Bistable molecular conductors with a field-switchable dipole group

A class of bistable "stator-rotor" molecules is proposed, where a stationary bridge (stator) connects the two electrodes and facilitates electron transport between them. The rotor part, which has a large dipole moment, is attached to an atom of the stator via a single sigma bond. Hydrogen bonds formed between the rotor and stator make the symmetric orientation of the dipole unstable. The rotor has two potential minima with equal energy for rotation about the sigma bond. The dipole orientation, which determines the conduction state of the molecule, can be switched by an external electric field that changes the relative energy of the two potential minima. Both orientation of the rotor correspond to asymmetric current-voltage characteristics that are the reverse of each other, so they are distinguishable electrically. Such bistable stator-rotor molecules could potentially be used as parts of molecular electronic devices.Comment: 8 pages, 7 figure

A framework for defining seagrass habitat for the Great Barrier Reef, Australia

This report describes a framework to define seagrass habitat and seagrass desired state for the Great Barrier Reef (GBR). We developed this by defining assessment zones using key physical attributes for the GBR. The assessment zones were developed with two main objectives: (1) to assess the representativeness of existing seagrass data throughout the GBR; and (2) to provide a framework in which to develop seagrass desired state (i.e. condition targets). We defined assessment zones using spatial data that reflect environmental and benthic condition likely to affect seagrass distribution, diversity and density. These include: (1) latitude, defined as regions using 6 Natural Resource Management (NRM) boundaries, (2) influence from and proximity to land (estuarine, coastal, reef, and offshore water bodies), and (3) water depth (intertidal, shallow subtidal 10m) resulting in 68 zones for the GBR. The largest assessment zone was the offshore water body in every region. Deep subtidal was the largest depth zone in coastal, reef, and offshore waters in each region. The estuarine deep subtidal zone was limited. Zones are seagrass-centric and not analogous to the Great Barrier Reef Marine Park zoning. Data from extensive seagrass surveys and long-term monitoring across the GBR since the early 1980s provides information on seagrass presence/absence, species composition, abundance, and spatial extent. Data rich areas include coastal and estuarine intertidal and shallow subtidal zones. Data from reef and offshore zones, and in deep subtidal zones, are more limited as it comes from sporadic one-off surveys and few meadows have been mapped. Available seagrass data ranges from sporadic large-scale survey data with low to medium spatial and low temporal resolution, to high spatial and high temporal resolution data collected seasonally at discrete sites. Defining these assessment zones is a critical first step in defining habitat types and quantifying desired state for GBR seagrasses. Habitat attributes not included in the zones, such as sediment type and exposure to wind and waves, as well as new seagrass biomass data will be used to update the framework, turning it into a full habitat assessment for defining desired state. A case study based in Cleveland Bay, as well as previous research, will be used to identify how this framework will be updated. Seagrass desired state is an ecological target that can be used to assess the effectiveness of management strategies to protect seagrass of the GBR. Desired state analysis requires data with medium to high spatial and temporal resolution that allows assessment in the context of disturbance events, recovery trajectories, and seasonal fluctuations. Robust analysis will be restricted to locations within zones where continuous data collection has occurred, e.g. the Marine Monitoring Program (MMP) and Queensland Ports Seagrass Monitoring Program (QPSMP), and for an adequate time span (generally >10 years)

Simultaneous observation of chorus and hiss near the plasmapause

On 4 August 2010 a moderate geomagnetic storm occurred with minimum Dst of −65 nT and maximum Kp of 7−. Shortly after the onset of this storm, VLF chorus was observed at Marion Island (L= 2.6). Over time the spectral structure of the chorus transformed into a hiss band spanning the same frequency range. The observation of overlapping chorus and hiss suggests that Marion Island was close to the plasmapause at the time of this event, and provides ground-based observational confirmation of the generation mechanism of plasmaspheric hiss from chorus waves outside of the plasmasphere. Chorus observations at Marion Island were not common during this period of the solar cycle and so this event was investigated in detail. The geomagnetic conditions are discussed and geosynchronous particle data and broadband data from two other stations are presented. Empirical models are employed to predict the location of the plasmapause, and its location is inferred from a knee whistler recorded at Dunedin, New Zealand. These show that Marion Island is in the vicinity of the plasmapause during the event. The event is also compared to chorus observed at similarL after the Halloween storms of 2003. The rarity of the chorus observation is quantified using DEMETER VLF data. The DEMETER data, along with the various ground based VLF measurements, allows us to infer temporal and spatial variations in the chorus source region

Crystal field splitting on D↔S transitions of atomic manganese isolated in solid krypton

Narrow excitation features present on the [Ar]3d⁶4s¹ a⁶D(J=9/2–1/2)←[Ar]3d⁵4s² a⁶S1/2 transitions of manganese atoms isolated in solid Kr are analyzed within the framework of weak crystal field splitting. Use of the Wp optical lineshape function allowed identification of multiple zero-phonon lines for individual spin-orbit J states of the a⁶D←a⁶S transition recorded with laser-induced excitation spectroscopy. Excellent agreement exists between the predicted crystal field splitting patterns for the J levels of the a⁶D state isolated in the «red» tetravacancy site of solid Kr. The tetrahedral crystal field of the «red» trapping site splits J>3/2 levels of the a⁶DJ and a⁴D₇/₂ states by approximately 30 cm⁻¹. This report represents the first definitive evidence of crystal field splitting, induced by the weak van der Waals interactions between a neutral metal atom and the rare gas atoms surrounding it in a well defined solid state site

