1,393 research outputs found

    Reduction Of Trace Quantities Of Chromium (vi) By Strong Acids

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    The chemical behavior of Cr(VI) at low concentrations (10-4 to 10-7 mol L-1) in several strong acids was studied using high specific activity 51Cr(VI) as a tracer. The speciation of the products from these systems was carried out by ion exchange chromatography with stepwise elution. The results show that trace quantities of Cr(VI), monitored by means of radiochromium (51Cr), are reduced in the presence of mineral acids such as perchloric, hydrochloric, hydrofluoric, sulfuric, nitric and trifluoromethanesulfonic acids, even in the absence of conventional reducing agents, producing different measureable Cr(III) species, depending on the acid anion. Detailed studies of the reduction of low concentrations of Cr(VI) with nitric acid have shown that the relative rate of reduction increases as the concentration of the acid increases or as the concentration of the Cr(VI) decreases.1515865Weeks, M.E., Leicester, H.M., (1968) Discovery of the Elements, 7th Ed., , American Chemical Society: EastonFeigl, F., (1943) J. Chem. Educ., 20, p. 240Westheimer, F.H., (1949) Chem. Rev., 45, p. 419Wiberg, K.B., (1965) Oxidation in Organic Chemistry, Part A, , Academic: New YorkCainelli, G., Cardillo, G., (1984) Chromium Oxidations in Organic Chemistry, , Springer-Verlag: BerlinDas, A.K., (2001) Oxid. Commun., 24, p. 321Beattie, J.K., Haight Jr., G.P., (1972) Prog. Inorg. Chem., 17, p. 93Fendorf, S., Wienlinga, B.W., Hansel, C.M., (2000) Int. Geol. Rev., 42, p. 691Smith, G.F., (1934) Ind. Eng. Chem. Anal. Edition, 6, p. 229Bobtelsky, M., Glasner, A., (1948) J. Chem. Soc., p. 1376Ho, W.-H., (1979) Proc. Natl. Sci. Counc. ROC, 4, p. 1Archundia, C., Collins, C.H., Collins, K.E., (1990) J. Radioanal. Nucl. Chem. Lett., 146, p. 49Archundia, C., Bonato, P.S., Lugo Rivera, J.F., Mascioli, L.C., Collins, C.H., Collins, K.E., (1993) Sci. Total Environ., 130-131, p. 231Archundia, C., Lugo Rivera, J.F., Collins, K.E., Collins, C.H., (1995) J. Radioanal. Nucl. Chem. Art., 195, p. 363Pezzin, S.H., Archundia, C., Collins, C.H., Collins, K.E., (1997) Radiochim. Acta, 77, p. 91Khan, Z., Hashmi, A.A., Din, K., (1998) Transition Met. Chem., 23, p. 147Pezzin, S.H., Collins, C.H., Archundia, C., Collins, K.E., (1998) J. Radioanal. Nucl. Chem., 236, p. 209Pezzin, S.H., Archundia, C., Collins, K.E., Collins, C.H., (2000) Czech. J. Phys., 50, p. 315Pezzin, S.H., Collins, C.H., Collins, K.E., (2000) Proceedings of the National Meeting on Nuclear Applications, , Rio de Janeiro, Brazil, CD-ROM, paper no. 61Pavel, J., Kliment, J., Stoerk, S., Suter, O., (1985) Fresenius Z. Anal. Chem., 321, p. 587Stollenwerk, K.G., Grove, D.B., (1985) J. Environ. Qual., 14, p. 386Gil, M., Escolar, D., Iza, N., Montero, J.L., (1986) Appl. Spectrosc., 40, p. 1156Tong, J.Y.P., King, E.L., (1960) J. Am. Chem. Soc., 82, p. 3805Espenson, J.H., King, E.L., (1963) J. Am. Chem. Soc., 85, p. 3328Khan, Z., Din, K., (2001) Indian J. Chem., 40 A, p. 528Haight Jr., G.P., Richardson, D.C., Coburn, N.H., (1964) Inorg. Chem., 3, p. 1777Espenson, J.H., (1964) J. Am. Chem. Soc., 86, p. 5101Pezzin, S.H., Collins, C.H., Collins, K.E., (2001) Radiochim. Acta, 89, p. 845House, D.A., (1994) Mechanisms of Inorganic and Organometallic Reactions, p. 97. , Twigg, M. V., ed.Plenum: New YorkSena, M.M., Scarminio, I.S., Collins, K.E., Collins, C.H., (2000) Talanta, 53, p. 453Cruywagen, J.J., Heyns, J.B.B., Rohwer, E.A., (1998) Polyhedron, 17, p. 1741Brito, F., Ascanio, J., Mateo, S., Hernandez, C., Araujo, L., Gili, P., MartinZarza, P., Mederos, A., (1997) Polyhedron, 16, p. 3835Nriagu, J.O., Nieboer, E., (1988) Chromium in the Natural and Human Environments, , Wiley: New YorkCollins, C.H., Pezzin, S.H., Lugo Rivera, J.F., Bonato, P.S., Windmöller, C., Archundia, C., Collins, K.E., (1997) J. Chromatogr. A, 789, p. 469Marques, M.J., Salvador, A., Morales-Rubio, A., De La Guardia, M., (2000) Fresenius. J. Anal. Chem., 367, p. 601Collins, K.E., Bonato, P.S., Archundia, C., De Queiroz, M.E.L.R., Collins, C.H., (1988) Chromatographia, 26, p. 160Collins, C.H., Collins, K.E., Ackerhalt, R.E., (1971) J. Radioanal. Chem., 8, p. 263De Andrade, J.C., Collins, K.E., (1981) Quim. Nova, 4, p. 89Gates, H.S., King, E.L., (1958) J. Am. Chem. Soc., 80, p. 5011Autenrieth, W., (1902) Ber. Deutsch. Chem. Ges., 35, p. 2057Krauss, H.L., Leder, M., Münster, G., (1963) Chem. Ber., 96, p. 3008Finholt, J.E., Ph.D. Thesis, Lawrence Radiation Laboratory Report UCRL-8879, University of California, Berkeley, 1960Collins, C.H., Lanças, F.M., (1982) Radiochem. Radioanal. Letters, 19, p. 117Jones, K.M., Bjerrum, J., (1965) Acta Chem. Scand., 19, p. 974Aggett, J., Udy, D.J., (1970) J. Inorg. Nucl. Chem., 32, p. 2802Chaabouni, M., Chausse, T., Pascal, J.L., Potier, J., (1980) J. Chem. Res. (S), 72Archundia, C., Collins, C.H., Collins, K.E., (1988) Proceedings of the Second General Congress on Nuclear Energy, 2, p. 415. , Rio de Janeiro, BrazilStünzi, H., Marty, W., (1983) Inorg. Chem., 22, p. 2145(1985) Chemical Analysis of Metals and Metal-Bearing Ores, , Annual Book of ASTM Standards, Section 3, Vol.03.05, American Society for Testing and MaterialsPhiladelphiaOttaway, J.M., Fell, G.S., (1986) Pure Appl. Chem., 58, p. 170

