Effect of surface conditions on internal oxidation and nitridation of HVOF MCrAlY coatings

This study deals with the isothermal oxidation behaviour of high velocity oxy-fuel sprayed MCrAlY coatings. Both free-standing coatings and coatings attached to IN738 and CMSX4 substrates undergo isothermal oxidation at 1100°C for up to 100h. The effect of surface conditions (as-sprayed and polished) has been investigated. Scanning electron microscopy and energy dispersive X-ray analysis were used to characterise the details of oxidation behaviour. The results have shown that both surface conditions and substrate type have a pronounced effect on oxidation behaviour. Extensive internal oxidation and nitridation is observed for polished coatings on Inconel 738 and is attributed to the combined effects of titanium diffusion from the substrate and enhanced surface diffusion due to polishing

CKM and Tri-bimaximal MNS Matrices in a SU(5) x (d)T Model

We propose a model based on SU(5) x {}^{(d)}T which successfully gives rise to near tri-bimaximal leptonic mixing as well as realistic CKM matrix elements for the quarks. The Georgi-Jarlskog relations for three generations are also obtained. Due to the {}^{(d)}T transformation property of the matter fields, the b-quark mass can be generated only when the {}^{(d)}T symmetry is broken, giving a dynamical origin for the hierarchy between m_{b} and m_{t}. There are only nine operators allowed in the Yukawa sector up to at least mass dimension seven due to an additional Z_{12} x Z'_{12} symmetry, which also forbids, up to some high orders, operators that lead to proton decay. The resulting model has a total of nine parameters in the charged fermion and neutrino sectors, and hence is very predictive. In addition to the prediction for \theta_{13} \simeq \theta_{c}/3 \sqrt{2}, the model gives rise to a sum rule, \tan^{2}\theta_{\odot} \simeq \tan^{2} \theta_{\odot, \mathrm{TBM}} - {1/2} \theta_{c} \cos\beta, which is a consequence of the Georgi-Jarlskog relations in the quark sector. This deviation could account for the difference between the experimental best fit value for the solar mixing angle and the value predicted by the tri-bimaximal mixing matrix.Comment: 11 pages; v2: additional references added; minor modifications made; conclusion unchanged; v3: version to appear in Phys. Lett.

Meso-scale transboundary units for the management of coral reefs in the South China Sea area

Local communities and local government units are recognized as the primary stakeholders and participants in the management of coral reef resources and the primary beneficiaries of small-scale fishing activities in the nearshore areas of the coastal zone. The issues relating to the management of the coastal zone are multi-faceted and some issues are largely intertwined with national policy and development goals. Thus, national governments have jurisdiction over these nearshore coastal resources to harmonize policies, monitor resource use and provide incentives for sustainable use. However, the natural boundaries of these reef resources, the processes that support reef ecosystems, and the local or national affiliation of the people who benefit from them may transcend the boundaries of the local and national management units. Therefore, efforts to arrest the decline in fish catch and loss of biodiversity for reefs require management interventions and assessment activities to be carried out at varying scales. In Southeast Asia, some aspects of reef and reef resources management — particularly in deciding the allocation of catch among competing fisheries, development of sustainable harvest strategies, use of broodstock for restocking or stock enhancement programs, protection of nursery and spawning areas, designation of systems of marine protected areas, and the identification of representative, adequate and comprehensive areas for biodiversity conservation in the region — may require the definition of larger management units. At the regional level, multi-country initiatives will need to define units for the transboundary management of resources. The use of large marine ecosystems (LMEs) to identify and manage fisheries resources may be a starting point; however, given the relatively sedentary nature of coral reef-dwelling and reef-associated organisms compared with other pelagic and demersal species, meso-scale transboundary units within the LMEs have to be defined. This paper provides suggestions for transboundary management units for coral reef and reef-associated resources in Southeast Asia based on information from genetic structures of model organisms in the region. In addition, specific reef areas are identified, which may be important beyond their national boundaries, as potential sources of recruits.Coral reefs, Resource management, Large marine ecosystems, Population genetics, Reef fisheries, Fishery management, South China Sea,

The massless higher-loop two-point function

We introduce a new method for computing massless Feynman integrals analytically in parametric form. An analysis of the method yields a criterion for a primitive Feynman graph $G$ to evaluate to multiple zeta values. The criterion depends only on the topology of $G$, and can be checked algorithmically. As a corollary, we reprove the result, due to Bierenbaum and Weinzierl, that the massless 2-loop 2-point function is expressible in terms of multiple zeta values, and generalize this to the 3, 4, and 5-loop cases. We find that the coefficients in the Taylor expansion of planar graphs in this range evaluate to multiple zeta values, but the non-planar graphs with crossing number 1 may evaluate to multiple sums with $6^\mathrm{th}$ roots of unity. Our method fails for the five loop graphs with crossing number 2 obtained by breaking open the bipartite graph $K_{3,4}$ at one edge

Modeling Regional Carbon Dioxide Flux over California using the WRF‑ACASA Coupled Model

