3,912 research outputs found

    Ignition and Front Propagation in Polymer Electrolyte Membrane Fuel Cells

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    Water produced in a Polymer Electrolyte Membrane (PEM) fuel cell enhances membrane proton conductivity; this positive feedback loop can lead to current ignition. Using a segmented anode fuel cell we study the effect of gas phase convection and membrane diffusion of water on the spatiotemporal nonlinear dynamics - localized ignition and front propagation - in the cell. Co-current gas flow causes ignition at the cell outlet, and membrane diffusion causes the front to slowly propagate to the inlet; counter-current flow causes ignition in the interior of the cell, with the fronts subsequently spreading towards both inlets. These instabilities critically affect fuel cell performance

    Optical Properties of Organometallic Perovskite: An ab initio Study using Relativistic GW Correction and Bethe-Salpeter Equation

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    In the development of highly efficient photovoltaic cells, solid perovskite systems have demonstrated unprecedented promise, with the figure of merit exceeding nineteen percent of efficiency. In this paper, we investigate the optical and vibrational properties of organometallic cubic perovskite CH3NH3PbI3 using first-principles calculations. For accurate theoretical description, we go beyond conventional density functional theory (DFT), and calculated optical conductivity using relativist quasi-particle (GW) correction. Incorporating these many-body effects, we further solve Bethe-Salpeter equations (BSE) for excitons, and found enhanced optical conductivity near the gap edge. Due to the presence of organic methylammonium cations near the center of the perovskite cell, the system is sensitive to low energy vibrational modes. We estimate the phonon modes of CH3NH3PbI3 using small displacement approach, and further calculate the infrared absorption (IR) spectra. Qualitatively, our calculations of low-energy phonon frequencies are in good agreement with our terahertz measurements. Therefore, for both energy scales (around 2 eV and 0-20 meV), our calculations reveal the importance of many-body effects and their contributions to the desirable optical properties in the cubic organometallic perovskites system.Comment: 5 pages, 4 figure

    A high flux source of cold strontium atoms

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    We describe an experimental apparatus capable of achieving a high loading rate of strontium atoms in a magneto-optical trap operating in a high vacuum environment. A key innovation of this setup is a two dimensional magneto-optical trap deflector located after a Zeeman slower. We find a loading rate of 6x10^9/s whereas the lifetime of the magnetically trapped atoms in the 3P2 state is 54s.Comment: 12 pages, 16 figure

    Penetration depth study of LaOs4_4Sb12_{12}: Multiband s-wave superconductivity

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    We measured the magnetic penetration depth λ(T)\lambda(T) in single crystals of LaOs4_{4}Sb12_{12} (TcT_c=0.74 K) down to 85 mK using a tunnel diode oscillator technique. The observed low-temperature exponential dependence indicates a s-wave gap. Fitting the low temperature data to BCS s-wave expression gives the zero temperature gap value Δ(0)=(1.34±0.07)kBTc\Delta (0)= (1.34 \pm 0.07) k_B T_c which is significantly smaller than the BCS value of 1.76kBTck_B T_c. In addition, the normalized superfluid density ρ(T)\rho(T) shows an unusually long suppression near TcT_c, and are best fit by a two-band s-wave model.Comment: 5 pages, 2 figure

    Probing the superconducting gap symmetry of PrRu4_{4}Sb12_{12}: A comparison with PrOs4_{4}Sb12_{12}

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    We report measurements of the magnetic penetration depth λ\lambda in single crystals of PrRu4_{4}Sb12_{12} down to 0.1 K. Both λ\lambda and superfluid density ρs\rho_{s} exhibit an exponential behavior for TT << 0.5TcT_{c}, with parameters Δ\Delta(0)/\textit{k}B_{B}\textit{T}c_{c} = 1.9 and λ(0)\lambda(0) = 2900 \AA. The value of Δ\Delta(0) is consistent with the specific-heat jump value of ΔC/γTc\Delta C/\gamma T_{c} = 1.87 measured elsewhere, while the value of λ(0)\lambda(0) is consistent with the measured value of the electronic heat-capacity coefficient γ\gamma. Our data are consistent with PrRu4_{4}Sb12_{12} being a moderate-coupling, fully-gapped superconductor. We suggest experiments to study how the nature of the superconducting state evolves with increasing Ru substitution for Os

    Field-angle Dependence of the Zero-Energy Density of States in the Unconventional Heavy-Fermion Superconductor CeCoIn5

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    Field-angle dependent specific heat measurement has been done on the heavy-fermion superconductor CeCoIn5 down to ~ 0.29 K, in a magnetic field rotating in the tetragonal c-plane. A clear fourfold angular oscillation is observed in the specific heat with the minima (maxima) occurring along the [100] ([110]) directions. Oscillation persists down to low fields H << Hc2, thus directly proving the existence of gap nodes. The results indicate that the superconducting gap symmetry is most probably of dxy type.Comment: 8 pages, 3 figures, to be published in J. Phys. Condens. Matte

    Tunable magnetic interaction at the atomic scale in oxide heterostructures

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    We report on a systematic study of a number of structurally identical but chemically distinct transition metal oxides in order to determine how the material-specific properties such as the composition and the strain affect the properties at the interface of heterostructures. Our study considers a series of structures containing two layers of ferromagnetic SrRuO3, with antiferromagnetic insulating manganites sandwiched in between. The results demonstrate how to control the strength and relative orientation of interfacial ferromagnetism in correlated electron materials by means of valence state variation and substrate-induced strain, respectively

    Probing Lepton Flavor Violation at Future Colliders

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    Supersymmetric theories with significant lepton flavor violation have e~\tilde{e} and μ~\tilde{\mu} nearly degenerate. In this case, pair production of e~+e~\tilde{e}^+ \tilde{e}^- and μ~+μ~\tilde{\mu}^+ \tilde{\mu}^- at LEPII and at the Next Linear Collider leads to the phenomenon of slepton oscillations, which is analogous to neutrino oscillations. The reach in Δm2\Delta m^2 and sin22θ\sin^2 2 \theta gives a probe of lepton flavor violation which is significantly more powerful than the current bounds from rare processes, such as μeγ\mu \to e\gamma. Polarizable ee^- beams and the eee^-e^- mode at the NLC are found to be promising options.Comment: 10 pages, 3 figures, RevTeX, minor corrections, published versio
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