478 research outputs found
Russian industry in global value-added chains
The paper analyzes Russia's participation in global value-added chains in the context of global trends in their development and the challenges facing the Russian economy in modernizing its industry.
The analysis is based on the OECDβs TiVA indicators. The results indicate that the extent of Russia's involvement in GVACs is very significant, but the nature of this participation is purely raw.
The specificity of the participation of the Russian Federation in the international fragmentation of production within GVACs is that most of the links in value chains are bottom-up. Russia is extremely limited in using imported flows to create export products with high added value.
The study confirms that in the international division of labor, Russia retains a historically established specialization, with predominance in the export of mineral and agricultural raw materials, which determines the current profile of Russia's participation in global value-added chains.peer-reviewe
ΠΡΠ΅Π½ΠΊΠ° ΠΊΠ°ΡΠ΅ΡΡΠ²Π° ΠΏΠ΅ΡΠ΅Π²ΠΎΠ·ΠΎΠΊ ΠΏΠ°ΡΡΠ°ΠΆΠΈΡΠΎΠ² Π² Π³ΠΎΡΠΎΠ΄Π΅ ΠΠΎΠ»ΠΆΡΠΊΠΎΠΌ ΠΏΠΎ ΡΡΠ΅Π±ΠΎΠ²Π°Π½ΠΈΡΠΌ ΡΠΎΡΠΈΠ°Π»ΡΠ½ΠΎΠ³ΠΎ ΡΡΠ°Π½Π΄Π°ΡΡΠ°
The article considers organisation of transportation services for passengers with public transport followed by their quality assessment in conformity with the requirements of the social standard. The objective of the article is to determine quality of passenger transportation by a municipal passenger enterprise with buses of large and medium capacity and by individual entrepreneurs carrying out transportation with minibuses. The article uses reporting materials on transportation of passengers by municipal and private carriers. To achieve the purpose, quality indicators of passenger transportation by public transport were calculated using the methodology of the social standard approved by the Ministry of Transport of the Russian Federation. The number of points for each indicator defined by the social standard for municipal carriers and individual entrepreneurs is determined, the results of relevant calculations are presented. The analysis of quality of passenger transportation services provided by municipal and private carriers was carried out. The quantitative characteristics of quality indicators values made it possible to determine the current state of passenger transportation services, identify shortcomings and make a forecast for improving quality of services. To improve quality of passenger transportation services, measures were proposed for bodies responsible for transportation and carriers.