833 research outputs found
Structure Factor and Electronic Structure of Compressed Liquid Rubidium
We have applied the quantal hypernetted-chain equations in combination with
the Rosenfeld bridge-functional to calculate the atomic and the electronic
structure of compressed liquid-rubidium under high pressure (0.2, 2.5, 3.9, and
6.1 GPa); the calculated structure factors are in good agreement with
experimental results measured by Tsuji et al. along the melting curve. We found
that the Rb-pseudoatom remains under these high pressures almost unchanged with
respect to the pseudoatom at room pressure; thus, the effective ion-ion
interaction is practically the same for all pressure-values. We observe that
all structure factors calculated for this pressure-variation coincide almost
into a single curve if wavenumbers are scaled in units of the Wigner-Seitz
radius although no corresponding scaling feature is observed in the
effective ion-ion interaction.This scaling property of the structure factors
signifies that the compression in liquid-rubidium is uniform with increasing
pressure; in absolute Q-values this means that the first peak-position ()
of the structure factor increases proportionally to ( being the
specific volume per ion), as was experimentally observed by Tsuji et al.Comment: 18 pages, 11 figure
Nucleus-Electron Model for States Changing from a Liquid Metal to a Plasma and the Saha Equation
We extend the quantal hypernetted-chain (QHNC) method, which has been proved
to yield accurate results for liquid metals, to treat a partially ionized
plasma. In a plasma, the electrons change from a quantum to a classical fluid
gradually with increasing temperature; the QHNC method applied to the electron
gas is in fact able to provide the electron-electron correlation at arbitrary
temperature. As an illustrating example of this approach, we investigate how
liquid rubidium becomes a plasma by increasing the temperature from 0 to 30 eV
at a fixed normal ion-density . The electron-ion
radial distribution function (RDF) in liquid Rb has distinct inner-core and
outer-core parts. Even at a temperature of 1 eV, this clear distinction remains
as a characteristic of a liquid metal. At a temperature of 3 eV, this
distinction disappears, and rubidium becomes a plasma with the ionization 1.21.
The temperature variations of bound levels in each ion and the average
ionization are calculated in Rb plasmas at the same time. Using the
density-functional theory, we also derive the Saha equation applicable even to
a high-density plasma at low temperatures. The QHNC method provides a procedure
to solve this Saha equation with ease by using a recursive formula; the charge
population of differently ionized species are obtained in Rb plasmas at several
temperatures. In this way, it is shown that, with the atomic number as the only
input, the QHNC method produces the average ionization, the electron-ion and
ion-ion RDF's, and the charge population which are consistent with the atomic
structure of each ion for a partially ionized plasma.Comment: 28 pages(TeX) and 11 figures (PS
Meixner polynomials of the second kind and quantum algebras representing su(1,1)
We show how Viennot's combinatorial theory of orthogonal polynomials may be
used to generalize some recent results of Sukumar and Hodges on the matrix
entries in powers of certain operators in a representation of su(1,1). Our
results link these calculations to finding the moments and inverse polynomial
coefficients of certain Laguerre polynomials and Meixner polynomials of the
second kind. As an immediate consequence of results by Koelink, Groenevelt and
Van Der Jeugt, for the related operators, substitutions into essentially the
same Laguerre polynomials and Meixner polynomials of the second kind may be
used to express their eigenvectors. Our combinatorial approach explains and
generalizes this "coincidence".Comment: several correction
Polynomial solutions of nonlinear integral equations
We analyze the polynomial solutions of a nonlinear integral equation,
generalizing the work of C. Bender and E. Ben-Naim. We show that, in some
cases, an orthogonal solution exists and we give its general form in terms of
kernel polynomials.Comment: 10 page
Probing Ion-Ion and Electron-Ion Correlations in Liquid Metals within the Quantum Hypernetted Chain Approximation
We use the Quantum Hypernetted Chain Approximation (QHNC) to calculate the
ion-ion and electron-ion correlations for liquid metallic Li, Be, Na, Mg, Al,
K, Ca, and Ga. We discuss trends in electron-ion structure factors and radial
distribution functions, and also calculate the free-atom and metallic-atom
form-factors, focusing on how bonding effects affect the interpretation of
X-ray scattering experiments, especially experimental measurements of the
ion-ion structure factor in the liquid metallic phase.Comment: RevTeX, 19 pages, 7 figure
Computing the Hessenberg matrix associated with a self-similar measure
We introduce in this paper a method to calculate the Hessenberg matrix of a sum of measures from the Hessenberg matrices of the component measures. Our method extends the spectral techniques used by G. Mantica to calculate the Jacobi matrix associated with a sum of measures from the Jacobi matrices of each of the measures.
