tert-Butyl 5-methoxy-3-pentylindole-1-carboxylate

he molecule of the title compound, C₁₉H₂₇NO₃, is essentially planar, with all non-H atoms within 0.2 Å of the nine-membered indole plane, except for the three tert-butyl C atoms. The C₅ pentyl chain is in an extended conformation, with three torsion angles of 179.95 (13), 179.65 (13) and -178.95 (15)° (the latter two angles include the C atoms of the C5 chain only). Three intramolecular C-H...O=C contacts are present (C...O 115°), and an intermolecular C-H...O=C contact and π-π stacking complete the intermolecular interactions

Observing IMBH-IMBH Binary Coalescences via Gravitational Radiation

Recent numerical simulations have suggested the possibility of forming double intermediate mass black holes (IMBHs) via the collisional runaway scenario in young dense star clusters. The two IMBHs formed would exchange into a common binary shortly after their birth, and quickly inspiral and merge. Since space-borne gravitational wave (GW) observatories such as LISA will be able to see the late phases of their inspiral out to several Gpc, and LIGO will be able to see the merger and ringdown out to similar distances, they represent potentially significant GW sources. In this Letter we estimate the rate at which LISA and LIGO will see their inspiral and merger in young star clusters, and discuss the information that can be extracted from the observations. We find that LISA will likely see tens of IMBH--IMBH inspirals per year, while advanced LIGO could see ~10 merger and ringdown events per year, with both rates strongly dependent on the distribution of cluster masses and densities.Comment: Accepted for publication in ApJL. Minor changes to reflect accepted version. 4 pages in emulateapj, 3 figure

Optical fiber cable chemical stripping fixture

An elongated fixture handle member is connected to a fixture body member with both members having interconnecting longitudinal central axial bores for the passage of an optical cable therethrough. The axial bore of the fixture body member, however, terminates in a shoulder stop for the outer end of a jacket of the optical cable covering both an optical fiber and a coating therefor, with an axial bore of reduced diameter continuing from the shoulder stop forward for a predetermined desired length to the outer end of the fixture body member. A subsequent insertion of the fixture body member including the above optical fiber elements into a chemical stripping solution results in a softening of the exposed external coating thereat which permits easy removal thereof from the optical fiber while leaving a desired length coated fiber intact within the fixture body member

6-(4-Fluorophenyl)-8-phenyl-2,3-dihydro-4H-imidazo[5,1-b][1,3]thiazin-4-one: an unusual [6-5] fused-ring system

The title compound, C₁₈H₁₃FN₂OS, is the first structural example of a [6-5] fused ring incorporating the 2,3-dihydro-4H-imidazo[5,1-b][1,3]thiazin-4-one molecular scaffold. The six-membered 2,3-dihydro-1,3-thiazin-4-one ring adopts an envelope conformation, with the S-CH₂ C atom displaced by 0.761 (2) Å from the five-atom plane (all within 0.05 Å of the mean plane). The imidazole ring is planar. The phenyl ring is twisted from coplanarity with the imidazole ring by 23.84 (5)° and the 4-fluorophenyl ring is twisted by 53.36 (6)°, due to a close C(aryl)-H...O=C contact with the thiazin-4-one carbonyl O atom. The primary intermolecular interaction involves a CH₂ group with the F atom [C...F = 3.256 (2) Å and C-H...F = 137°]

The joint US/UK 1990 epoch world magnetic model

A detailed summary of the data used, analyses performed, modeling techniques employed, and results obtained in the course of the 1990 Epoch World Magnetic Modeling effort are given. Also, use and limitations of the GEOMAG algorithm are presented. Charts and tables related to the 1990 World Magnetic Model (WMM-90) for the Earth's main field and secular variation in Mercator and polar stereographic projections are presented along with useful tables of several magnetic field components and their secular variation on a 5-degree worldwide grid

General Relativistic Simulations of Magnetized Plasmas around Merging Supermassive Black Holes