ΠΡΡΠ°ΡΡΠ΅ ΡΠ°ΡΡΠΌΠ°ΡΡΠΈΠ²Π°ΡΡΡΡ Π²ΠΎΠΏΡΠΎΡΡ ΠΎΡΠ³Π°Π½ΠΈΠ·Π°ΡΠΈΠΈ ΡΡΠ°Π½ΡΠΏΠΎΡΡΠ½ΠΎΠ³ΠΎ ΠΎΠ±ΡΠ»ΡΠΆΠΈΠ²Π°Π½ΠΈΡ ΠΏΠ°ΡΡΠ°ΠΆΠΈΡΠΎΠ² ΠΎΠ±ΡΠ΅ΡΡΠ²Π΅Π½Π½ΡΠΌ ΡΡΠ°Π½ΡΠΏΠΎΡΡΠΎΠΌ Ρ ΠΎΡΠ΅Π½ΠΊΠΎΠΉ Π΅Π³ΠΎ ΠΊΠ°ΡΠ΅ΡΡΠ²Π° ΠΏΠΎ ΡΡΠ΅Π±ΠΎΠ²Π°Π½ΠΈΡΠΌ ΡΠΎΡΠΈΠ°Π»ΡΠ½ΠΎΠ³ΠΎ ΡΡΠ°Π½Π΄Π°ΡΡΠ°. Π¦Π΅Π»Ρ ΡΡΠ°ΡΡΠΈ β ΠΎΠΏΡΠ΅Π΄Π΅Π»ΠΈΡΡ ΠΊΠ°ΡΠ΅ΡΡΠ²ΠΎ ΠΏΠ΅ΡΠ΅Π²ΠΎΠ·ΠΎΠΊ ΠΏΠ°ΡΡΠ°ΠΆΠΈΡΠΎΠ² ΠΌΡΠ½ΠΈΡΠΈΠΏΠ°Π»ΡΠ½ΡΠΌ ΠΏΠ°ΡΡΠ°ΠΆΠΈΡΡΠΊΠΈΠΌ ΠΏΡΠ΅Π΄ΠΏΡΠΈΡΡΠΈΠ΅ΠΌ Π½Π° Π°Π²ΡΠΎΠ±ΡΡΠ°Ρ
Π±ΠΎΠ»ΡΡΠΎΠΉ ΠΈ ΡΡΠ΅Π΄Π½Π΅ΠΉ Π²ΠΌΠ΅ΡΡΠΈΠΌΠΎΡΡΠΈ ΠΈ ΠΈΠ½Π΄ΠΈΠ²ΠΈΠ΄ΡΠ°Π»ΡΠ½ΡΠΌΠΈ ΠΏΡΠ΅Π΄ΠΏΡΠΈΠ½ΠΈΠΌΠ°ΡΠ΅Π»ΡΠΌΠΈ, ΠΎΡΡΡΠ΅ΡΡΠ²Π»ΡΡΡΠΈΠΌΠΈ ΠΏΠ΅ΡΠ΅Π²ΠΎΠ·ΠΊΠΈ Π½Π° Π°Π²ΡΠΎΠ±ΡΡΠ°Ρ
ΠΌΠ°Π»ΠΎΠΉ Π²ΠΌΠ΅ΡΡΠΈΠΌΠΎΡΡΠΈ. Π ΡΡΠ°ΡΡΠ΅ ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½Ρ ΠΎΡΡΡΡΠ½ΡΠ΅ ΠΌΠ°ΡΠ΅ΡΠΈΠ°Π»Ρ ΠΏΠΎ ΠΏΠ΅ΡΠ΅Π²ΠΎΠ·ΠΊΠ΅ ΠΏΠ°ΡΡΠ°ΠΆΠΈΡΠΎΠ² ΠΌΡΠ½ΠΈΡΠΈΠΏΠ°Π»ΡΠ½ΡΠΌΠΈ ΠΈ ΡΠ°ΡΡΠ½ΡΠΌΠΈ ΠΏΠ΅ΡΠ΅Π²ΠΎΠ·ΡΠΈΠΊΠ°ΠΌΠΈ. ΠΠ»Ρ Π΄ΠΎΡΡΠΈΠΆΠ΅Π½ΠΈΡ ΠΏΠΎΡΡΠ°Π²Π»Π΅Π½Π½ΠΎΠΉ ΡΠ΅Π»ΠΈ ΠΏΡΠΎΠΈΠ·Π²Π΅Π΄ΡΠ½ ΡΠ°ΡΡΡΡ ΠΏΠΎΠΊΠ°Π·Π°ΡΠ΅Π»Π΅ΠΉ ΠΊΠ°ΡΠ΅ΡΡΠ²Π° ΠΏΠ΅ΡΠ΅Π²ΠΎΠ·ΠΎΠΊ ΠΏΠ°ΡΡΠ°ΠΆΠΈΡΠΎΠ² ΠΎΠ±ΡΠ΅ΡΡΠ²Π΅Π½Π½ΡΠΌ ΡΡΠ°Π½ΡΠΏΠΎΡΡΠΎΠΌ Ρ ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΠ΅ΠΌ ΠΌΠ΅ΡΠΎΠ΄ΠΈΠΊΠΈ ΡΠΎΡΠΈΠ°Π»ΡΠ½ΠΎΠ³ΠΎ ΡΡΠ°Π½Π΄Π°ΡΡΠ° ΠΠΈΠ½ΡΡΠ°Π½ΡΠ° Π Π€. ΠΠΏΡΠ΅Π΄Π΅Π»Π΅Π½ΠΎ ΠΊΠΎΠ»ΠΈΡΠ΅ΡΡΠ²ΠΎ Π±Π°Π»Π»ΠΎΠ² ΠΏΠΎ ΠΊΠ°ΠΆΠ΄ΠΎΠΌΡ ΠΎΠΏΡΠ΅Π΄Π΅Π»ΡΠ½Π½ΠΎΠΌΡ ΡΠΎΡΠΈΠ°Π»ΡΠ½ΡΠΌ ΡΡΠ°Π½Π΄Π°ΡΡΠΎΠΌ ΠΏΠΎΠΊΠ°Π·Π°ΡΠ΅Π»Ρ Π΄Π»Ρ ΠΌΡΠ½ΠΈΡΠΈΠΏΠ°Π»ΡΠ½ΡΡ
ΠΏΠ΅ΡΠ΅Π²ΠΎΠ·ΡΠΈΠΊΠΎΠ² ΠΈ ΠΈΠ½Π΄ΠΈΠ²ΠΈΠ΄ΡΠ°Π»ΡΠ½ΡΡ
ΠΏΡΠ΅Π΄ΠΏΡΠΈΠ½ΠΈΠΌΠ°ΡΠ΅Π»Π΅ΠΉ, ΠΏΡΠ΅Π΄ΡΡΠ°Π²Π»Π΅Π½Ρ ΡΠ΅Π·ΡΠ»ΡΡΠ°ΡΡ ΡΠ°ΡΡΡΡΠΎΠ². ΠΡΠΎΠ²Π΅Π΄ΡΠ½ Π°Π½Π°Π»ΠΈΠ· ΠΊΠ°ΡΠ΅ΡΡΠ²Π° ΡΡΠ»ΡΠ³ ΠΏΠΎ ΠΏΠ΅ΡΠ΅Π²ΠΎΠ·ΠΊΠ΅ ΠΏΠ°ΡΡΠ°ΠΆΠΈΡΠΎΠ² ΠΌΡΠ½ΠΈΡΠΈΠΏΠ°Π»ΡΠ½ΡΠΌΠΈ ΠΈ ΡΠ°ΡΡΠ½ΡΠΌΠΈ ΠΏΠ΅ΡΠ΅Π²ΠΎΠ·ΡΠΈΠΊΠ°ΠΌΠΈ. ΠΠΎΠ»ΠΈΡΠ΅ΡΡΠ²Π΅Π½Π½ΡΠ΅ Ρ
Π°ΡΠ°ΠΊΡΠ΅ΡΠΈΡΡΠΈΠΊΠΈ ΠΏΠΎΠΊΠ°Π·Π°ΡΠ΅Π»Π΅ΠΉ ΠΊΠ°ΡΠ΅ΡΡΠ²Π° ΠΏΠΎΠ·Π²ΠΎΠ»ΠΈΠ»ΠΈ ΠΎΠΏΡΠ΅Π΄Π΅Π»ΠΈΡΡ ΡΠ΅ΠΊΡΡΠ΅Π΅ ΡΠΎΡΡΠΎΡΠ½ΠΈΠ΅ ΡΡΠ»ΡΠ³ ΠΏΠΎ ΠΏΠ΅ΡΠ΅Π²ΠΎΠ·ΠΊΠ΅ ΠΏΠ°ΡΡΠ°ΠΆΠΈΡΠΎΠ², Π²ΡΡΠ²ΠΈΡΡ Π½Π΅Π΄ΠΎΡΡΠ°ΡΠΊΠΈ ΠΈ Π΄Π°ΡΡ ΠΏΡΠΎΠ³Π½ΠΎΠ· ΡΠ»ΡΡΡΠ΅Π½ΠΈΡ ΠΊΠ°ΡΠ΅ΡΡΠ²Π° ΡΡΠ»ΡΠ³. Π‘ ΡΠ΅Π»ΡΡ ΡΠ»ΡΡΡΠ΅Π½ΠΈΡ ΠΊΠ°ΡΠ΅ΡΡΠ²Π° ΡΡΠ»ΡΠ³ ΠΏΠΎ ΠΏΠ΅ΡΠ΅Π²ΠΎΠ·ΠΊΠ΅ ΠΏΠ°ΡΡΠ°ΠΆΠΈΡΠΎΠ² ΠΏΡΠ΅Π΄Π»ΠΎΠΆΠ΅Π½Ρ ΠΌΠ΅ΡΠΎΠΏΡΠΈΡΡΠΈΡ Π΄Π»Ρ ΠΎΡΠ³Π°Π½ΠΈΠ·Π°ΡΠΎΡΠΎΠ² ΠΏΠ΅ΡΠ΅Π²ΠΎΠ·ΠΎΠΊ ΠΈ ΠΏΠ΅ΡΠ΅Π²ΠΎΠ·ΡΠΈΠΊΠΎΠ²
