Inertio-capillary rebound of a droplet impacting a fluid bath

The rebound of droplets impacting a deep fluid bath is studied both experimentally and theoretically. Millimetric drops are generated using a piezoelectric droplet-on-demand generator and normally impact a bath of the same fluid. Measurements of the droplet trajectory and other rebound metrics are compared directly to the predictions of a linear quasi-potential model, as well as fully resolved direct numerical simulations (DNS) of the unsteady Navier-Stokes equations. Both models resolve the time-dependent bath and droplet shapes in addition to the droplet trajectory. In the quasi-potential model, the droplet and bath shape are decomposed using orthogonal function decompositions leading to two sets of coupled damped linear harmonic oscillator equations solved using an implicit numerical method. The underdamped dynamics of the drop are directly coupled to the response of the bath through a single-point kinematic match condition which we demonstrate to be an effective and efficient model in our parameter regime of interest. Starting from the inertio-capillary limit in which both gravitational and viscous effects are negligible, increases in gravity or viscosity lead to a decrease in the coefficient of restitution and an increase in the contact time. The inertio-capillary limit defines an upper bound on the possible coefficient of restitution for droplet-bath impact, depending only on the Weber number. The quasi-potential model is able to rationalize historical experimental measurements for the coefficient of restitution, first presented by Jayaratne and Mason (1964).Comment: 33 pages, 13 figure

Inertio-capillary rebound of a droplet impacting a fluid bath

The rebound of droplets impacting a deep fluid bath is studied both experimentally and theoretically. Millimetric drops are generated using a piezoelectric droplet-on-demand generator and normally impact a bath of the same fluid. Measurements of the droplet trajectory and other rebound metrics are compared directly with the predictions of a linear quasipotential model, as well as fully resolved direct numerical simulations of the unsteady Navier–Stokes equations. Both models resolve the time-dependent bath and droplet shapes in addition to the droplet trajectory. In the quasipotential model, the droplet and bath shape are decomposed using orthogonal function decompositions leading to two sets of coupled damped linear harmonic oscillator equations solved using an implicit numerical method. The underdamped dynamics of the drop are directly coupled to the response of the bath through a single-point kinematic match condition which we demonstrate to be an effective and efficient model in our parameter regime of interest. Starting from the inertio-capillary limit in which both gravitational and viscous effects are negligible, increases in gravity or viscosity lead to a decrease in the coefficient of restitution and an increase in the contact time. The inertio-capillary limit defines an upper bound on the possible coefficient of restitution for droplet–bath impact, depending only on the Weber number. The quasipotential model is able to rationalize historical experimental measurements for the coefficient of restitution, first presented by Jayaratne & Mason (Proc. R. Soc. Lond. A, vol. 280, issue 1383, 1964, pp. 545–565)

Weak Charge Transfer between an Acceptor Molecule and Metal Surfaces Enabling Organic/Metal Energy Level Tuning

Evidence for charge transfer (CT) between the electron acceptor molecule octafluoroanthraquinone (FAQ) and the metal surfaces Ag(111) and polycrystalline Au is provided by ultraviolet photoelectron spectroscopy. The energy level alignment of subsequently deposited sexithienyl (6T) on FAQ-precovered metal substrates was investigated. Due to the metal work function change induced by the FAQ-metal CT, the hole injection barrier of 6T on FAQ-precovered metals could be reduced by up to 0.60 eV compared to that of 6T on pristine metal surfaces

Pilot lifestyle education intervention for patients with severe mental illness during the inpatient stay

Dear Editor, Individuals diagnosed with a severe mental illness (SMI) hold a significantly increased risk of obesity, diabetes, and cardiovascular disease (Teasdale et al., 2017; Gurusamy et al., 2018). Elevated cardiovascular risk for individuals diagnosed with SMI may be attributable to numerous factors, prominently including a cluster of clinical features that define the metabolic syndrome (MetS): abdominal adiposity, atherogenic dyslipidemia, hypertension, and impaired fasting glucose/ diabetes (Kucerova et al., 2015). The incidence rate of MetS and obesity among patients diagnosed with schizophrenia has been estimated to be as high as 54% and 40–50% respectively, twice that observed in the general population (Gurusamy et al., 2018;Fan et al., 2010)

Droplet impact onto a spring-supported plate: analysis and simulations

The high-speed impact of a droplet onto a flexible substrate is a highly nonlinear process of practical importance which poses formidable modelling challenges in the context of fluid-structure interaction. We present two approaches aimed at investigating the canonical system of a droplet impacting onto a rigid plate supported by a spring and a dashpot: matched asymptotic expansions and direct numerical simulation (DNS). In the former, we derive a generalisation of inviscid Wagner theory to approximate the flow behaviour during the early stages of the impact. In the latter, we perform detailed DNS designed to validate the analytical framework, as well as provide insight into later times beyond the reach of the proposed mathematical model. Drawing from both methods, we observe the strong influence that the mass of the plate, resistance of the dashpot and stiffness of the spring have on the motion of the solid, which undergoes forced damped oscillations. Furthermore, we examine how the plate motion affects the dynamics of the droplet, predominantly through altering its internal hydrodynamic pressure distribution. We build on the interplay between these techniques, demonstrating that a hybrid approach leads to improved model and computational development, as well as result interpretation, across multiple length- and time-scales.Comment: 28 pages, 6 figure