Coalescing supermassive black hole binaries are produced by the mergers of galaxies and are the most powerful sources of gravitational waves accessible to space-based gravitational observatories. Some such mergers may occur in the presence of matter and magnetic fields and hence generate an electromagnetic counterpart. In this Letter, we present the first general relativistic simulations of magnetized plasma around merging supermassive black holes using the general relativistic magnetohydrodynamic code Whisky. By considering different magnetic field strengths, going from non-magnetically dominated to magnetically dominated regimes, we explore how magnetic fields affect the dynamics of the plasma and the possible emission of electromagnetic signals. In particular we observe a total amplification of the magnetic field of ~2 orders of magnitude which is driven by the accretion onto the binary and that leads to much stronger electromagnetic signals, more than a factor of 10^4 larger than comparable calculations done in the force-free regime where such amplifications are not possible.Comment: 7 pages, 5 figures. Minor changes to match version accepted for publication on The Astrophysical Journal Letter

Corn Seed Spacing Uniformity as Affected by Seed Tube Condition

Variation in corn seed spacing from a John Deere MaxEmergeTM Plus Vacumeter planter was evaluated on the University of Nebraska Planter Test Stand in a laboratory setting for two seed tube conditions (new or worn) with two examples of corn seed shape (round or flat). Seed spacing uniformity was measured using three seed spacing uniformity parameters: Coefficient of Precision (CP3), ISO Multiples index, and ISO Miss index. Differences were detected in all three seed spacing uniformity parameters due to the seed tube condition. The new seed tubes had better seed spacing uniformity than the worn seed tubes, within each example of the seed shapes (round or flat) used in this experiment. For the seed used in this experiment, the round corn seed had better seed spacing uniformity than the flat corn seed, within each of the seed tube conditions (new or worn). A recommended schedule for seed tube replacement to maintain seed spacing uniformity has not been developed, and more research in this area is needed. Currently, sugarbeet growers in western Nebraska use one of three options: a) test one of their seed tubes on a good planter test stand every year before sugarbeet planting season and replace all tubes when results indicate it will improve seed spacing uniformity to the desired level; b) feel the inside front surface of the seed tube every year before sugarbeet planting season and change seed tubes when the feel of the surface changes from a slick plastic to a very fine sandpaper; or c) replace seed tubes before sugarbeet planting season when they have planted over approximately 150 acres of corn per planter row with their current seed tubes

Creditor\u27s Rights in Ohio: An Extensive Revision

House Bill No. 254, effective August 26, 1982, involves a balancing of competing interests as well as an attempt to bring Ohio law into compliance with the procedural requirements mandated, on Constitutional grounds, by various U.S. Supreme Court cases. It involves a cost-benefit analysis because, in making decisions in this area, one must balance the costs associated with procedural requirements against the benefits afforded to consumers. The costs involved are costs to consumers, as there is little doubt that any costs associated with the procedural requirements in effect since August 26, 1982, will be borne by consumers. To be sure, financial institutions are subject to financial and regulatory constraints. However, given any reasonable assumptions about elasticity of demand, the financial institutions have the economic power to pass increased costs on. Of course, we are talking about primary demand, not selective demand; selective demand is not an issue since all financial institutions will be subject to procedural requirement of H.B. 254. As for regulation, this author is not aware of any regulations that would prevent financial institutions from passing the procedural cost on to consumers

Internal Frame Dragging and a Global Analog of the Aharonov-Bohm Effect

It is shown that the breakdown of a {\it global} symmetry group to a discrete subgroup can lead to analogues of the Aharonov-Bohm effect. At sufficiently low momentum, the cross-section for scattering of a particle with nontrivial $\Z_2$ charge off a global vortex is almost equal to (but definitely different from) maximal Aharonov-Bohm scattering; the effect goes away at large momentum. The scattering of a spin-1/2 particle off a magnetic vortex provides an amusing experimentally realizable example.Comment: (14 pp