2,375 research outputs found
Exploring the Way to Approach the Efficiency Limit of Perovskite Solar Cells by Drift-Diffusion Model
Drift-diffusion model is an indispensable modeling tool to understand the
carrier dynamics (transport, recombination, and collection) and simulate
practical-efficiency of solar cells (SCs) through taking into account various
carrier recombination losses existing in multilayered device structures.
Exploring the way to predict and approach the SC efficiency limit by using the
drift-diffusion model will enable us to gain more physical insights and design
guidelines for emerging photovoltaics, particularly perovskite solar cells. Our
work finds out that two procedures are the prerequisites for predicting and
approaching the SC efficiency limit. Firstly, the intrinsic radiative
recombination needs to be corrected after adopting optical designs which will
significantly affect the open-circuit voltage at its Shockley-Queisser limit.
Through considering a detailed balance between emission and absorption of
semiconductor materials at the thermal equilibrium, and the Boltzmann
statistics at the non-equilibrium, we offer a different approach to derive the
accurate expression of intrinsic radiative recombination with the optical
corrections for semiconductor materials. The new expression captures light
trapping of the absorbed photons and angular restriction of the emitted photons
simultaneously, which are ignored in the traditional Roosbroeck-Shockley
expression. Secondly, the contact characteristics of the electrodes need to be
carefully engineered to eliminate the charge accumulation and surface
recombination at the electrodes. The selective contact or blocking layer
incorporated nonselective contact that inhibits the surface recombination at
the electrode is another important prerequisite. With the two procedures, the
accurate prediction of efficiency limit and precise evaluation of efficiency
degradation for perovskite solar cells are attainable by the drift-diffusion
model.Comment: 32 pages, 11 figure
From the surface to the seafloor: How giant larvaceans transport microplastics into the deep sea.
Plastic waste is a pervasive feature of marine environments, yet little is empirically known about the biological and physical processes that transport plastics through marine ecosystems. To address this need, we conducted in situ feeding studies of microplastic particles (10 to 600 μm in diameter) with the giant larvacean Bathochordaeus stygius. Larvaceans are abundant components of global zooplankton assemblages, regularly build mucus "houses" to filter particulate matter from the surrounding water, and later abandon these structures when clogged. By conducting in situ feeding experiments with remotely operated vehicles, we show that giant larvaceans are able to filter a range of microplastic particles from the water column, ingest, and then package microplastics into their fecal pellets. Microplastics also readily affix to their houses, which have been shown to sink quickly to the seafloor and deliver pulses of carbon to benthic ecosystems. Thus, giant larvaceans can contribute to the vertical flux of microplastics through the rapid sinking of fecal pellets and discarded houses. Larvaceans, and potentially other abundant pelagic filter feeders, may thus comprise a novel biological transport mechanism delivering microplastics from surface waters, through the water column, and to the seafloor. Our findings necessitate the development of tools and sampling methodologies to quantify concentrations and identify environmental microplastics throughout the water column
Fibromyalgia: management strategies for primary care providers
Aims
Fibromyalgia (FM), a chronic disorder defined by widespread pain, often accompanied by fatigue and sleep disturbance, affects up to one in 20 patients in primary care. Although most patients with FM are managed in primary care, diagnosis and treatment continue to present a challenge, and patients are often referred to specialists. Furthermore, the lack of a clear patient pathway often results in patients being passed from specialist to specialist, exhaustive investigations, prescription of multiple drugs to treat different symptoms, delays in diagnosis, increased disability and increased healthcare resource utilisation. We will discuss the current and evolving understanding of FM, and recommend improvements in the management and treatment of FM, highlighting the role of the primary care physician, and the place of the medical home in FM management.
Methods
We reviewed the epidemiology, pathophysiology and management of FM by searching PubMed and references from relevant articles, and selected articles on the basis of quality, relevance to the illness and importance in illustrating current management pathways and the potential for future improvements.
Results
The implementation of a framework for chronic pain management in primary care would limit unnecessary, time-consuming, and costly tests, reduce diagnostic delay and improve patient outcomes.
Discussion
The patient-centred medical home (PCMH), a management framework that has been successfully implemented in other chronic diseases, might improve the care of patients with FM in primary care, by bringing together a team of professionals with a range of skills and training.
Conclusion
Although there remain several barriers to overcome, implementation of a PCMH would allow patients with FM, like those with other chronic conditions, to be successfully managed in the primary care setting
C-reactive protein and implications in rheumatoid arthritis and associated comorbidities
C-reactive protein (CRP) is routinely assessed as a marker of systemic inflammation in rheumatoid arthritis (RA). However, it is also an immune regulator that plays an important role in inflammatory pathways associated with RA and promotes atherogenic effects. Comorbidities linked to systemic inflammation are common in RA, and CRP has been associated with the risk for cardiovascular disease, diabetes, metabolic syndrome, pulmonary diseases, and depression. The relationship between systemic inflammation, CRP, and comorbidities in RA is complex, and it is challenging to determine how changing CRP levels may affect the risk or progression of these comorbidities. We review the biological role of CRP in RA and its implications for disease activity and treatment response. We also discuss the impact of treatment on CRP levels and whether reducing systemic inflammation and inhibiting CRP-mediated inflammatory pathways may have an impact on conditions commonly comorbid with RA
Simulation studies of permeation through two-dimensional ideal polymer networks
We study the diffusion process through an ideal polymer network, using
numerical methods. Polymers are modeled by random walks on the bonds of a
two-dimensional square lattice. Molecules occupy the lattice cells and may jump
to the nearest-neighbor cells, with probability determined by the occupation of
the bond separating the two cells. Subjected to a concentration gradient across
the system, a constant average current flows in the steady state. Its behavior
appears to be a non-trivial function of polymer length, mass density and
temperature, for which we offer qualitative explanations.Comment: 8 pages, 4 figure
The Efficiency Limit of CH3NH3PbI3 Perovskite Solar Cells
With the consideration of photon recycling effect, the efficiency limit of methylammonium lead iodide (CH3NH3PbI3) perovskite solar cells is predicted by a detailed balance model. To obtain convincing predictions, both AM 1.5 spectrum of Sun and experimentally measured complex refractive index of perovskite material are employed in the detailed balance model. The roles of light trapping and angular restriction in improving the maximal output power of thin-film perovskite solar cells are also clarified. The efficiency limit of perovskite cells (without the angular restriction) is about 31%, which approaches to Shockley-Queisser limit (33%) achievable by gallium arsenide (GaAs) cells. Moreover, the Shockley-Queisser limit could be reached with a 200 nm-thick perovskite solar cell, through integrating a wavelength-dependent angular-restriction design with a textured light-trapping structure. Additionally, the influence of the trap-assisted nonradiative recombination on the device efficiency is investigated. The work is fundamentally important to high-performance perovskite photovoltaics.published_or_final_versio
Insulating charge density wave for a half-filled SU(N) Hubbard model with an attractive on-site interaction in one dimension
We study a one-dimensional SU(N) Hubbard model with an attractive on-site
interaction and at half-filling on the bipartite lattice using
density-matrix renormalization-group method and a perturbation theory. We find
that the ground state of the SU(N) Hubbard model is a charge density wave state
with two-fold degeneracy. All the excitations are found to be gapful, resulting
in an insulating ground state, on contrary to that in the SU(2) case. Moreover,
the charge gap is equal to the Cooperon gap, which behaves as
in the strong coupling regime. However, the spin gap and the
quasiparticle gap as well open exponentially in the weak coupling
region, while in the strong coupling region, they linearly depend on such
that and .Comment: 7 pages, 7 figure
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