The incidence and aggravating factors of male hypogonadism in type 2 diabetes
BACKGROUND: Male hypogonadism is associated with type 2 diabetes mellitus (T2DM), therefore, it is of interest to study its frequency. The clinical symptoms of hypogonadism are not specific, and laboratory diagnostics is the basis for its detection. The optimal method for this diagnostics is isotope dilution liquid chromatography/tandem mass spectrometry, which was used in our study.Β AIMS: Assessment of the incidence and aggravating factors of male hypogonadism in type 2 diabetesMATERIALS AND METHODS: A full-design, cross-sectional, screening, single-center, non-interventional study included men with T2DM, who were he was treated in Endocrinology Research Centre, Moscow. The study was conducted from October 2021 to January 2022. Medical history assessment, physical examination with determination of body mass index (BMI), measurement estimation of total testosterone by isotope dilution liquid chromatography/tandem mass spectrometry, glycated hemoglobin (HbA1c) and lipid profiles were performed. The groups were compared using the Mann-Whitney U-test for quantitative indicators and ΟΒ² with Yatesβ correction for qualitative ones. Differences were considered statistically significant with p0,05.RESULTS: Hypogonadism was detected in 355 (70.3%) men with T2DM. Patients with hypogonadism had statistically significantly higher BMI, worse glycemic control, lower HDL levels, and higher triglycerides than eugonadal men. An additional comparative analysis among non-obese individuals showed the presence of statistically significant differences in the level of HbA1c (higher in hypogonadal men) and HDL (lower in hypogonadal men). An analysis of hypogonadal patients depending on the presence of obesity showed statistically significant differences between groups in the level of total testosterone (lower in obese men) and triglycerides (higher in obese men).CONCLUSIONS: The prevalence of male hypogonadism in type 2 diabetes was 70,3%. Its development was associated with obesity and poor glycemic control
Study of the surface microrelief of copper nanoparticles by the method of scanning probe microscopy
