160 research outputs found
Critical point calculation for binary mixtures of symmetric non-additive hard disks
We have calculated the values of critical packing fractions for the mixtures
of symmetric non-additive hard disks. An interesting feature of the model is
the fact that the internal energy is zero and the phase transitions are
entropically driven. A cluster algorithm for Monte Carlo simulations in a
semigrand ensemble was used. The finite size scaling analysis was employed to
compute the critical packing fractions for infinite systems with high accuracy
for a range of non-additivity parameters wider than in the previous studies.Comment: 8 pages, 4 figure
Mesoscopic theory for size- and charge- asymmetric ionic systems. I. Case of extreme asymmetry
A mesoscopic theory for the primitive model of ionic systems is developed for
arbitrary size, , and charge, ,
asymmetry. Our theory is an extension of the theory we developed earlier for
the restricted primitive model. The case of extreme asymmetries
and is studied in some detail in a mean-field
approximation. The phase diagram and correlation functions are obtained in the
asymptotic regime and , and for infinite
dilution of the larger ions (volume fraction or less). We find a
coexistence between a very dilute 'gas' phase and a crystalline phase in which
the macroions form a bcc structure with the lattice constant . Such coexistence was observed experimentally in deionized aqueous
solutions of highly charged colloidal particles
Phase behavior of hard spheres confined between parallel hard plates: Manipulation of colloidal crystal structures by confinement
We study the phase behavior of hard spheres confined between two parallel
hard plates using extensive computer simulations. We determine the full
equilibrium phase diagram for arbitrary densities and plate separations from
one to five hard-sphere diameters using free energy calculations. We find a
first-order fluid-solid transition, which corresponds to either capillary
freezing or melting depending on the plate separation. The coexisting solid
phase consists of crystalline layers with either triangular or square symmetry.
Increasing the plate separation, we find a sequence of crystal structures from
n triangular to (n+1) square to (n+1) triangular, where n is the number of
crystal layers, in agreement with experiments on colloids. At high densities,
the transition between square to triangular phases are intervened by
intermediate structures, e.g., prism, buckled, and rhombic phases.Comment: 9 pages, 4 figures. Accepted for publication in J. Phys.: Condens.
Matte
Field theory for size- and charge asymmetric primitive model of electrolytes. Mean-field stability analysis and pretransitional effects
The primitive model of ionic systems is investigated within a field-theoretic
description for the whole range of size-, \lambda, and charge, Z, ratios of the
two ionic species. Two order parameters (OP) are identified, and their
relations to physically relevant quantities are described for various values of
\lambda and Z. Instabilities of the disordered phase associated with the two
OP's are determined in the mean-field approximation.
A gas-liquid separation occurs for any Z and \lambda different from 1. In
addition, an instability with respect to various types of periodic ordering of
the two kinds of ions is found
Surface critical behavior of driven diffusive systems with open boundaries
Using field theoretic renormalization group methods we study the critical
behavior of a driven diffusive system near a boundary perpendicular to the
driving force. The boundary acts as a particle reservoir which is necessary to
maintain the critical particle density in the bulk. The scaling behavior of
correlation and response functions is governed by a new exponent eta_1 which is
related to the anomalous scaling dimension of the chemical potential of the
boundary. The new exponent and a universal amplitude ratio for the density
profile are calculated at first order in epsilon = 5-d. Some of our results are
checked by computer simulations.Comment: 10 pages ReVTeX, 6 figures include
Daily Precipitation over Southern Africa: A New Resource for Climate Studies
This paper describes a new high-resolution multiplatform multisensor satellite rainfall product for southern Africa covering the period 1993–2002. The microwave infrared rainfall algorithm (MIRA) employed to generate the rainfall estimates combines high spatial and temporal resolution Meteosat infrared data with infrequent Special Sensor Microwave Imager (SSM/I) overpasses. A transfer function relating Meteosat thermal infrared cloud brightness temperatures to SSM/I rainfall estimates is derived using collocated data from the two instruments and then applied to the full coverage of the Meteosat data. An extensive continental-scale validation against synoptic station data of both the daily MIRA precipitation product and a normalized geostationary IR-only Geostationary Operational Environmental Satellite (GOES) precipitation index (GPI) demonstrates a consistent advantage using the former over the latter for rain delineation. Potential uses for the resulting high-resolution daily rainfall dataset are discussed
Thermodynamics of Dipolar Chain Systems
The thermodynamics of a quantum system of layers containing perpendicularly
oriented dipolar molecules is studied within an oscillator approximation for
both bosonic and fermionic species. The system is assumed to be built from
chains with one molecule in each layer. We consider the effects of the
intralayer repulsion and quantum statistical requirements in systems with more
than one chain. Specifically, we consider the case of two chains and solve the
problem analytically within the harmonic Hamiltonian approach which is accurate
for large dipole moments. The case of three chains is calculated numerically.
Our findings indicate that thermodynamic observables, such as the heat
capacity, can be used to probe the signatures of the intralayer interaction
between chains. This should be relevant for near future experiments on polar
molecules with strong dipole moments.Comment: 15 pages, 5 figures, final versio
High pressure route to generate magnetic monopole dimers in spin ice
The gas of magnetic monopoles in spin ice is governed by one key parameter: the monopole chemical potential. A significant variation of this parameter could access hitherto undiscovered magnetic phenomena arising from monopole correlations, as observed in the analogous electrical Coulomb gas, like monopole dimerization, critical phase separation, or charge ordering. However, all known spin ices have values of chemical potential imposed by their structure and chemistry that place them deeply within the weakly correlated regime, where none of these interesting phenomena occur. Here we use high-pressure synthesis to create a new monopole host, Dy2Ge2O7, with a radically altered chemical potential that stabilizes a large fraction of monopole dimers. The system is found to be ideally described by the classic Debye–Huckel–Bjerrum theory of charge correlations. We thus show how to tune the monopole chemical potential in spin ice and how to access the diverse collective properties of magnetic monopoles
Critical adsorption near edges
Symmetry breaking surface fields give rise to nontrivial and long-ranged
order parameter profiles for critical systems such as fluids, alloys or magnets
confined to wedges. We discuss the properties of the corresponding universal
scaling functions of the order parameter profile and the two-point correlation
function and determine the critical exponents eta_parallel and
eta_perpendicular for the so-called normal transition.Comment: 22 pages, 5 figures, accepted for publication in PR
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