unexpected impact of the number of glutamine residues on metal complex stability

The emerging question which this study aims to answer is: what impact do glutamines have on the stability of metal–peptide complexes? We focused our attention on the N-terminal domain of Hpn and Hpn-like proteins from Helicobacter pylori. Cu2+ and Ni2+ complexes of the model peptides MAHHE-NH2, MAHHEEQ-NH2, MAHHEQQ-NH2 and MAHHEQQHQA-NH2 were studied by means of different thermodynamic and spectroscopic techniques, as well as through molecular modelling computation. Experimental results, in very good agreement with theoretical findings, lead to the not obvious conclusion that the stability of metal complexes distinctly increases with the number of glutamine residues present in the peptide, although glutamine side-chains do not directly take part in coordination. This peculiar finding allows one to look at polyglutamine sequences, not only the ones present in some bacterial chaperones but also those involved in several neurodegenerative diseases, from a new perspective

Chemical Characterization of a Volatile Dubnium Compound, DbOCl3

The formation and the chemical characterization of single atoms of dubnium (Db, element 105), in the form of its volatile oxychloride, was investigated using the on-line gas phase chromatography technique, in the temperature range 350–600 °C. Under the exactly same chemical conditions, comparative studies with the lighter homologues of Group 5 in the Periodic Table clearly indicate the volatility sequence being NbOCl3 > TaOCl3 ≥ DbOCl3. From the obtained experimental results, thermochemical data for DbOCl3 were derived. The present study delivers reliable experimental information for theoretical calculations on chemical properties of transactinides

Removal of radioactive cesium from contaminated water by whey protein amyloids–carbon hybrid filters

We report on the application of an innovative whey protein amyloids–carbon hybrid filter for the removal and disposal of the long-lived radioactive fission product 137Cs from aqueous samples. Test experiments revealed a reduction of 137Cs radioactivity by a factor of 340 compared to the initial solution, with an efficiency as high as 99.7%. The adsorption capacity of the membrane was explored by performing several cycles of filtration, indicating a potential retention of more than 115 MBq per gram of filtering material at the applied experimental conditions. These results pave the way for further investigations on the applicability of this filter material to other nuclear fission products

Preparation of PbSe targets for 79Se neutron capture cross section studies

A methodology for the production of PbSe targets for 79Se neutron capture cross section studies is presented. PbSe material was synthesized by direct reaction of its constituents at high temperature, and characterized by X-ray diffraction. Thin PbSe targets, produced for cross section experiments with the surrogate reaction method, were obtained by applying a physical vapor deposition technique, and their morphology and composition were analyzed by X-ray fluorescence, Scanning Electron Microscopy, and Energy dispersive X-ray spectroscopy. Pb79Se targets produced for cross section measurements with the Time of Flight method were characterized by γ-ray spectroscopy. Finally, a procedure for the recovery of Se from PbSe is suggested. The purity of the retrieved Se was determined with Inductively Coupled Plasma Optical Emission Spectroscopy.ISSN:0168-9002ISSN:1872-957

Chemical Characterization of a Volatile Dubnium Compound, DbOCl3

The formation and the chemical characterization of single atoms of dubnium (Db, element 105), in the form of its volatile oxychloride, was investigated using the on‐line gas phase chromatography technique, in the temperature range 350–600 °C. Under the exactly same chemical conditions, comparative studies with the lighter homologues of Group 5 in the Periodic Table clearly indicate the volatility sequence being NbOCl(3) > TaOCl(3) ≥ DbOCl(3). From the obtained experimental results, thermochemical data for DbOCl(3) were derived. The present study delivers reliable experimental information for theoretical calculations on chemical properties of transactinides