Oxidation of Columbium-Chromium Alloys at Elevated Temperatures

Screening studies of the oxidation characteristics of binary alloys of columbium (Ref. 1) showed that chromium was an additive element worthy of intensive study. The screening studies showed that chromium additions were especially helpful in decreasing the oxidation rate of columbium at 10000deg C and were somewhat less beneficial at 12000deg C. It is the purpose of this investigation to study the oxidation characteristics of binary columbium-chromium alloys in more detail

Vibration/vacuum screening of space lubricants Final report

Evaluation of solid film lubricants for ball bearings in space environment

Simulations and experiments of short intense envelope solitons of surface water waves

The problem of existence of stable nonlinear groups of gravity waves in deep water is revised by means of laboratory and numerical simulations with the focus on intense waves. Wave groups with steepness up to $A_{cr} \omega_m^2 /g \approx 0.30$ are reproduced in laboratory experiments ($A_{cr}$ is the wave crest amplitude, $\omega_m$ is the mean angular frequency and $g$ is the gravity acceleration). We show that the groups remain stable and exhibit neither noticeable radiation nor structural transformation for more than 60 wave lengths or about 15-30 group lengths. These solitary wave patterns differ from the conventional envelope solitons, as only a few individual waves are contained in the group. Very good agreement is obtained between the laboratory results and strongly nonlinear numerical simulations of the potential Euler equations. The envelope soliton solution of the nonlinear Schr\"odinger equation is shown to be a reasonable first approximation for specifying the wavemaker driving signal. The short intense envelope solitons possess vertical asymmetry similar to regular Stokes waves with the same frequency and crest amplitude. Nonlinearity is found to have remarkably stronger effect on the speed of envelope solitons in comparison to the nonlinear correction to the Stokes wave velocity.Comment: Under review in Physics of Fluid

Surface roughness during depositional growth and sublimation of ice crystals

Full version of an earlier discussion paper (Chou et al. 2018)Ice surface properties can modify the scattering properties of atmospheric ice crystals and therefore affect the radiative properties of mixed-phase and cirrus clouds. The Ice Roughness Investigation System (IRIS) is a new laboratory setup designed to investigate the conditions under which roughness develops on single ice crystals, based on their size, morphology and growth conditions (relative humidity and temperature). Ice roughness is quantified through the analysis of speckle in 2-D light-scattering patterns. Characterization of the setup shows that a supersaturation of 20 % with respect to ice and a temperature at the sample position as low as-40 °C could be achieved within IRIS. Investigations of the influence of humidity show that higher supersaturations with respect to ice lead to enhanced roughness and irregularities of ice crystal surfaces. Moreover, relative humidity oscillations lead to gradual ratcheting-up of roughness and irregularities, as the crystals undergo repeated growth-sublimation cycles. This memory effect also appears to result in reduced growth rates in later cycles. Thus, growth history, as well as supersaturation and temperature, influences ice crystal growth and properties, and future atmospheric models may benefit from its inclusion in the cloud evolution process and allow more accurate representation of not just roughness but crystal size too, and possibly also electrification properties.Peer reviewe

Heterogeneous ice nucleation: exploring the transition from stochastic to singular freezing behavior

Heterogeneous ice nucleation, a primary pathway for ice formation in the atmosphere, has been described alternately as being stochastic, in direct analogy with homogeneous nucleation, or singular, with ice nuclei initiating freezing at deterministic temperatures. We present an idealized, conceptual model to explore the transition between stochastic and singular ice nucleation. This "soccer ball" model treats particles as being covered with surface sites (patches of finite area) characterized by different nucleation barriers, but with each surface site following the stochastic nature of ice embryo formation. The model provides a phenomenological explanation for seemingly contradictory experimental results obtained in our research groups. Even with ice nucleation treated fundamentally as a stochastic process this process can be masked by the heterogeneity of surface properties, as might be typical for realistic atmospheric particle populations. Full evaluation of the model findings will require experiments with well characterized ice nucleating particles and the ability to vary both temperature and waiting time for freezing