout genus Pachycara Zugmayer, 1911, is described from specimens collected from an active hydrothermal vent field at a depth of about 2300 m at the Mid-Cayman Spreading Centre of the Caribbean Sea. A tentatively identified early juvenile is recorded at a methane seep at a depth of 1049 m near Tobago. The new species is distinguished from its congeners mainly by its few pectoral fin rays, low vertebral counts, single, mediolateral branch of the lateral line system and presence of scales on the nape and cheeks
Rotational Dynamics of Organic Cations in CH3NH3PbI3 Perovskite
Methylammonium lead iodide (CH3NH3PbI3) based solar cells have shown
impressive power conversion efficiencies of above 20%. However, the microscopic
mechanism of the high photovoltaic performance is yet to be fully understood.
Particularly, the dynamics of CH3NH3+ cations and their impact on relevant
processes such as charge recombination and exciton dissociation are still
poorly understood. Here, using elastic and quasi-elastic neutron scattering
techniques and group theoretical analysis, we studied rotational modes of the
CH3NH3+ cation in CH3NH3PbI3. Our results show that, in the cubic (T > 327K)
and tetragonal (165K < T < 327K) phases, the CH3NH3+ ions exhibit four-fold
rotational symmetry of the C-N axis (C4) along with three-fold rotation around
the C-N axis (C3), while in orthorhombic phase (T < 165K) only C3 rotation is
present. Around room temperature, the characteristic relaxation times for the
C4 rotation is found to be ps while for the C3 rotation ps. The -dependent
rotational relaxation times were fitted with Arrhenius equations to obtain
activation energies. Our data show a close correlation between the C4
rotational mode and the temperature dependent dielectric permittivity. Our
findings on the rotational dynamics of CH3NH3+ and the associated dipole have
important implications on understanding the low exciton binding energy and slow
charge recombination rate in CH3NH3PbI3 which are directly relevant for the
high solar cell performance
Evaluating the Written Work of Others: One Way Economics Students Can Learn to Write
The authors present a series of writing assignments that teaches students how to evaluate and critique the written economic work of others. The foundation text is McCloskey’s (2000) Economical Writing. The students’ dialogues with McCloskey, with each other, and with the authors of the pieces they evaluate sharpen their understanding of, and ability to use, language as an instrument of economic thought. Interviews with former students identify specific benefits from the student perspective of this approach. The authors show how the assignment series can be modified in several ways and how the general approach, as well as the foundation text, can be used in different economics courses
HSPG Modification by the Secreted Enzyme Notum Shapes the Wingless Morphogen Gradient
AbstractThe secreted signaling protein Wingless acts as a morphogen to pattern the imaginal discs of Drosophila. Here we report identification of a secreted repressor of Wingless activity, which we call Notum. Loss of Notum function leads to increased Wingless activity by altering the shape of the Wingless protein gradient. When overexpressed, Notum blocks Wingless activity. Notum encodes a member of the α/β-hydrolase superfamily, with similarity to pectin acetylesterases. We present evidence that Notum influences Wingless protein distribution by modifying the heparan sulfate proteoglycans Dally-like and Dally. High levels of Wingless signaling induce Notum expression. Thus, Wingless contributes to shaping its own gradient by regulating expression of a protein that modifies its interaction with cell surface proteoglycans
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