1,302 research outputs found

    Sintering Kinetics of Plasma-Sprayed Zirconia TBCs

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    A model of the sintering exhibited by EB-PVD TBCs, based on principles of free energy minimization, was recently published by Hutchinson et al. In the current paper, this approach is applied to sintering of plasma-sprayed TBCs and comparisons are made with experimental results. Predictions of through-thickness shrinkage and changing pore surface area are compared with experimental data obtained by dilatometry and BET analysis respectively. The sensitivity of the predictions to initial pore architecture and material properties are assessed. The model can be used to predict the evolution of contact area between overlying splats. This is in turn related to the through-thickness thermal conductivity, using a previously-developed analytical model

    Ice-lens formation and connement-induced supercooling in soils and other colloidal materials

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    We present a new, physically-intuitive model of ice-lens formation and growth during the freezing of soils and other dense, particulate suspensions. Motivated by experimental evidence, we consider the growth of an ice-filled crack in a freezing soil. At low temperatures, ice in the crack exerts large pressures on the crack walls that will eventually cause the crack to split open. We show that the crack will then propagate across the soil to form a new lens. The process is controlled by two factors: the cohesion of the soil, and the confinement-induced supercooling of the water in the soil; a new concept introduced to measure the energy available to form a new ice lens. When the supercooling exceeds a critical amount (proportional to the cohesive strength of the soil) a new ice lens forms. This condition for ice-lens formation and growth does not appeal to any ad hoc, empirical assumptions, and explains how periodic ice lenses can form with or without the presence of a frozen fringe. The proposed mechanism is in good agreement with experiments, in particular explaining ice-lens pattern formation, and surges in heave rate associated with the growth of new lenses. Importantly for systems with no frozen fringe, ice-lens formation and frost heave can be predicted given only the unfrozen properties of the soil. We use our theory to estimate ice-lens growth temperatures obtaining quantitative agreement with experiments. The theory is generalizable to complex natural-soil scenarios, and should therefore be useful in the prediction of macroscopic frost heave rates

    Study of the general mechanism of stress corrosion of aluminum alloys and development of techniques for its detection Annual summary report, 2 Jun. 1967 - 1 Jun. 1968

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    Stress corrosion cracking of high strength aluminum alloys investigated by electrochemical, mechanical, and electron microscopic technique

    Legume-Rhizobia Relationship in the Nitrogen Fixation of a New Mediterranean Pasture Legume (Biserrula Pelecinus L.)

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    Biserrula pelecinus (biserrula) is a pasture legume of Mediterranean climates. Because of its ability to survive on acidic and infertile soils, it has been introduced to southern Australia as a potential alternative or companion plant to serradella and subterranean clover. The successful introduction of this species will be reliant upon the selection of an appropriate inoculant strain of its root-nodule bacteria and understanding of its ecology. A selection of five rhizobial strains isolated from biserrula nodules collected in Sardinia and Greece were examined for their ability to nodulate and fix nitrogen with 3 genotypes of biserrula. Although all rhizobial strains nodulated all host genotypes of biserrula, great variability in capacity to fix nitrogen was evident. Distinct PCR amplification profiles were generated for individual rhizobial strains which confirmed the phenotypic variability of the strains. Attention needs to be given to the large host-strain variability for nitrogen fixation in this symbiosis before proceeding with agronomic evaluation

    Simultaneous description of four positive and four negative parity bands

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    The extended coherent state model is further extended in order to describe two dipole bands of different parities. The formalism provides a consistent description of eight rotational bands. A unified description for spherical, transitional and deformed nuclei is possible. Projecting out the angular momentum and parity from a sole state, the KĎ€=1+K^{\pi}=1^+ band acquires a magnetic character, while the electric properties prevail for the other band. Signatures for a static octupole deformation in some states of the dipole bands are pointed out. Some properties which distinguish between the dipole band states and states of the same parity but belonging to other bands are mentioned. Interesting features concerning the decay properties of the two bands are found. Numerical applications are made for 158^{158}Gd, 172^{172}Yb, 228,232^{228,232}Th, 226^{226}Ra, 238^{238}U and 238^{238}Pu, and the results are compared with the available data.Comment: 36 pages, 13 figures, 12 table

    "Beat" patterns for the odd-even staggering in octupole bands from a quadrupole-octupole Hamiltonian

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    We propose a collective Hamiltonian which incorporates the standard quadrupole terms, octupole terms classified according to the irreducible representations of the octahedron group, a quadrupole-octupole interaction, as well as a term for the bandhead energy linear in K (the projection of angular momentum on the body-fixed z-axis). The energy is subsequently minimized with respect to K for each given value of the angular momentum I, resulting in K values increasing with I within each band, even in the case in which K is restricted to a set of microscopically plausible values. We demonstrate that this Hamiltonian is able to reproduce a variety of ``beat'' patterns observed recently for the odd-even staggering in octupole bands of light actinides.Comment: LaTeX, 20 pages plus 12 figures given in separate .ps file

    Anxiety, anticipation and contextual information: a test of attentional control theory

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    We tested the assumptions of Attentional Control Theory (ACT) by examining the impact of anxiety on anticipation using a dynamic, time-constrained task. Moreover, we examined the involvement of high- and low-level cognitive processes in anticipation and how their importance may interact with anxiety. Skilled and less-skilled tennis players anticipated the shots of opponents under low- and high-anxiety conditions. Participants viewed three types of video stimuli, each depicting different levels of contextual information. Performance effectiveness (response accuracy) and processing efficiency (response accuracy divided by corresponding mental effort) were measured. Skilled players recorded higher levels of response accuracy and processing efficiency compared to less-skilled counterparts. Processing efficiency significantly decreased under high- compared to low-anxiety conditions. No difference in response accuracy was observed. When reviewing directional errors, anxiety was most detrimental to performance in the condition conveying only contextual information, suggesting that anxiety may have a greater impact on high-level (top-down) cognitive processes, potentially due to a shift in attentional control. Our findings provide partial support for ACT; anxiety elicited greater decrements in processing efficiency than performance effectiveness, possibly due to predominance of the stimulus-driven attentional system
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