This work was supported by grants from the RFBR β 17-07-00407-Π° and β 17-32-50137-mol_nr
Ethnic stereotypesβ reflection by means of modern cinematography
The aim of the research work is to identify the specifics of auto and hetero stereotypes about Americans and Russians on the example of modern cinema in the USA and Russia. It is established that the specificity of ethnic stereotypes represented by modern films of the USA and Russia depends on the culture of the society, the conditions of its development, the depth of contacts between ethnic groups in the process of historical developmen
Β«ΠΠ½ΡΠ΅ΡΠ²Π°Π»Ρ Π±Π΅Π·ΠΎΠΏΠ°ΡΠ½ΠΎΡΡΠΈΒ» Π½Π° ΠΎΡΡΠ°Π½ΠΎΠ²ΠΊΠ°Ρ Π°Π²ΡΠΎΠ±ΡΡΠΎΠ² Π³ΠΎΡΠΎΠ΄Π° ΠΠΎΠ»ΠΆΡΠΊΠΎΠ³ΠΎ
[For the English abstract and full text of the article please see the attached PDF-File (English version follows Russian version)].ABSTRACT Analysis of the street-road network in the city of Volzhsky, a tense security situation with embarkation and disembarkation of public transport passengers is provided. The discrepancy between the lengths of stopping points and the incoming traffic of buses is determined. Proposals are made to improve the quality of passenger transportation, taking into account safety intervals at bus stops and optimizing the routes of urban public transport, private buses and fixed-route taxis. Keywords: urban public transport, bus, stopping point, safety interval, route network, route optimization.Π’Π΅ΠΊΡΡ Π°Π½Π½ΠΎΡΠ°ΡΠΈΠΈ Π½Π° Π°Π½Π³Π». ΡΠ·ΡΠΊΠ΅ ΠΈ ΠΏΠΎΠ»Π½ΡΠΉ ΡΠ΅ΠΊΡΡ ΡΡΠ°ΡΡΠΈ Π½Π° Π°Π½Π³Π». ΡΠ·ΡΠΊΠ΅ Π½Π°Ρ
ΠΎΠ΄ΠΈΡΡΡ Π² ΠΏΡΠΈΠ»Π°Π³Π°Π΅ΠΌΠΎΠΌ ΡΠ°ΠΉΠ»Π΅ ΠΠΠ€ (Π°Π½Π³Π». Π²Π΅ΡΡΠΈΡ ΡΠ»Π΅Π΄ΡΠ΅Ρ ΠΏΠΎΡΠ»Π΅ ΡΡΡΡΠΊΠΎΠΉ Π²Π΅ΡΡΠΈΠΈ).ΠΠ½Π°Π»ΠΈΠ· ΡΠ»ΠΈΡΠ½ΠΎ-Π΄ΠΎΡΠΎΠΆΠ½ΠΎΠΉ ΡΠ΅ΡΠΈ Π² Π³ΠΎΡΠΎΠ΄Π΅ ΠΠΎΠ»ΠΆΡΠΊΠΎΠΌ, Π½Π°ΠΏΡΡΠΆΡΠ½Π½ΠΎΠΉ ΡΠΈΡΡΠ°ΡΠΈΠΈ Ρ ΠΎΠ±Π΅ΡΠΏΠ΅ΡΠ΅Π½ΠΈΠ΅ΠΌ Π±Π΅Π·ΠΎΠΏΠ°ΡΠ½ΠΎΡΡΠΈ Ρ ΠΏΠΎΡΠ°Π΄ΠΊΠΎΠΉ ΠΈ Π²ΡΡΠ°Π΄ΠΊΠΎΠΉ ΠΏΠ°ΡΡΠ°ΠΆΠΈΡΠΎΠ² ΠΎΠ±ΡΠ΅ΡΡΠ²Π΅Π½Π½ΠΎΠ³ΠΎ ΡΡΠ°Π½ΡΠΏΠΎΡΡΠ°. ΠΠΏΡΠ΅Π΄Π΅Π»Π΅Π½ΠΎ Π½Π΅ΡΠΎΠΎΡΠ²Π΅ΡΡΡΠ²ΠΈΠ΅ Π΄Π»ΠΈΠ½ ΠΎΡΡΠ°Π½ΠΎΠ²ΠΎΡΠ½ΡΡ
ΠΏΡΠ½ΠΊΡΠΎΠ² Π²Ρ
ΠΎΠ΄ΡΡΠ΅ΠΌΡ ΠΏΠΎΡΠΎΠΊΡ Π°Π²ΡΠΎΠ±ΡΡΠΎΠ². ΠΡΠ΅Π΄Π»ΠΎΠΆΠ΅Π½Ρ ΠΌΠ΅ΡΠΎΠΏΡΠΈΡΡΠΈΡ ΠΏΠΎ ΡΠ»ΡΡΡΠ΅Π½ΠΈΡ ΠΊΠ°ΡΠ΅ΡΡΠ²Π° ΠΏΠ΅ΡΠ΅Π²ΠΎΠ·ΠΊΠΈ ΠΏΠ°ΡΡΠ°ΠΆΠΈΡΠΎΠ² Ρ ΡΡΡΡΠΎΠΌ ΠΈΠ½ΡΠ΅ΡΠ²Π°Π»ΠΎΠ² Π±Π΅Π·ΠΎΠΏΠ°ΡΠ½ΠΎΡΡΠΈ Π½Π° ΠΎΡΡΠ°Π½ΠΎΠ²ΠΊΠ°Ρ
Π°Π²ΡΠΎΠ±ΡΡΠΎΠ² ΠΈ ΠΎΠΏΡΠΈΠΌΠΈΠ·Π°ΡΠΈΠΈ ΠΌΠ°ΡΡΡΡΡΠΎΠ² Π³ΠΎΡΠΎΠ΄ΡΠΊΠΎΠ³ΠΎ ΠΎΠ±ΡΠ΅ΡΡΠ²Π΅Π½Π½ΠΎΠ³ΠΎ ΡΡΠ°Π½ΡΠΏΠΎΡΡΠ°, ΡΠ°ΡΡΠ½ΡΡ