    EVALUATIONS OF URANIUM MONONITRIDE CERMET FUEL.

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    Soft-gluon effects in WW production at hadron colliders

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    We consider QCD radiative corrections to WW pair production in hadron collisions. We perform a calculation that consistently combines next-to-leading order predictions with soft-gluon resummation valid at small transverse momenta ptWW of the WW pair. We present results for the ptWW distribution at the LHC up to (almost) next-to-next-to-leading logarithmic accuracy, and study the effect of resummation on the charged-lepton distributions. Soft-gluon effects are typically mild, but they can be strongly enhanced when hard cuts are applied. The relevant distributions are generally well described by the MC@NLO event generator.Comment: 15 pages, 12 postscript figures. Error corrected in NLO plot for WW transverse-mass distribution. Results unchange

    Qubits from Number States and Bell Inequalities for Number Measurements

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    Bell inequalities for number measurements are derived via the observation that the bits of the number indexing a number state are proper qubits. Violations of these inequalities are obtained from the output state of the nondegenerate optical parametric amplifier.Comment: revtex4, 7 pages, v2: results identical but extended presentation, v3: published versio

    Higher-Order QCD Corrections to Inclusive Particle Production in p anti-p Collisions

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    Inclusive single-particle production cross sections have been calculated including higher-order QCD corrections. Transverse-momentum and rapidity distributions are presented and the scale dependence is studied. The results are compared with experimental data from the CERN S(p anti-p)S Collider and the Fermilab Tevatron.Comment: 28 pages, [12 uuencoded PS figures, 3 available under request]. Preprint DESY 92-13

    QCD Factorized Drell-Yan Cross Section at Large Transverse Momentum

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    We derive a new factorization formula in perturbative quantum chromodynamics for the Drell-Yan massive lepton-pair cross section as a function of the transverse momentum QTQ_T of the pair. When QTQ_T is much larger than the pair's invariant mass QQ, this factorization formula systematically resums the logarithmic contributions of the type αsmlnm(QT2/Q2)\alpha_s^m \ln^m(Q_T^2/Q^2) to all orders in the strong coupling αs\alpha_s. When QTQQ_T\sim Q, our formula yields the same Drell-Yan cross section as conventional fixed order QCD perturbation theory. We show that resummation is important when the collision energy S\sqrt{S} is large enough and QTQQ_T\gg Q, and we argue that perturbative expansions are more stable and reliable in terms of the modified factorization formula.Comment: 36 pages, latex, including 16 figure

    Differential Equations for Definition and Evaluation of Feynman Integrals

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    It is shown that every Feynman integral can be interpreted as Green function of some linear differential operator with constant coefficients. This definition is equivalent to usual one but needs no regularization and application of RR-operation. It is argued that presented formalism is convenient for practical calculations of Feynman integrals.Comment: pages, LaTEX, MSU-PHYS-HEP-Lu2/9

    Virtual photon fragmentation functions

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    We introduce operator definitions for virtual photon fragmentation functions, which are needed for reliable calculations of Drell-Yan transverse momentum (QTQ_T) distributions when QTQ_T is much larger than the invariant mass QQ. We derive the evolution equations for these fragmentation functions. We calculate the leading order evolution kernels for partons to fragment into a unpolarized as well as a polarized virtual photon. We find that fragmentation functions to a longitudinally polarized virtual photon are most important at small zz, and the fragmentation functions to a transversely polarized virtual photon dominate the large zz region. We discuss the implications of this finding to the J/ψ\psi mesons' polarization at large transverse momentum.Comment: Latex, 19 pages including 6 figures. An error in the first version has been corrected, and references update

    Azimuthal correlation in DIS

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    We introduce the azimuthal correlation for the deep inelastic scattering process. We present the QCD prediction to the level of next-to-leading log resummation, matching to the fixed order prediction. We also estimate the leading non-perturbative power correction. The observable is compared with the energy-energy correlation in e+e- annihilation, on which it is modelled. The effects of the resummation and of the leading power correction are both quite large. It would therefore be particularly instructive to study this observable experimentally.Comment: 33 pages, 4 figures, JHEP class included. One figure and some clarifications adde
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