ANC–BNC titrations and geochemical modeling for characterizing calcareous and siliceous mining waste

Pyrite and calcite are mineral phases that play a major role in acid and neutral mine drainage processes. However, the prediction of acid mine drainage (AMD) or contaminated neutral drainage (CND) requires knowledge of the mineral composition of mining waste and the related potential for element release. This paper studies the combination of acid–base neutralizing capacity (ANC–BNC) with geochemical modeling for the characterization of mining waste and prediction of AMD and CND. The proposed approach is validated with three synthetic mineral assemblages: (1) siliceous sand with pyrite only, representing mining waste responsible for AMD, (2) siliceous sand with calcite and pyrite, representing calcareous waste responsible for CND, and (3) siliceous sand with calcite only, simulating calcareous matrices without any pyrite. The geochemical modeling approach using PHREEQC software was used to model pH evolution and main element release as a function of the added amount of acid or base over the entire pH range: 1 < pH < 13. For calcareous matrices (sand with calcite), the results are typical of a carbonated environment, the geochemistry of which is well known. For matrices containing pyrite, the results identify different pH values favoring the dissolution of pyrite: pH = 2 in a pyrite-only environment and pH = 6 where pyrite coexists with calcite. The neutral conditions can be explained by the buffering capacity of calcite, which allows iron oxyhy-droxide precipitation. Major element release is then related to the dissolution and precipitation of the mineral assemblages. The geochemical modeling allows the prediction of element speciation in the solid and liquid phases. Our findings clearly prove the potential of combined ANC–BNC experiments along with geochemical modeling for the characterization of mining waste and the assessment of risk of AMD and CND. © 2020 by the authors. *Please note that there are multiple authors for this article therefore only the name of the first 5 including Federation University Australia affiliate “Thomas Baumgartl” is provided in this record*

Impact of the volume of gaseous phase in closed reactors on ANC results and modelling.

International audienc

Caractérisation et modélisation géochimique de la solubilisation des éléments minéraux majeurs dans les sédiments de l’assainissement urbain.

National audienc

ANC–BNC Titrations and Geochemical Modeling for Characterizing Calcareous and Siliceous Mining Waste

International audiencePyrite and calcite are mineral phases that play a major role in acid and neutral mine drainage processes. However, the prediction of acid mine drainage (AMD) or contaminated neutral drainage (CND) requires knowledge of the mineral composition of mining waste and the related potential for element release. This paper studies the combination of acid–base neutralizing capacity (ANC–BNC) with geochemical modeling for the characterization of mining waste and prediction of AMD and CND. The proposed approach is validated with three synthetic mineral assemblages: (1) siliceous sand with pyrite only, representing mining waste responsible for AMD, (2) siliceous sand with calcite and pyrite, representing calcareous waste responsible for CND, and (3) siliceous sand with calcite only, simulating calcareous matrices without any pyrite. The geochemical modeling approach using PHREEQC software was used to model pH evolution and main element release as a function of the added amount of acid or base over the entire pH range: 1 < pH < 13. For calcareous matrices (sand with calcite), the results are typical of a carbonated environment, the geochemistry of which is well known. For matrices containing pyrite, the results identify different pH values favoring the dissolution of pyrite: pH = 2 in a pyrite-only environment and pH = 6 where pyrite coexists with calcite. The neutral conditions can be explained by the buffering capacity of calcite, which allows iron oxyhydroxide precipitation. Major element release is then related to the dissolution and precipitation of the mineral assemblages. The geochemical modeling allows the prediction of element speciation in the solid and liquid phases. Our findings clearly prove the potential of combined ANC–BNC experiments along with geochemical modeling for the characterization of mining waste and the assessment of risk of AMD and CND

From drought to flooding: understanding the abrupt 2010-11 hydrological annual cycle in the Amazonas River and tributaries

In this work we document and analyze the hydrological annual cycles characterized by a rapid transition between low and high flows in the Amazonas River (Peruvian Amazon) and we show how these events, which may impact vulnerable riverside residents, are related to regional climate variability. Our analysis is based on comprehensive discharge, rainfall and average suspended sediment data sets. Particular attention is paid to the 2010–11 hydrological year, when an unprecedented abrupt transition from the extreme September 2010 drought (8300 m3s−1) to one of the four highest discharges in April 2011 (49 500 m3s−1) was recorded at Tamshiyacu (Amazonas River). This unusual transition is also observed in average suspended sediments. Years with a rapid increase in discharge are characterized by negative sea surface temperature anomalies in the central equatorial Pacific during austral summer, corresponding to a La Nina-like mode. It originates a geopotential height wave train over the ˜subtropical South Pacific and southeastern South America, with a negative anomaly along the southern Amazon and the southeastern South Atlantic convergence zone region. As a consequence, the monsoon flux is retained over the Amazon and a strong convergence of humidity occurs in the Peruvian Amazon basin, favoring high rainfall and discharge. These features are also reported during the 2010–11 austral summer, when an intense La Nina event ˜ characterized the equatorial Pacific

