THE EFFECTS OF RARE EARTHS ON ACTIVITY AND SURFACE PROPERTIES OF Ru/γ-AL2O3 CATALYST FOR WATER GAS SHIFT REACTION

A series of Ru-RE/γ-AL2O3 (RE = Ce, Pr, La, Sm, Tb or Gd) and Ru/γ-AL2O3 catalysts were prepared by impregnation method. The influence of rare earths on the catalytic performance of Ru/γ-AL2O3 catalyst for the water gas shift reaction was studied. The catalysts were characterized by X-ray diffraction (XRD), temperature programmed reduction (TPR), temperature programmed desorption (TPD), and CO chemisorption. The results show that the addition of rare earths increases the catalytic activity of Ru based catalyst. Among these cerium is the most remarkably. The addition of cerium increases the active surface area, improves the dispersion of ruthenium, and weakens the interaction between ruthenium and the support. Cerium also affects the adsorption and reduction properties of Ru/γ-AL2O3 catalyst. KEY WORDS: Rare earths, Ruthenium-based catalyst, Water gas shift reaction Bull. Chem. Soc. Ethiop. 2007, 21(3), 389-395

Visual and Textual Prior Guided Mask Assemble for Few-Shot Segmentation and Beyond

Few-shot segmentation (FSS) aims to segment the novel classes with a few annotated images. Due to CLIP's advantages of aligning visual and textual information, the integration of CLIP can enhance the generalization ability of FSS model. However, even with the CLIP model, the existing CLIP-based FSS methods are still subject to the biased prediction towards base classes, which is caused by the class-specific feature level interactions. To solve this issue, we propose a visual and textual Prior Guided Mask Assemble Network (PGMA-Net). It employs a class-agnostic mask assembly process to alleviate the bias, and formulates diverse tasks into a unified manner by assembling the prior through affinity. Specifically, the class-relevant textual and visual features are first transformed to class-agnostic prior in the form of probability map. Then, a Prior-Guided Mask Assemble Module (PGMAM) including multiple General Assemble Units (GAUs) is introduced. It considers diverse and plug-and-play interactions, such as visual-textual, inter- and intra-image, training-free, and high-order ones. Lastly, to ensure the class-agnostic ability, a Hierarchical Decoder with Channel-Drop Mechanism (HDCDM) is proposed to flexibly exploit the assembled masks and low-level features, without relying on any class-specific information. It achieves new state-of-the-art results in the FSS task, with mIoU of $77.6$ on $\text{PASCAL-}5^i$ and $59.4$ on $\text{COCO-}20^i$ in 1-shot scenario. Beyond this, we show that without extra re-training, the proposed PGMA-Net can solve bbox-level and cross-domain FSS, co-segmentation, zero-shot segmentation (ZSS) tasks, leading an any-shot segmentation framework

Transcription factor Hlx controls a systematic switch from white to brown fat through Prdm16-mediated co-activation

Browning of subcutaneous white fat (iWAT) involves several reprograming events, but the underlying mechanisms are incompletely understood. Here we show that the transcription factor Hlx is selectively expressed in brown adipose tissue (BAT) and iWAT, and is translationally upregulated by beta3-adrenergic signaling-mediated suppression of the translational inhibitor 4E-BP1. Hlx interacts with and is co-activated by Prdm16 to control BAT-selective gene expression and mitochondrial biogenesis. Hlx heterozygous knockout mice have defects in brown-like adipocyte formation in iWAT, and develop glucose intolerance and high fat-induced hepatic steatosis. Conversely, transgenic expression of Hlx at a physiological level drives a full program of thermogenesis and converts iWAT to brown-like fat, which improves glucose homeostasis and prevents obesity and hepatic steatosis. The adipose remodeling phenotypes are recapitulated by fat-specific injection of Hlx knockdown and overexpression viruses, respectively. Our studies establish Hlx as a powerful regulator for systematic white adipose tissue browning and offer molecular insights into the underlying transcriptional mechanism.The transcriptional co-activator Prdm16 regulates browning of white adipose tissue (WAT). Here, the authors show that Prdm16 interacts with the transcription factor Hlx, which is stabilized in response to beta3-adrenergic signaling, to increase thermogenic gene expression and mitochondrial biogenesis in subcutaneous WAT

Metabolic Profiling Study of Yang Deficiency Syndrome in Hepatocellular Carcinoma by H

This study proposes a 1H NMR-based metabonomic approach to explore the biochemical characteristics of Yang deficiency syndrome in hepatocellular carcinoma (HCC) based on serum metabolic profiling. Serum samples from 21 cases of Yang deficiency syndrome HCC patients (YDS-HCC) and 21 cases of non-Yang deficiency syndrome HCC patients (NYDS-HCC) were analyzed using 1H NMR spectroscopy and partial least squares discriminant analysis (PLS-DA) was applied to visualize the variation patterns in metabolic profiling of sera from different groups. The differential metabolites were identified and the biochemical characteristics were analyzed. We found that the intensities of six metabolites (LDL/VLDL, isoleucine, lactate, lipids, choline, and glucose/sugars) in serum of Yang deficiency syndrome patients were lower than those of non-Yang deficiency syndrome patients. It implies that multiple metabolisms, mainly including lipid, amino acid, and energy metabolisms, are unbalanced or weakened in Yang deficiency syndrome patients with HCC. The decreased intensities of metabolites including LDL/VLDL, isoleucine, lactate, lipids, choline, and glucose/sugars in serum may be the distinctive metabolic variations of Yang deficiency syndrome patients with HCC. And these metabolites may be potential biomarkers for diagnosis of Yang deficiency syndrome in HCC

