1,154 research outputs found

    Kinetics of Heterogeneous Single-Species Annihilation

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    We investigate the kinetics of diffusion-controlled heterogeneous single-species annihilation, where the diffusivity of each particle may be different. The concentration of the species with the smallest diffusion coefficient has the same time dependence as in homogeneous single-species annihilation, A+A-->0. However, the concentrations of more mobile species decay as power laws in time, but with non-universal exponents that depend on the ratios of the corresponding diffusivities to that of the least mobile species. We determine these exponents both in a mean-field approximation, which should be valid for spatial dimension d>2, and in a phenomenological Smoluchowski theory which is applicable in d<2. Our theoretical predictions compare well with both Monte Carlo simulations and with time series expansions.Comment: TeX, 18 page

    Heterogeneous Catalysis on a Disordered Surface

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    We introduce a simple model of heterogeneous catalysis on a disordered surface which consists of two types of randomly distributed sites with different adsorption rates. Disorder can create a reactive steady state in situations where the same model on a homogeneous surface exhibits trivial kinetics with no steady state. A rich variety of kinetic behaviors occur for the adsorbate concentrations and catalytic reaction rate as a function of model parameters.Comment: 4 pages, gzipped PostScript fil

    Corner Exponents in the Two-Dimensional Potts Model

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    The critical behavior at a corner in two-dimensional Ising and three-state Potts models is studied numerically on the square lattice using transfer operator techniques. The local critical exponents for the magnetization and the energy density for various opening angles are deduced from finite-size scaling results at the critical point for isotropic or anisotropic couplings. The scaling dimensions compare quite well with the values expected from conformal invariance, provided the opening angle is replaced by an effective one in anisotropic systems.Comment: 11 pages, 2 eps-figures, uses LaTex and eps

    Equilibrium Properties of A Monomer-Monomer Catalytic Reaction on A One-Dimensional Chain

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    We study the equilibrium properties of a lattice-gas model of an A+B0A + B \to 0 catalytic reaction on a one-dimensional chain in contact with a reservoir for the particles. The particles of species AA and BB are in thermal contact with their vapor phases acting as reservoirs, i.e., they may adsorb onto empty lattice sites and may desorb from the lattice. If adsorbed AA and BB particles appear at neighboring lattice sites they instantaneously react and both desorb. For this model of a catalytic reaction in the adsorption-controlled limit, we derive analytically the expression of the pressure and present exact results for the mean densities of particles and for the compressibilities of the adsorbate as function of the chemical potentials of the two species.Comment: 19 pages, 5 figures, submitted to Phys. Rev.

    Adsorption of Reactive Particles on a Random Catalytic Chain: An Exact Solution

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    We study equilibrium properties of a catalytically-activated annihilation A+A0A + A \to 0 reaction taking place on a one-dimensional chain of length NN (NN \to \infty) in which some segments (placed at random, with mean concentration pp) possess special, catalytic properties. Annihilation reaction takes place, as soon as any two AA particles land onto two vacant sites at the extremities of the catalytic segment, or when any AA particle lands onto a vacant site on a catalytic segment while the site at the other extremity of this segment is already occupied by another AA particle. Non-catalytic segments are inert with respect to reaction and here two adsorbed AA particles harmlessly coexist. For both "annealed" and "quenched" disorder in placement of the catalytic segments, we calculate exactly the disorder-average pressure per site. Explicit asymptotic formulae for the particle mean density and the compressibility are also presented.Comment: AMSTeX, 27 pages + 4 figure

    The apéritif effect: Alcohol's effects on the brain's response to food aromas in women

