819 research outputs found

    Varieties of firm: complementarity and bounded diversity

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    This is a study of the nature of internal diversity within liberal and collaborative market economies. Based on large scale comparative survey data, we assess the extent to which specific clusters of practices are associated with specific varieties of capitalism. Given that recent literature has pointed to internal diversity within specific national contexts, we explore the nature of internal diversity within both liberal and collaborative market economies, and what makes each variety of capitalism distinct. We find that more than one cluster of practices is indeed likely to be encountered in a particular national context, but that this diversity was bounded: only a limited number of alternative paradigms are likely to emerge and persist. The survey findings not only shed light on the nature of this internal diversity, but also reveal the fact that liberal and collaborative markets remain distinct, with the rights accruing to employees being more deeply embedded in a wide cross section of firms within the latter

    Elasticity-Dependent Self-assembly of Micro-Templated Chromonic Liquid Crystal Films

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    We explore micropatterned director structures of aqueous lyotropic chromonic liquid crystal (LCLC) films created on square lattice cylindrical-micropost substrates. The structures are manipulated by modulating the LCLC mesophases and their elastic properties via concentration through drying. Nematic LCLC films exhibit preferred bistable alignment along the diagonals of the micropost lattice. Columnar LCLC films, dried from nematics, form two distinct director and defect configurations: a diagonally aligned director pattern with local squares of defects, and an off-diagonal configuration with zig-zag defects. The formation of these states appears to be tied to the relative splay and bend free energy costs of the initial nematic films. The observed nematic and columnar configurations are understood numerically using a Landau-de Gennes free energy model. Among other attributes, the work provide first examples of quasi-2D micropatterning of LC films in the columnar phase and lyotropic LC films in general, and it demonstrates alignment and configuration switching of typically difficult-to-align LCLC films via bulk elastic properties.Comment: 9 pages; 9 figures; accepted for publication in Soft Matte

    Deposition And Drying Dynamics Of Liquid Crystal Droplets

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    Drop drying and deposition phenomena reveal a rich interplay of fundamental science and engineering, give rise to fascinating everyday effects (coffee rings), and influence technologies ranging from printing to genotyping. Here we investigate evaporation dynamics, morphology, and deposition patterns of drying lyotropic chromonic liquid crystal droplets. These drops differ from typical evaporating colloidal drops primarily due to their concentration-dependent isotropic, nematic, and columnar phases. Phase separation occurs during evaporation, and in the process creates surface tension gradients and significant density and viscosity variation within the droplet. As a result, the drying multiphase drops exhibit different convective currents, drop morphologies, and deposition patterns (coffee-rings)

    Effective index of refraction, optical rotation, and circular dichroism in isotropic chiral liquid crystals

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    This paper concerns optical properties of the isotropic phase above the isotropic-cholesteric transition and of the blue phase BP III. We introduce an effective index, which describes spatial dispersion effects such as optical rotation, circular dichroism, and the modification of the average index due to the fluctuations. We derive the wavelength dependance of these spatial dispersion effects quite generally without relying on an expansion in powers of the chirality and without assuming that the pitch of the cholesteric PP is much shorter than the wavelength of the light λ\lambda, an approximation which has been made in previous studies of this problem. The theoretical predictions are supported by comparing them with experimental spectra of the optical activity in the BP III phase.Comment: 15 pages and 7 figures. Submitted to PR

    The critical current density of advanced internal-Mg-diffusion-processed MgB2 wires

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    Recent advances in MgB2 conductors are leading to a new level of performance. Based on the use of proper powders, proper chemistry, and an architecture which incorporates internal Mg diffusion (IMD), a dense MgB2 structure with not only a high critical current density Jc, but also a high engineering critical current density, Je, can be obtained. In this paper, a series of these advanced (or second - generation, "2G") conductors has been prepared. Scanning electron microscopy and associated energy dispersive X-ray spectroscopy were applied to characterize the microstructures and compositions of the wires, and a dense MgB2 layer structure was observed. The best layer Jc for our sample is 1.07x105 A/cm2 at 10 T, 4.2 K, and our best Je is seen to be 1.67x104 A/cm2 at 10 T, 4.2 K. Optimization of the transport properties of these advanced wires is discussed in terms of B-powder choice, area fraction, and the MgB2 layer growth mechanism.Comment: 13 pages, 3 tables, 7 figures (or 8 pp in published version

    Associations of social and economic and pregnancy exposures with blood pressure in UK White British and Pakistani children age 4/5.

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    South Asians have higher rates of coronary heart disease (CHD) than White European individuals. Blood pressure (BP) is one of the most important risk factors for CHD and ethnic differences in BP have been identified in childhood. Early life exposures could explain some of these differences. We examined associations of family social and economic and maternal pregnancy exposures and BP at age 4/5 in 1644 White British and 1824 Pakistani mother-offspring pairs from the Born in Bradford study. We found that systolic BP was similar but diastolic BP was higher, in Pakistani compared to White British children (adjusted mean differences were -0.170 mmHg 95% CI -0.884, 0.543 for systolic BP; 1.328 mmHg 95% CI 0.592, 2.064 for diastolic BP). Social and economic exposures were not associated with BP in either ethnic group. Maternal BMI was positively associated with BP in both groups but this association was mediated by child BMI. Only gestational hypertension was associated with child systolic and diastolic BP and this was only identified in Pakistani mother-offspring pairs. These findings suggest that Pakistani populations may have a different BP trajectory compared to White British groups and that this is already evident at age 4/5 years

    Columnar Molecular Aggregation In The Aqueous Solutions Of Disodium Cromoglycate

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    Stack, chimneylike, and threadlike assemblies have previously been proposed for the structure of disodium cromoglycate (DSCG) aggregates in aqueous solutions. The results of the synchrotron x-ray scattering investigations reported here reveal the formation of simple columnar assemblies with pi-pi stacking at a separation of 3.4 angstrom between the DSCG molecules. Lateral separation between the assemblies is concentration and temperature dependent, varying from similar to 35 to 42 angstrom in the orientationally ordered nematic (N) phase and from 27 to 32 angstrom in the columnar or middle (M) phase having long range lateral positional order. The assemblies\u27 length depends on concentration and consists of similar to 23 molecules in the N phase, becoming three to ten times larger in the M phase. The scission energy is concentration dependent in the N phase with values similar to 7.19 +/- 0.14 k(B)T (15 wt%), 2.73 +/- 0.4 k(B)T (20 wt%), and 3.05 +/- 0.2 k(B)T (25 wt%). Solutions of all concentrations undergo a spinodal decomposition at temperatures above similar to 40 degrees C, resulting in DSCG-rich regions with the M phase and water-rich regions in the N and isotropic phases
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