Cruise Report 71-S-7: Crab

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Cavity ringdown laser absorption spectroscopy and time-of-flight mass spectroscopy of jet-cooled silver silicides

The cavity ringdown technique has been employed for the first spectroscopic characterization of the AgSi molecule, which is generated in a pulsed laser vaporization plasma reactor. A total of 20 rovibronic bands between 365 and 385 nm have been measured and analyzed to yield molecular properties for the X, B, and C 2Sigma states of AgSi. A time-of-flight mass spectrometer simultaneously monitors species produced in the molecular beam and has provided the first direct evidence for the existence of polyatomic silver silicides. Comparison of the AgSi data to our recent results for the CuSi diatom reveals very similar chemical bonding in the two coinage metal silicides, apparently dominated by covalent interactions

High aspect ratio silicon dioxide-coated single-walled carbon nanotube scanning probe nanoelectrodes

We have fabricated high aspect ratio, hydrophilic nanoelectrodes from individual single-walled carbon nanotubes (SWNTs) mounted on conductive atomic force microscope (AFM) tips for use as electrochemical probes. Individual SWNTs with an average diameter of 5 nm and up to 1.5 μm in length were passivated with nanometer-thick SiO_2 films, deposited conformally in an inductively coupled plasma reactor. The electrically insulating SiO_2 films improved the nanotube rigidity and stabilized the nanotube−AFM tip contact to enable use in aqueous environments. The nanotube tip was successfully exposed by subjecting the probe to nanosecond electrical pulse etching but only after electron beam irradiation in a transmission electron microscope (TEM). Probe functionality was verified by electrodepositing gold nanoparticles from aqueous solution only at the exposed tip

Nanopencil as a wear-tolerant probe for ultrahigh density data storage

A dielectric-sheathed carbon nanotube probe, resembling a “nanopencil,” has been fabricated by conformal deposition of silicon-oxide on a carbon nanotube and subsequent “sharpening” to expose its tip. The high aspect-ratio nanopencil probe takes advantage of the small nanotube electrode size, while avoiding bending and buckling issues encountered with naked or polymer-coated carbon nanotube probes. Since the effective electrode diameter of the probe would not change even after significant wear, it is capable of long-lasting read/write operations in contact mode with a bit size of several nanometers

Estimating the masses of extra-solar planets

All extra-solar planet masses that have been derived spectroscopically are lower limits since the inclination of the orbit to our line-of-sight is unknown except for transiting systems. It is, however, possible to determine the inclination angle, i, between the rotation axis of a star and an observer's line-of-sight from measurements of the projected equatorial velocity (v sin i), the stellar rotation period (P_rot) and the stellar radius (R_star). This allows the removal of the sin i dependency of spectroscopically derived extra-solar planet masses under the assumption that the planetary orbits lie perpendicular to the stellar rotation axis. We have carried out an extensive literature search and present a catalogue of v sin i, P_rot, and R_star estimates for exoplanet host stars. In addition, we have used Hipparcos parallaxes and the Barnes-Evans relationship to further supplement the R_star estimates obtained from the literature. Using this catalogue, we have obtained sin i estimates using a Markov-chain Monte Carlo analysis. This allows proper 1-sigma two-tailed confidence limits to be placed on the derived sin i's along with the transit probability for each planet to be determined. While a small proportion of systems yield sin i's significantly greater than 1, most likely due to poor P_rot estimations, the large majority are acceptable. We are further encouraged by the cases where we have data on transiting systems, as the technique indicates inclinations of ~90 degrees and high transit probabilities. In total, we estimate the true masses of 133 extra-solar planets. Of these, only 6 have revised masses that place them above the 13 Jupiter mass deuterium burning limit. Our work reveals a population of high-mass planets with low eccentricities and we speculate that these may represent the signature of different planetary formation mechanisms at work.Comment: 40 pages, 6 tables, 2 figures. Accepted for publication in the Monthly Notices of the Royal Astronomical Society after editing of Tables 1 & 6 for electronic publication. Html abstract shortened for astro-ph submissio

Fully inverted single-digit nanometer domains in ferroelectric films

Achieving stable single-digit nanometer inverted domains in ferroelectric thin films is a fundamental issue that has remained a bottleneck for the development of ultrahigh density (>1 Tbit/in.^2) probe-based memory devices using ferroelectric media. Here, we demonstrate that such domains remain stable only if they are fully inverted through the entire ferroelectric film thickness, which is dependent on a critical ratio of electrode size to the film thickness. This understanding enables the formation of stable domains as small as 4 nm in diameter, corresponding to 10 unit cells in size. Such domain size corresponds to 40 Tbit/in.^2 data storage densitie

The resilience of indigenous knowledge in small-scale African agriculture: key drivers

The successful use of indigenous knowledge (IK) in development practice in rural Africa over the last couple of decades has proved to be elusive and disappointing. Using empirical field data from northern Malawi, this study suggests that the two key drivers for farmers in this area are household food security and the maintenance of soil fertility. Indigenous ways of knowing underpin the agricultural system which has been developed, rather than the adoption of more modern, ‘scientific’ ways, to deliver against these drivers. Such IKs, however, are deeply embedded in the economic, social and cultural environments in which they operate

On the ground electronic states of copper silicide and its ions

The low-lying electronic states of SiCu, SiCu^+, and SiCu^− have been studied using a variety of high-level ab initio techniques. As expected on the basis of simple orbital occupancy and bond forming for Si(s^2p^2)+Cu(s^1) species, ^2Π_r, ^1Σ^+, and ^3Σ^− states were found to be the ground electronic states for SiCu, SiCu^+, and SiCu^−, respectively; the ^2Π_r state is not that suggested in most recent experimental studies. All of these molecules were found to be quite strongly bound although the bond lengths, bond energies, and harmonic frequencies vary slightly among them, as a result of the nonbonding character of the 2π-MO (molecular orbital) [composed almost entirely of the Si 3p-AO (atomic orbital)], the occupation of which varies from 0 to 2 within the ^1Σ^+, ^2Π_r, and ^3Σ^− series. The neutral SiCu is found to have bound excited electronic states of ^4Σ^−, ^2Δ, ^2Σ^+, and ^2Π_i symmetry lying 0.5, 1.2, 1.8, and 3.2 eV above the ^2Π_r ground state. It is possible but not yet certain that the ^2Π_i state is, in fact, the “B state” observed in the recent experimental studies by Scherer, Paul, Collier, and Saykally