Optical studies of two LMC X-ray transients : RX J0544.1-7100 and RX J0520.5-6932

We report observations which confirm the identities of the optical counterpart to the transient sources RX J0544.1-7100 and RX J0520.5-6932. The counterparts are suggested to be a B-type stars. Optical data from the observations carried out at ESO and SAAO, together with results from the OGLE data base, are presented. In addition, X-ray data from the RXTE all-sky monitor are investigated for long term periodicities. A strong suggestion for a binary period of 24.4d is seen in RX J0520.5-6932 from the OGLE data.Comment: 6 pages, 7 figure

In situ aerosol measurements taken during the 2007 COPS field campaign at the Hornisgrinde ground site

Copyright @ 2011 Royal Meteorological Society.The Convective and Orographically-induced Precipitation Study (COPS) campaign was conducted during the summer of 2007. A suite of instruments housed at the top of the Hornisgrinde Mountain (1156 m) in the Black Forest region of south-west Germany provided datasets that allow an investigation into the physical, chemical and hygroscopic properties of the aerosol particles sampled during COPS. Organic mass loadings were found to dominate the aerosol composition for the majority of the project, exceeding 8 µg m−3 during a period of high pressure, high temperature, and low wind speed. The ratio of organic:sulphate sub-micron mass concentration exceeds 10:1 during the same time period. Back trajectories show air from this time-frame passing slowly over the local forest and not passing over any local anthropogenic sources. Occasional peaks in nitrate mass loadings were associated with changes in the typical wind direction from south-westerly to north-westerly where air had passed over the Stuttgart region. Size distribution data shows a dominant accumulation-mode when the measurement site was free from precipitation events. A sharp increase in ultrafine particle number concentration was seen during most days commencing around noon. The apparent growth of these particles is associated with an increase in organic mass loading, suggesting condensational growth. For the most part, with the exception of the high pressure period, the aerosol properties recorded during COPS were comparable to previous studies of continental aerosol properties.NER

Improving Dark Energy Constraints with High Redshift Type Ia Supernovae from CANDELS and CLASH

Aims. We investigate the degree of improvement in dark energy constraints that can be achieved by extending Type Ia Supernova (SN Ia) samples to redshifts z > 1.5 with the Hubble Space Telescope (HST), particularly in the ongoing CANDELS and CLASH multi-cycle treasury programs. Methods. Using the popular CPL parametrization of the dark energy, w = w0 +wa(1-a), we generate mock SN Ia samples that can be projected out to higher redshifts. The synthetic datasets thus generated are fitted to the CPL model, and we evaluate the improvement that a high-z sample can add in terms of ameliorating the statistical and systematic uncertainties on cosmological parameters. Results. In an optimistic but still very achievable scenario, we find that extending the HST sample beyond CANDELS+CLASH to reach a total of 28 SN Ia at z > 1.0 could improve the uncertainty in the wa parameter by up to 21%. The corresponding improvement in the figure of merit (FoM) would be as high as 28%. Finally, we consider the use of high-redshift SN Ia samples to detect non-cosmological evolution in SN Ia luminosities with redshift, finding that such tests could be undertaken by future spacebased infrared surveys using the James Webb Space Telescope (JWST).Comment: 9 pages, 6 figures, accepted for publication on Astronomy & Astrophysic

SXP 7.92: A Recently Rediscovered Be/X-ray Binary in the Small Magellanic Cloud, Viewed Edge On