Π°Π²ΡΠΎΠ±ΡΡΠΎΠ² ΠΈ ΠΌΠ°ΡΡΡΡΡΠ½ΡΡ
ΡΠ°ΠΊΡΠΈ
Predicted facies, sedimentary structures and potential resources of Jurassic petroleum complex in S-E Western Siberia (based on well logging data)
This paper is devoted to the current problem in petroleum geology and geophysics- prediction of facies sediments for further evaluation of productive layers. Applying the acoustic method and the characterizing sedimentary structure for each coastal-marine-delta type was determined. The summary of sedimentary structure characteristics and reservoir properties (porosity and permeability) of typical facies were described. Logging models SP, EL and GR (configuration, curve range) in interpreting geophysical data for each litho-facies were identified. According to geophysical characteristics these sediments can be classified as coastal-marine-delta. Prediction models for potential Jurassic oil-gas bearing complexes (horizon J[1]{1}) in one S-E Western Siberian deposit were conducted. Comparing forecasting to actual testing data of layer J[1]{1} showed that the prediction is about 85%
Extracellular vesicles derived from Acholeplasma laidlawii PG8
Extracellular vesicle production is believed to be a ubiquitous process in bacteria, but the data on such a process in Mollicutes are absent. We report the isolation of ultramicroforms - extracellular vesicles from supernatants of Acholeplasma laidlawii PG8 (ubiquitous mycoplasma; the main contaminant of cell culture). Considering sizes, morphology, and ultrastructural organization, the ultramicroforms of A. laidlawii PG8 are similar to membrane vesicles of Gram-positive and Gram-negative bacteria. We demonstrate that A. laidlawii PG8 vesicles contain genetic material and proteins, and are mutagenic to lymphocytes of human peripheral blood. We show that Mycoplasma gallisepticum S6, the other mycoplasma, also produce similar structures, which suggests that shedding of the vesicles might be the common phenomenon in Mollicutes. We found that the action of stress conditions results in the intensive formation of ultramicroforms in mycoplasmas. The role of vesicular formation in mycoplasmas remains to be studied. Β©2011 with author. Published by TheScientificWorld
Hydrochemical and biogeochemical features of freshwater and brackish lakes in eastern Sikhote-Alin