Morphology and oil quality of introduced olive cultivars (Olea europaea L.) in southwest China

There are enormous benefits of olive cultivation in China. However, rare researches are reported about the morphological and oil qualitative characteristics of the introduced olive cultivars in southwest China. The characteristics of morphological and oil qualitative were investigated among seven introduced olive cultivars and an indigenous cultivar cultivated in southwest China. The results elucidated that all cultivars had adapted to a new environment and expressed unique characteristics. The Coratina, Koroneiki and Grossanne remained excellent oil cultivars with the fresh oil content of 20.42, 18.58 and 16.46%, respectively. The free acidity and peroxide value of olive oil were within the range of the extra virgin olive oil category. And the extracted olive oil was rich in unsaturated fatty acid, α-tocopherol, squalene, stigmasterol, β-sitosterol and phenolic compounds. Moreover, the olive cultivated in southwest China exhibited a higher content of moisture, oleic acid and unsaturated fatty acid compared to scientific studies. Therefore, the region of southwest China (Jintang), a new environment, was a potential for cultivation and development of olive in the future. In addition, the results can provide theoretical guidance for olive planting and cultivar selection in southwest China

Case report: Adrenal myelolipoma resected by laparoscopic surgery

IntroductionAdrenal myelolipomas are benign tumors composed mainly of lipomatous elements with myeloid cells. With the development of medical imaging technology, the detection rate has gradually increased. We report a case of adrenal myelolipoma successfully excised through the laparoscope and reviewed existing literature in recent ten years to summarize the feasibility of the laparoscopic approach for this tumor.Case presentationHerein, we described a case of adrenal myelolipoma resected by laparoscope in a 63-year-old male patient. He did not have any other symptoms except the incidental finding of a left adrenal mass. An abdominal CT examination revealed a mixed-density lesion containing some amount of adipose tissue. In conjunction with the patient’s willingness, we performed a laparoscopic operation to remove the lump. The definite diagnosis was confirmed as an adrenal myelolipoma according to the pathology. The patient recovered well postoperatively and without signs of recurrence at a 5-month follow-up.ConclusionAdrenal myelolipoma is commonly benign, asymptomatic, and hormonal inactivity. A surgical strategy is suggested for high-complication-risk patients. The laparoscopic approach is safe and effective with an obvious advantage over open procedures

Highly Efficient Visible Light Catalysts Driven by Ti3+-V-O-2Ti(4+)-N3- Defect Clusters

Local defect structures play significant roles on material properties, but they are seriously neglected in the design, synthesis, and development of highly efficient TiO2‐based visible light catalysts (VLCs). Here, we take anatase TiO2 nanocrystals that contain (Ti3+, N3−) ions and have the complicated chemical formula of (urn:x-wiley:2199692X:media:cnma201800400:cnma201800400-math-0001 )(urn:x-wiley:2199692X:media:cnma201800400:cnma201800400-math-0002 □z) as an example, and point out that the formation of Ti3+‐VO‐2Ti4+‐N3− local defect clusters is a key missing step for significantly enhancing VLC properties of host TiO2 nanocrystals. Experimental and theoretical investigations also demonstrate the emergent behaviors of these intentionally introduced defect clusters for developing highly efficient VLCs. This research thus not only provides highly efficient visible light catalysts for various practical applications but also addresses the significance of local defect structures on modifying material properties.Q. Sun, D. Cortie, T. J. Frankcome, N. Cox and Y. Liu acknowledge the supports of the Australian Research Council in the form of Discovery Projects and the ARC Future Fellowships program. S. Zhang and W. Shi thank the support from CAS (1A1111KYSB20180017, XDB17030000)

Deep Intraspecific Divergence in the Endemic Herb Lancea tibetica (Mazaceae) Distributed Over the Qinghai-Tibetan Plateau

Qinghai-Tibetan Plateau (QTP) is an important biodiversity hub, which is very sensitive to climate change. Here in this study, we investigated genetic diversity and past population dynamics of Lancea tibetica (Mazaceae), an endemic herb to QTP and adjacent highlands. We sequenced chloroplast and nuclear ribosomal DNA fragments for 429 individuals, collected from 29 localities, covering their major distribution range at the QTP. A total of 19 chloroplast haplotypes and 13 nuclear genotypes in two well-differentiated lineages, corresponding to populations into two groups isolated by Tanggula and Bayangela Mountains. Meanwhile, significant phylogeographical structure was detected among sampling range of L. tibetica, and 61.50% of genetic variations was partitioned between groups. Gene flow across the whole region appears to be restricted by high mountains, suggesting a significant role of geography in the genetic differences between the two groups. Divergence time between the two lineages dated to 8.63 million years ago, which corresponded to the uplifting of QTP during the late Miocene and Pliocene. Ecological differences were found between both the lineages represent species-specific characteristics, sufficient to keep the lineages separated to a high degree. The simulated distribution from the last interglacial period to the current period showed that the distribution of L. tibetica experienced shrinkage and expansion. Climate changes during the Pleistocene glacial-interglacial cycles had a dramatic effect on L. tibetica distribution ranges. Multiple refugia of L. tibetica might have remained during the species history, to south of the Tanggula and north of Bayangela Mountains, both appeared as topological barrier and contributed to restricting gene flow between the two lineages. Together, geographic isolation and climatic factors have played a fundamental role in promoting diversification and evolution of L. tibetica