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    OBJECTIVE: Consuming alcohol prior to a meal (an apéritif) increases food consumption. This greater food consumption may result from increased activity in brain regions that mediate reward and regulate feeding behavior. Using functional magnetic resonance imaging, we evaluated the blood oxygenation level dependent (BOLD) response to the food aromas of either roast beef or Italian meat sauce following pharmacokinetically controlled intravenous infusion of alcohol. METHODS: BOLD activation to food aromas in non-obese women (n = 35) was evaluated once during intravenous infusion of 6% v/v EtOH, clamped at a steady-state breath alcohol concentration of 50 mg%, and once during infusion of saline using matching pump rates. Ad libitum intake of roast beef with noodles or Italian meat sauce with pasta following imaging was recorded. RESULTS: BOLD activation to food relative to non-food odors in the hypothalamic area was increased during alcohol pre-load when compared to saline. Food consumption was significantly greater, and levels of ghrelin were reduced, following alcohol. CONCLUSIONS: An alcohol pre-load increased food consumption and potentiated differences between food and non-food BOLD responses in the region of the hypothalamus. The hypothalamus may mediate the interplay of alcohol and responses to food cues, thus playing a role in the apéritif phenomenon

    Surface Critical Behavior in Systems with Non-Equilibrium Phase Transitions

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    We study the surface critical behavior of branching-annihilating random walks with an even number of offspring (BARW) and directed percolation (DP) using a variety of theoretical techniques. Above the upper critical dimensions d_c, with d_c=4 (DP) and d_c=2 (BARW), we use mean field theory to analyze the surface phase diagrams using the standard classification into ordinary, special, surface, and extraordinary transitions. For the case of BARW, at or below the upper critical dimension, we use field theoretic methods to study the effects of fluctuations. As in the bulk, the field theory suffers from technical difficulties associated with the presence of a second critical dimension. However, we are still able to analyze the phase diagrams for BARW in d=1,2, which turn out to be very different from their mean field analog. Furthermore, for the case of BARW only (and not for DP), we find two independent surface beta_1 exponents in d=1, arising from two distinct definitions of the order parameter. Using an exact duality transformation on a lattice BARW model in d=1, we uncover a relationship between these two surface beta_1 exponents at the ordinary and special transitions. Many of our predictions are supported using Monte-Carlo simulations of two different models belonging to the BARW universality class.Comment: 19 pages, 12 figures, minor additions, 1 reference adde

    Rethinking feasibility analysis for urban development: a multidimensional decision support tool

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    Large-scale urban development projects featured over the past thirty years have shown some critical issues related to the implementation phase. Con-sequently, the current practice seems oriented toward minimal and wide-spread interventions meant as urban catalyst. This planning practice might solve the problem of limited reliability of large developments’ feasibility studies, but it rises an evaluation demand related to the selection of coali-tion of projects within a multidimensional and multi-stakeholders deci-sion-making context. This study aims to propose a framework for the generation of coalitions of elementary actions in the context of urban regeneration processes and for their evaluation using a Multi Criteria Decision Analysis approach. The proposed evaluation framework supports decision makers in exploring dif-ferent combinations of actions in the context of urban interventions taking into account synergies, i.e. positive or negative effects on the overall per-formance of an alternative linked to the joint realization of specific pairs of actions. The proposed evaluation framework has been tested on a pilot case study dealing with urban regeneration processes in the city of Milan (Italy)

    The three species monomer-monomer model: A mean-field analysis and Monte Carlo study

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    We study the phase diagram and critical behavior of a one dimensional three species monomer-monomer surface reaction model. Static Monte Carlo simulations show a phase diagram consisting of a reactive steady state bordered by three equivalent unreactive phases where the surface is saturated with one monomer species. The transitions from the reactive to saturated phases are all continuous, while the transitions between poisoned phases are first-order, with bicritical points where the reactive phase meets two poisoned phases. A mean-field cluster analysis predicts all of the qualitative features of the phase diagram only when correlations up to triplets of adjacent sites are included. Dynamic Monte Carlo simulations show that the transition from the reactive to a saturated phase show critical behavior in the directed percolation universality class, while the bicritical point shows critical behavior in the even branching annihilating random walk class. The crossover from bicritical to critical behavior is also studied.Comment: 16 pages using RevTeX, plus 10 figures. Uses psfig.st
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