Many processes and interactions in the atmosphere and the biosphere influence the rate of carbon dioxide exchange between these two systems. However, it is difficult to estimate the carbon dioxide flux over regions with diverse ecosystems and complex terrains, such as California. Traditional carbon dioxide measurements are sparse and limited to specific ecosystems. Therefore, accurately estimating carbon dioxide flux on a regional scale remains a major challenge. In this study, we couple the Weather Research and Forecasting Model (WRF) with the Advanced Canopy-Atmosphere-Soil Algorithm (ACASA), a high complexity land surface model. Although WRF is a state-of-the-art regional atmospheric model with high spatial and temporal resolutions, the land surface schemes available in WRF lack the capability to simulate carbon dioxide. ACASA is a complex multilayer land surface model with interactive canopy physiology and full surface hydrological processes. It allows microenvironmental variables such as air and surface temperatures, wind speed, humidity, and carbon dioxide concentration to vary vertically. Carbon dioxide, sensible heat, water vapor, and momentum fluxes between the atmosphere and land surface are estimated in the ACASA model through turbulence equations with a third order closure scheme. It therefore permits counter-gradient transports that low-order turbulence closure models are unable to simulate. A new CO2 tracer module is introduced into the model framework to allow the atmospheric carbon dioxide concentration to vary according to terrestrial responses. In addition to the carbon dioxide simulation, the coupled WRF-ACASA model is also used to investigate the interactions of neighboring ecosystems in their response to atmospheric carbon dioxide concentration. The model simulations with and without the CO2 tracer for WRF-ACASA are compared with surface observations from the AmeriFlux network.This work is supported in part by the National Science Foundation under Awards No.ATM-0619139 and EF-1137306. The Joint Program on the Science and Policy of Global Change is funded by a number of federal agencies and a consortium of 40 industrial and foundation sponsors. (For the complete list see http://globalchange.mit.edu/sponsors/current.html)

Interference - minimized multipath routing with congestion control in wireless sensor network for multimedia streaming

Master'sMASTER OF ENGINEERIN

Impact of Canopy Representations on Regional Modeling of Evapotranspiration using the WRF-ACASA Coupled Model

In this study, we couple the Weather Research and Forecasting Model (WRF) with the Advanced Canopy-Atmosphere-Soil Algorithm (ACASA), a high complexity land surface model, to investigate the impact of canopy representation on regional evapotranspiration. The WRF-ACASA model uses a multilayer structure to represent the canopy, consequently allowing microenvironmental variables such as leaf area index (LAI), air and canopy temperature, wind speed and humidity to vary both horizontally and vertically. The improvement in canopy representation and canopy-atmosphere interaction allow for more realistic simulation of evapotranspiration on both regional and local scales. Accurate estimates of evapotranspiration (both potential and actual) are especially important for regions with limited water availability and high water demand, such as California. Water availability has been and will continue to be the most important issue facing California for years and perhaps decades to come. Terrestrial evapotranspiration is influenced by many processes and interactions in the atmosphere and the bio-sphere such as water, carbon, and momentum exchanges. The need to improve representation within of surface-atmosphere interactions remains an urgent priority within the modeling community.This work is supported in part by the National Science Foundation under Awards No.ATM-0619139 and EF-1137306. The Joint Program on the Science and Policy of Global Change is funded by a number of federal agencies and a consortium of 40 industrial and foundation sponsors. (For the complete list see http://globalchange.mit.edu/sponsors/current.html)

Group Theoretical Origin of CP Violation

We propose the complex group theoretical Clebsch-Gordon coefficients as a novel origin of CP violation. This is manifest in our model based on SU(5) combined with the T' group as the family symmetry. The complex CG coefficients in T' lead to explicit CP violation which is thus geometrical in origin. The predicted CP violation measures in the quark sector are consistent with the current experimental data. The corrections due to leptonic Dirac CP violating phase gives the experimental best fit value for the solar mixing angle, and we also gets the right amount of the baryonic asymmetry.Comment: v1: 4 pages; v2: RGE corrections included giving better agreement with experiments, abstract shortened; v3: Title of the paper has been changed, references added, version to appear in Phys. Lett.

Ago-2-Mediated Slicer Activity Is Essential for Anti-Flaviviral Efficacy of RNAi

RNA interference can be mediated by fully complementary siRNA or partially complementary miRNA. siRNAs are widely used to suppress viral replication and the fully complementary siRNA bound Ago-2 in the RISC is known to degrade the target RNA. Although other argonaute proteins lacking slicer activity can also bind oligonucleotides with both si and miRNA structures, whether they can also contribute to antiviral effects is not entirely clear. We tested si and miRNA structured oligos for target repression in dual luciferase assays as well as for inhibition of Dengue and West Nile virus replication in ES cells expressing individual Ago proteins. In luciferase assays, both fully complementary and partially complementary oligos effectively repressed their targets in all individual Ago expressing cell lines, although the efficacy with fully complementary oligos was higher in Ago-2+ cells. However, partially complementary oligos had no effect on virus replication in any cell line, while fully complementary siRNAs were highly effective in Ago-2 expressing, but not in cells expressing other Ago proteins. This occurred irrespective of whether the target sequences were located in the coding region or 3′UTR of the virus. We conclude that Ago-2 slicer activity is essential for anti-viral efficacy of siRNAs and miRNA-mediated translational repression/transcript destabilization is too weak to suppress the abundantly expressed flaviviral proteins