Cerebrospinal fluid volume and nerve root vulnerability during lumbar puncture or spinal anaesthesia at different vertebral levels

[EN]Cerebrospinal fluid (CSF) and nerve root volumes within the lumbosacral dural sac were estimated at various vertebral levels, in an attempt to determine any possible relevance to the incidence of nerve root trauma during lumbar puncture or spinal anaesthesia. Magnetic resonance images from seven patients were studied. Volumes were calculated by semi-automatic threshold segmentation combined with manual editing of each slice. The mean dural sac volume from S1 to T12 was 42.8±5.8 ml and the mean CSF volume 34.3±5.1 ml with the mean root volume being 10.4±2.2 cm3 . The mean CSF volume per vertebral segment ranged from 4.3±0.7 ml at L5, to 5.8±2.5 ml at L1, with high inter-individual variability. The mean root volume ranged from 0.6±0.1 cm3 at L5 to 2.4±0.5 cm3 at T12. The conus medullaris was located at L1 in four of the five patients scanned at upper lumbar levels, and at the lower border of L2 in the other. Vulnerability to nerve root damage was expressed as the Vulnerability Index (%), being defined as the ratio of root volume to dural sac volume (CSF volume + root volume). The value ranged between 7 and 14% at L5, increasing rostrally to 30 to 43% at T12. Caution is obviously required in high punctures to avoid contact with the conus medullaris, but the cauda equina is also vulnerable to contact with more caudal punctures and had a Vulnerability Index of about 25% at L4, that increased rostrally

Parents, children and the porous boundaries of the sexual family in law and popular culture

This article focuses on a perceived ideological overlap between popular cultural and judicial treatments of sex and conjugality that contributes to a discursive construction of parenthood and parenting. The author perceives that in both legal and popular cultural texts, there is a sense in which notions of ‘natural’ childhood are discursively constituted as being put at risk by those who reproduce outside of dominant sexual norms, and that signs of normative sexuality (typically in the form of heterosexual coupling) may be treated as a sign of safety. These ideas are rooted in ancient associations between fertility, sexuality and femininity that can also be traced in the historical development of the English language. With the help of commentators such as Martha Fineman, the article situates parents and children within a discourse of family which prioritises conjugality, with consequences for the ways in which the internal and external boundaries of families are delineated

Elastic Scattering of Pions From the Three-nucleon System

We examine the scattering of charged pions from the trinucleon system at a pion energy of 180 MeV. The motivation for this study is the structure seen in the experimental angular distribution of back-angle scattering for pi+ 3He and pi- 3H but for neither pi- 3He nor pi+ 3H. We consider the addition of a double spin flip term to an optical model treatment and find that, though the contribution of this term is non-negligible at large angles for pi+ 3He and pi- 3H, it does not reproduce the structure seen in the experiment.Comment: 15 pages + 5 figure

Current Profiles of Molecular Nanowires; DFT Green Function Representation

The Liouville-space Green function formalism is used to compute the current density profile across a single molecule attached to electrodes. Time ordering is maintained in real, physical, time, avoiding the use of artificial time loops and backward propagations. Closed expressions for molecular currents, which only require DFT calculations for the isolated molecule, are derived to fourth order in the molecule/electrode coupling.Comment: 21 page

Active Galaxies in the UV

In this article we present different aspects of AGN studies demonstrating the importance of the UV spectral range. Most important diagnostic lines for studying the general physical conditions as well as the metalicities in the central broad line region in AGN are emitted in the UV. The UV/FUV continuum in AGN excites not only the emission lines in the immediate surrounding but it is responsible for the ionization of the intergalactic medium in the early stages of the universe. Variability studies of the emission line profiles of AGN in the UV give us information on the structure and kinematics of the immediate surrounding of the central supermassive black hole as well as on its mass itself.Comment: 29 pages, 13 figures, Ap&SS in pres

Acetalated Dextran Microparticles for Codelivery of STING and TLR7/8 Agonists

Vaccines are the most effective tool for preventing infectious diseases; however, subunit vaccines, considered the safest type, suffer from poor immunogenicity and require adjuvants to create a strong and sustained immune response. As adjuvants, pathogen-associated molecular patterns (PAMPs) offer potent immunostimulatory properties and defined mechanisms of action through their cognate pattern recognition receptors (PRRs). Their activity can be further enhanced through combining two or more PAMPs, particularly those that activate multiple immune signaling pathways. However, the cytosolic localization of many PRRs requires intracellular delivery of PAMPs for optimal biological activity, which is particularly true of the stimulator of interferon genes (STING) PRR. Using acetalated dextran (Ace-DEX) microparticles (MPs) encapsulating STING agonist 3′3′-cyclic GMP-AMP (cGAMP) combined with soluble PAMPS, we screened the effect of codelivery of adjuvants using primary mouse bone marrow derived dendritic cells (BMDCs). We identified that codelivery of cGAMP MPs and soluble Toll-like receptor 7/8 (TLR7/8) agonist resiquimod (R848) elicited the broadest cytokine response. cGAMP and R848 were then coencapsulated within Ace-DEX MPs via electrospray. Using the model antigen ovalbumin, we observed that Ace-DEX MPs coencapsulating cGAMP and R848 (cGAMP/R848 Ace-DEX MPs) induced antigen-specific cellular immunity, and a balanced Th1/Th2 humoral response that was greater than cGAMP Ace-DEX MPs alone and PAMPs delivered in separate MPs. These data indicate that polymeric Ace-DEX MPs loaded with STING and TLR7/8 agonists represent a potent cellular and humoral vaccine adjuvant