Lead Mobilization and Speciation in Mining Waste: Experiments and Modeling

Mining produces significant amounts of solid mineral waste. Mine waste storage facilities are often challenging to manage and may cause environmental problems. Mining waste is often linked to contaminated mine drainage, including acidic waters with more or less elevated concentrations of trace metals such as lead. This work presents a study on the mobilization of lead from waste from two typical mining sites: Zeida and Mibladen, two now-closed former Pb–Zn mines in the Moulouya region of Morocco. Our research investigates the mobilization potential of Pb from the waste of these mines. The study involved acid–base neutralization capacity tests (ANC–BNC) combined with geochemical modeling. Experimental data allowed for the quantification of the buffering capacity of the samples and the mobilization rates of lead as a function of pH. The geochemical model was fitted to experimental results with thermodynamic considerations. The geochemical model allowed for the identification of the mineral phases involved in providing the buffering capacity of carbonated mining waste (Mibladen) and the meager buffering capacity of the silicate mining waste (Zeida). These cases are representative of contaminated neutral drainage (CND) and acid mine drainage (AMD), respectively. The results highlight the consistency between the ANC–BNC experimental data and the associated modeling in terms of geochemical behavior, validating the approach and identifying the main mechanisms involved. The modeling approach identifies the dissolution of the main solid phases, which impact the pH and the speciation of lead as a function of the pH. This innovative approach, combining ANC–BNC experiments and geochemical modeling, allowed for the accurate identification of mineral phases and surface complexation phenomena, which control the release of lead and its speciation in drainage solutions, as well as within solid phases, as a function of pH

Climate variability and extreme drought in the upper Solimões River (western Amazon Basin): Understanding the exceptional 2010 drought

International audienceThis work provides an initial overview of climate features and their related hydrological impacts during the recent extreme droughts (1995, 1998, 2005 and 2010) in the upper Solimões River (western Amazon), using comprehensive in situ discharge and rainfall datasets. The droughts are generally associated with positive SST anomalies in the tropical North Atlantic and weak trade winds and water vapor transport toward the upper Solimões, which, in association with increased subsidence over central and southern Amazon, explain the lack of rainfall and very low discharge values. But in 1998, toward the end of the 1997-98 El Niño event, the drought is more likely related to an anomalous divergence of water vapor in the western Amazon that is characteristic of a warm event in the Pacific. During the austral spring and winter of 2010, the most severe drought since the seventies has been registered in the upper Solimões. Its intensity and its length, when compared to the 2005 drought, can be explained by the addition of an El Niño in austral summer and a very warm episode in the Atlantic in boreal spring and summer. As in 2005, the lack of water in 2010 was more important in the southern tropical tributaries of the upper Solimões than in the northern ones

The specificity of Fe and P speciation in urban soils dedicated to stormwater infiltration

International audienc

From drought to flooding: understanding the abrupt 2010-11 hydrological annual cycle in the Amazonas River and tributaries

International audienceIn this work we document and analyze the hydrological annual cycles characterized by a rapid transition between low and high flows in the Amazonas River (Peruvian Amazon) and we show how these events, which may impact vulnerable riverside residents, are related to regional climate variability. Our analysis is based on comprehensive discharge, rainfall and average suspended sediment data sets. Particular attention is paid to the 2010-11 hydrological year, when an unprecedented abrupt transition from the extreme September 2010 drought (8300 m3 s-1) to one of the four highest discharges in April 2011 (49 500 m3 s-1) was recorded at Tamshiyacu (Amazonas River). This unusual transition is also observed in average suspended sediments. Years with a rapid increase in discharge are characterized by negative sea surface temperature anomalies in the central equatorial Pacific during austral summer, corresponding to a La Niña-like mode. It originates a geopotential height wave train over the subtropical South Pacific and southeastern South America, with a negative anomaly along the southern Amazon and the southeastern South Atlantic convergence zone region. As a consequence, the monsoon flux is retained over the Amazon and a strong convergence of humidity occurs in the Peruvian Amazon basin, favoring high rainfall and discharge. These features are also reported during the 2010-11 austral summer, when an intense La Niña event characterized the equatorial Pacific