We present a detailed optical and X-ray study of the 2013 outburst of the Small Magellanic Cloud Be/X-ray binary SXP 7.92, as well as an overview of the last 18 years of observations from OGLE (Optical Gravitational Lensing Experiment), RXTE, Chandra and XMM-Newton. We revise the position of this source to RA(J2000) = 00:57:58.4, Dec(J2000) = −72:22:29.5 with a 1σ uncertainty of 1.5 arcsec, correcting the previously reported position by Coe et al. by more than 20 arcmin. We identify and spectrally classify the correct counterpart as a B1Ve star. The optical spectrum is distinguished by an uncharacteristically deep narrow Balmer series, with the Hα line in particular having a distinctive shell profile, i.e. a deep absorption core embedded in an emission line. We interpret this as evidence that we are viewing the system edge on and are seeing self-obscuration of the circumstellar disc. We derive an optical period for the system of 40.0 ± 0.3 d, which we interpret as the orbital period, and present several mechanisms to describe the X-ray/optical behaviour in the recent outburst, in particular the ‘flares'and ‘dips’ seen in the optical light curve, including a transient accretion disc and an elongated precessing disc

Diquat Derivatives: Highly Active, Two-Dimensional Nonlinear Optical Chromophores with Potential Redox Switchability

In this article, we present a detailed study of structure−activity relationships in diquaternized 2,2′-bipyridyl (diquat) derivatives. Sixteen new chromophores have been synthesized, with variations in the amino electron donor substituents, π-conjugated bridge, and alkyl diquaternizing unit. Our aim is to combine very large, two-dimensional (2D) quadratic nonlinear optical (NLO) responses with reversible redox chemistry. The chromophores have been characterized as their PF_6^− salts by using various techniques including electronic absorption spectroscopy and cyclic voltammetry. Their visible absorption spectra are dominated by intense π → π^* intramolecular charge-transfer (ICT) bands, and all show two reversible diquat-based reductions. First hyperpolarizabilities β have been measured by using hyper-Rayleigh scattering with an 800 nm laser, and Stark spectroscopy of the ICT bands affords estimated static first hyperpolarizabilities β_0. The directly and indirectly derived β values are large and increase with the extent of π-conjugation and electron donor strength. Extending the quaternizing alkyl linkage always increases the ICT energy and decreases the E_(1/2) values for diquat reduction, but a compensating increase in the ICT intensity prevents significant decreases in Stark-based β_0 responses. Nine single-crystal X-ray structures have also been obtained. Time-dependent density functional theory clarifies the molecular electronic/optical properties, and finite field calculations agree with polarized HRS data in that the NLO responses of the disubstituted species are dominated by ‘off-diagonal’ β_(zyy) components. The most significant findings of these studies are: (i) β_0 values as much as 6 times that of the chromophore in the technologically important material (E)-4′-(dimethylamino)-N-methyl-4-stilbazolium tosylate; (ii) reversible electrochemistry that offers potential for redox-switching of optical properties over multiple states; (iii) strongly 2D NLO responses that may be exploited for novel practical applications; (iv) a new polar material, suitable for bulk NLO behavior

Airborne observations of aerosol microphysical properties and particle ageing processes in the troposphere above Europe

In-situ measurements of aerosol microphysical properties were performed in May 2008 during the EUCAARI-LONGREX campaign. Two aircraft, the FAAM BAe-146 and DLR Falcon 20, operated from Oberpfaffenhofen, Germany. A comprehensive data set was obtained comprising the wider region of Europe north of the Alps throughout the whole tropospheric column. Prevailing stable synoptic conditions enabled measurements of accumulating emissions inside the continental boundary layer reaching a maximum total number concentration of 19 000 particles cm<sup>−3</sup> stp. Ultra-fine particles as indicators for nucleation events were observed within the boundary layer during high pressure conditions and after updraft of emissions induced by frontal passages above 8 km altitude in the upper free troposphere. Aerosol ageing processes during air mass transport are analysed using trajectory analysis. The ratio of particles containing a non-volatile core (250 °C) to the total aerosol number concentration was observed to increase within the first 12 to 48 h from the particle source from 50 to 85% due to coagulation. Aged aerosol also features an increased fraction of accumulation mode particles of approximately 40% of the total number concentration. The presented analysis provides an extensive data set of tropospheric aerosol microphysical properties on a continental scale which can be used for atmospheric aerosol models and comparisons of satellite retrievals