Concentration of major ions and trace metals dissolved and suspended in water and trace metals in plankton of freshwater (Vaskovskoye, Golubichnoye, Yaponskoye) and brackish (Dukhovskoye, Krugloye, Mramornoye, Blagodati) lakes of eastern Sikhote-Alin is determined in July 2011-2012. The Lakes Golubichnoye and Blagodati are included in the Sikhote-Alin State Natural Biosphere Reserve. Anions are detected by the liquid chromatography (Shimadzu LC-10AVP), cations and metals are analyzed by the atomic absorption spectrophotometry (AAS Shimadzu 6800), and carbon concentration is measured by the method of thermocatalytic oxidation with infrared registration (TOC-VCPN, Shimadzu). The freshwater lakes of eastern Sikhote-Alin are distinguished by heightened concentrations of chlorides, sulfates, and sodium as compared with lakes of East-European Plain, mainly because of aerial transfer of ions from the sea. The ions concentration in brackish lakes is determined by direct penetration of seawater. Difference of the heavy metals concentration between freshwater and brackish lakes is negligible, except the manganese with higher concentration in the freshwater lakes. Lakes with wetlands in their drainage area have high concentrations of dissolved organic carbon, iron and manganese, which are depended on water regime. Concentrations of trace metals in the lakes water are low because of its pluvial origin (rainwater transforms slightly in the process of filtration through effusive rocks), with exception of Lake Vaskovskoe located in the area of mining and processing the polymetallic and borosilicate ores, close to the lead smeltery in Rudnaya Pristan stopped in 2009: the lead concentration in the water of this lake is heightened, both in dissolved and suspended forms, though does not exceed the maximal permissible concentration for drinking water. Accumulation of metals by plankton is determined mainly by biological need of the plankton in these elements and practically doesnβt depend on their concentration in water
ΠΠΠΠΠ’ΠΠ€ΠΠΠΠ¦ΠΠ― ΠΠ ΠΠΠΠ‘ΠΠ Π ΠΠ«Π‘ΠΠΠΠ§ΠΠ‘Π’ΠΠ Π‘ΠΠ Π Π‘ ΠΠ‘ΠΠΠΠ¬ΠΠΠΠΠΠΠΠ ΠΠΠ’ΠΠΠ Π₯Π ΠΠΠΠ’Π-ΠΠΠ‘Π‘-Π‘ΠΠΠΠ’Π ΠΠΠΠ’Π ΠΠ