We apply this method to approximate the Hessenberg matrix associated with a self-similar measure and compare it with the result obtained by a former method for self-similar measures which uses a fixed point theorem for moment matrices. Results are given for a series of classical examples of self-similar measures.
Finally, we also apply the method introduced in this paper to some examples of sums of (not self-similar) measures obtaining the exact value of the sections of the Hessenberg matrix
Birth and death processes and quantum spin chains
This papers underscores the intimate connection between the quantum walks
generated by certain spin chain Hamiltonians and classical birth and death
processes. It is observed that transition amplitudes between single excitation
states of the spin chains have an expression in terms of orthogonal polynomials
which is analogous to the Karlin-McGregor representation formula of the
transition probability functions for classes of birth and death processes. As
an application, we present a characterization of spin systems for which the
probability to return to the point of origin at some time is 1 or almost 1.Comment: 14 page
Cosine and Sine Operators Related with Orthogonal Polynomial Sets on the Intervall [-1,1]
The quantization of phase is still an open problem. In the approach of
Susskind and Glogower so called cosine and sine operators play a fundamental
role. Their eigenstates in the Fock representation are related with the
Chebyshev polynomials of the second kind. Here we introduce more general cosine
and sine operators whose eigenfunctions in the Fock basis are related in a
similar way with arbitrary orthogonal polynomial sets on the intervall [-1,1].
To each polynomial set defined in terms of a weight function there corresponds
a pair of cosine and sine operators. Depending on the symmetry of the weight
function we distinguish generalized or extended operators. Their eigenstates
are used to define cosine and sine representations and probability
distributions. We consider also the inverse arccosine and arcsine operators and
use their eigenstates to define cosine-phase and sine-phase distributions,
respectively. Specific, numerical and graphical results are given for the
classical orthogonal polynomials and for particular Fock and coherent states.Comment: 1 tex-file (24 pages), 11 figure
Escort mean values and the characterization of power-law-decaying probability densities
Escort mean values (or -moments) constitute useful theoretical tools for
describing basic features of some probability densities such as those which
asymptotically decay like {\it power laws}. They naturally appear in the study
of many complex dynamical systems, particularly those obeying nonextensive
statistical mechanics, a current generalization of the Boltzmann-Gibbs theory.
They recover standard mean values (or moments) for . Here we discuss the
characterization of a (non-negative) probability density by a suitable set of
all its escort mean values together with the set of all associated normalizing
quantities, provided that all of them converge. This opens the door to a
natural extension of the well known characterization, for the instance,
of a distribution in terms of the standard moments, provided that {\it all} of
them have {\it finite} values. This question would be specially relevant in
connection with probability densities having {\it divergent} values for all
nonvanishing standard moments higher than a given one (e.g., probability
densities asymptotically decaying as power-laws), for which the standard
approach is not applicable. The Cauchy-Lorentz distribution, whose second and
higher even order moments diverge, constitutes a simple illustration of the
interest of this investigation. In this context, we also address some
mathematical subtleties with the aim of clarifying some aspects of an
interesting non-linear generalization of the Fourier Transform, namely, the
so-called -Fourier Transform.Comment: 20 pages (2 Appendices have been added
A "missing" family of classical orthogonal polynomials
We study a family of "classical" orthogonal polynomials which satisfy (apart
from a 3-term recurrence relation) an eigenvalue problem with a differential
operator of Dunkl-type. These polynomials can be obtained from the little
-Jacobi polynomials in the limit . We also show that these polynomials
provide a nontrivial realization of the Askey-Wilson algebra for .Comment: 20 page
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