For the first time the molecular impurity composition of high-purity sulfur was investigated using gas chromatography-mass spectrometry method. The sample preparation consisted of extracting the impurities from the sulfur samples during their vacuum distillation. The sample mass of sulfur, which was used for the extraction, was up to 1 kg. Impurities were condensed in glass ampoules which then carried them to the inlet in the dosing system of gas chromatography-mass spectrometer. For their separation, GS-GasPro capillary adsorption columns with a modified silica gel sorbent and with polytrimethylsilylpropyne were used. The joint application of these columns made it possible to determine a wide range of impurity substances in sulfur. Identification of impurities was carried out by comparing their experimental mass spectra with the data from the NIST database. In the case of overlapping chromatographic peaks of impurities their identification was carried out according to the characteristic ions and subtracting the peaks of ions that belong to the adjacent component. It was found that, when using the column with polytrimethylsilylpropyne, oxygen and nitrogen containing organic substances elute in asymmetric peaks with a steep front and a diffused rear. In high purity sulfur the impurities of permanent gases, carbon dioxide, hydrogen sulfide, sulfur dioxide, Ρarbonyl sulphide, saturated and unsaturated hydrocarbons C2-C8, aromatic hydrocarbons, oxygen-, nitrogen-, sulfur-containing hydrocarbons were identified. The total number of identified impurities equaled to 51.Keywords: high-purity sulfur, impurities, identification, gas chromatography-mass spectrometry, capillary columnDOI: http://dx.doi.org/10.15826/analitika.2017.21.3.005Β Π.Iu. Sozin, M.F. Churbanov, Π.Iu. Chernova, T.G. Sorochkina, I.V. Skripachev, G.E. SnopatinΒ G.G. Devyatykh Institute of Chemistry of High-Purity Substances of the Russian Academy of Science, Tropinina Str., 49, Nizhny Novgood, 603950,Β Russian FederationΒ Β ΠΠΏΠ΅ΡΠ²ΡΠ΅ Ρ ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΠ΅ΠΌ ΠΌΠ΅ΡΠΎΠ΄Π° Ρ
ΡΠΎΠΌΠ°ΡΠΎ-ΠΌΠ°ΡΡ-ΡΠΏΠ΅ΠΊΡΡΠΎΠΌΠ΅ΡΡΠΈΠΈ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ ΠΌΠΎΠ»Π΅ΠΊΡΠ»ΡΡΠ½ΡΠΉ ΠΏΡΠΈΠΌΠ΅ΡΠ½ΡΠΉ ΡΠΎΡΡΠ°Π² Π²ΡΡΠΎΠΊΠΎΡΠΈΡΡΠΎΠΉ ΡΠ΅ΡΡ. ΠΠ»Ρ ΠΏΡΠΎΠ±ΠΎΠΏΠΎΠ΄Π³ΠΎΡΠΎΠ²ΠΊΠΈ ΠΎΠ±ΡΠ°Π·ΡΠΎΠ² ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π»ΠΈ ΠΈΠ·Π²Π»Π΅ΡΠ΅Π½ΠΈΠ΅ ΠΏΡΠΈΠΌΠ΅ΡΠ΅ΠΉ ΠΈΠ· ΡΠ΅ΡΡ ΠΏΡΠΈ Π΅Π΅ Π²Π°ΠΊΡΡΠΌΠ½ΠΎΠΉ ΠΏΠ΅ΡΠ΅Π³ΠΎΠ½ΠΊΠ΅. ΠΠ°ΡΡΠ° ΠΏΡΠΎΠ±Ρ ΡΠ΅ΡΡ, ΠΈΠ· ΠΊΠΎΡΠΎΡΠΎΠΉ ΠΏΡΠΎΠ²ΠΎΠ΄ΠΈΠ»ΠΈ ΠΈΠ·Π²Π»Π΅ΡΠ΅Π½ΠΈΠ΅, ΡΠΎΡΡΠ°Π²Π»ΡΠ»Π° Π΄ΠΎ 1 ΠΊΠ³. ΠΡΠΈΠΌΠ΅ΡΠΈ ΠΊΠΎΠ½Π΄Π΅Π½ΡΠΈΡΠΎΠ²Π°Π»ΠΈ Π² ΡΡΠ΅ΠΊΠ»ΡΠ½Π½ΡΡ
Π°ΠΌΠΏΡΠ»Π°Ρ
, ΠΈΠ· ΠΊΠΎΡΠΎΡΡΡ
Π·Π°ΡΠ΅ΠΌ ΠΎΡΡΡΠ΅ΡΡΠ²Π»ΡΠ»ΠΈ ΠΈΡ
Π½Π°ΠΏΡΡΠΊ Π² ΡΠΈΡΡΠ΅ΠΌΡ Π΄ΠΎΠ·ΠΈΡΠΎΠ²Π°Π½ΠΈΡ Ρ
ΡΠΎΠΌΠ°ΡΠΎ-ΠΌΠ°ΡΡ-ΡΠΏΠ΅ΠΊΡΡΠΎΠΌΠ΅ΡΡΠ°. ΠΠ»Ρ ΠΈΡ
ΡΠ°Π·Π΄Π΅Π»Π΅Π½ΠΈΡ ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π»ΠΈ ΠΊΠ°ΠΏΠΈΠ»Π»ΡΡΠ½ΡΠ΅ Π°Π΄ΡΠΎΡΠ±ΡΠΈΠΎΠ½Π½ΡΠ΅ ΠΊΠΎΠ»ΠΎΠ½ΠΊΠΈ GS-GasPro Ρ ΠΌΠΎΠ΄ΠΈΡΠΈΡΠΈΡΠΎΠ²Π°Π½Π½ΡΠΌ ΡΠΈΠ»ΠΈΒΠΊΠ°Π³Π΅Π»Π΅ΠΌ Π² ΠΊΠ°ΡΠ΅ΡΡΠ²Π΅ ΡΠΎΡΠ±Π΅Π½ΡΠ° ΠΈ Ρ ΠΏΠΎΠ»ΠΈΡΡΠΈΠΌΠ΅ΡΠΈΠ»ΡΠΈΠ»ΠΈΠ»ΠΏΡΠΎΠΏΠΈΠ½ΠΎΠΌ (ΠΠ’ΠΠ‘Π). Π‘ΠΎΠ²ΠΌΠ΅ΡΡΠ½ΠΎΠ΅ ΠΏΡΠΈΠΌΠ΅Π½Π΅Π½ΠΈΠ΅ ΡΡΠΈΡ
ΠΊΠΎΠ»ΠΎΠ½ΠΎΠΊ ΠΏΠΎΠ·Π²ΠΎΠ»ΡΠ΅Ρ ΠΎΠΏΡΠ΅Π΄Π΅Π»ΡΡΡ Π² ΡΠ΅ΡΠ΅ ΡΠΈΡΠΎΠΊΠΈΠΉ ΠΊΡΡΠ³ ΠΏΡΠΈΠΌΠ΅ΡΠ½ΡΡ
Π²Π΅ΡΠ΅ΡΡΠ². ΠΠ΄Π΅Π½ΡΠΈΡΠΈΠΊΠ°ΡΠΈΡ ΠΏΡΠΈΠΌΠ΅ΡΠ΅ΠΉ ΠΏΡΠΎΠ²ΠΎΠ΄ΠΈΠ»ΠΈ ΡΡΠ°Π²Π½Π΅Π½ΠΈΠ΅ΠΌ ΠΈΡ
ΡΠΊΡΠΏΠ΅ΡΠΈΠΌΠ΅Π½ΡΠ°Π»ΡΠ½ΡΡ
ΠΌΠ°ΡΡ-ΡΠΏΠ΅ΠΊΡΡΠΎΠ² Ρ Π΄Π°Π½Π½ΡΠΌΠΈ Π±Π°Π·Ρ NIST. Π ΡΠ»ΡΡΠ°Π΅ Π½Π°Π»ΠΎΠΆΠ΅Π½ΠΈΡ Ρ
ΡΠΎΠΌΠ°ΡΠΎΠ³ΡΠ°ΡΠΈΡΠ΅ΡΠΊΠΈΡ
ΠΏΠΈΠΊΠΎΠ² ΠΏΡΠΈΠΌΠ΅ΡΠ΅ΠΉ ΠΈΡ
ΠΈΠ΄Π΅Π½ΡΠΈΡΠΈΠΊΠ°ΡΠΈΡ ΠΏΡΠΎΠ²ΠΎΠ΄ΠΈΠ»ΠΈ ΠΏΠΎ Ρ
Π°ΡΠ°ΠΊΡΠ΅ΡΠΈΡΡΠΈΡΠ΅ΡΠΊΠΈΠΌ ΠΈΠΎΠ½Π°ΠΌ ΠΈ Ρ ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΠ΅ΠΌ Π²ΡΡΠΈΡΠ°Π½ΠΈΡ ΠΏΠΈΠΊΠΎΠ² ΠΈΠΎΠ½ΠΎΠ², ΠΏΡΠΈΠ½Π°Π΄Π»Π΅ΠΆΠ°ΡΠΈΡ
ΡΠΎΡΠ΅Π΄Π½Π΅ΠΌΡ ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½ΡΡ. Π£ΡΡΠ°Π½ΠΎΠ²Π»Π΅Π½ΠΎ, ΡΡΠΎ ΠΏΡΠΈ ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΠΈ ΠΊΠΎΠ»ΠΎΠ½ΠΊΠΈ Ρ ΠΏΠΎΠ»ΠΈΡΡΠΈΠΌΠ΅ΡΠΈΠ»ΡΠΈΠ»ΠΈΠ»ΠΏΡΠΎΠΏΠΈΠ½ΠΎΠΌ ΠΊΠΈΡΠ»ΠΎΡΠΎΠ΄- ΠΈ Π°Π·ΠΎΡΡΠΎΠ΄Π΅ΡΠΆΠ°ΡΠΈΠ΅ ΠΎΡΠ³Π°Π½ΠΈΡΠ΅ΡΠΊΠΈΠ΅ Π²Π΅ΡΠ΅ΡΡΠ²Π° ΡΠ»ΡΠΈΡΡΡΡΡΡ Π² Π²ΠΈΠ΄Π΅ Π°ΡΡΠΈΠΌΠ΅ΡΡΠΈΡΠ½ΡΡ
ΠΏΠΈΠΊΠΎΠ² Ρ ΠΊΡΡΡΡΠΌ ΡΡΠΎΠ½ΡΠΎΠΌ ΠΈ ΡΠ°Π·ΠΌΡΡΡΠΌ ΡΡΠ»ΠΎΠΌ. Π Π²ΡΡΠΎΠΊΠΎΡΠΈΡΡΠΎΠΉ ΡΠ΅ΡΠ΅ ΠΈΠ΄Π΅Π½ΡΠΈΡΠΈΡΠΈΡΠΎΠ²Π°Π½Ρ ΠΏΡΠΈΠΌΠ΅ΡΠΈ ΠΏΠΎΡΡΠΎΡΠ½Π½ΡΡ
Π³Π°Π·ΠΎΠ², Π΄ΠΈΠΎΠΊΡΠΈΠ΄Π° ΡΠ³Π»Π΅ΡΠΎΠ΄Π°, ΡΠ΅ΡΠΎΠ²ΠΎΠ΄ΠΎΡΠΎΠ΄Π°, Π΄ΠΈΠΎΠΊΡΠΈΠ΄Π° ΡΠ΅ΡΡ, ΡΠ΅ΡΠΎΠΎΠΊΠΈΡΠΈ ΡΠ³Π»Π΅ΡΠΎΠ΄Π°, ΠΏΡΠ΅Π΄Π΅Π»ΡΠ½ΡΡ
ΠΈ Π½Π΅ΠΏΡΠ΅Π΄Π΅Π»ΡΠ½ΡΡ
ΡΠ³Π»Π΅Π²ΠΎΠ΄ΠΎΡΠΎΠ΄ΠΎΠ² Π‘2βΠ‘8, Π°ΡΠΎΠΌΠ°ΡΠΈΡΠ΅ΡΠΊΠΈΡ
ΡΠ³Π»Π΅Π²ΠΎΠ΄ΠΎΡΠΎΠ΄ΠΎΠ², ΠΊΠΈΡΠ»ΠΎΡΠΎΠ΄-, Π°Π·ΠΎΡ-, ΡΠ΅ΡΠΎΡΠΎΠ΄Π΅ΡΠΆΠ°ΡΠΈΡ
Π²Π΅ΡΠ΅ΡΡΠ². ΠΠ±ΡΠ΅Π΅ ΠΈΡ
ΡΠΈΡΠ»ΠΎ ΡΠΎΡΡΠ°Π²ΠΈΠ»ΠΎ 51.ΠΠ»ΡΡΠ΅Π²ΡΠ΅ ΡΠ»ΠΎΠ²Π°: Π²ΡΡΠΎΠΊΠΎΡΠΈΡΡΠ°Ρ ΡΠ΅ΡΠ°, ΠΏΡΠΈΠΌΠ΅ΡΠΈ, ΠΈΠ΄Π΅Π½ΡΠΈΡΠΈΠΊΠ°ΡΠΈΡ, Ρ
ΡΠΎΠΌΠ°ΡΠΎ-ΠΌΠ°ΡΡ-ΡΠΏΠ΅ΠΊΡΡΠΎΠΌΠ΅ΡΡΠΈΡ, ΠΊΠ°ΠΏΠΈΠ»Π»ΡΡΠ½Π°Ρ ΠΊΠΎΠ»ΠΎΠ½ΠΊΠ°DOI: http://dx.doi.org/10.15826/analitika.2017.21.3.00
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