1,032 research outputs found

    Continuum chemical reactions in the oil industry

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    Vacuum moulding of a superplastic

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    The objective of this research is to develop a model for simulating the super-plastic forming process and for predicting the thickness distribution as well the minimum radius of curvature when the material has to fill a sharp corner. Other questions of interest are the deflection of the sheet as a function of pressure for a given mould opening, and the deflection as a function of mould diameter for a given pressure. Modeling based on shell theory is carried out for cylindrical, spherical and arbitrary-shape shells of uniform as well as non-uniform thick- nesses

    Full characterisation of a focussed extreme ultraviolet beam using a non-redundant array of apertures

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    This paper presents a novel technique for characterising wavefront curvature and M2, by utilising a non-redundant array (NRA) of apertures to define the plane of investigation through an experimental extreme ultraviolet (EUV) focus. Appropriately sampled, far-field EUV scattering from this NRA is captured on a CCD as the NRA is scanned along the beam axis through the focus. By taking the inverse Fourier transform (IFT), it is possible obtain the spatial autocorrelation functions, via the Wiener-Khinchin theorem, of the exit wave field. By observing the position of the first-order peaks in the autocorrelation as a function of grid translation, both the real and imaginary parts of the complex beam parameter can be determined and the M2 calculated, yielding full characterisation of the embedded Gaussian. Since the periodicity of the grid is known, the planar pixel resolution can be calculated, also allowing the translations movement to be confirmed due to the change in angular acceptance of the fixed CCD. This makes the technique self-calibrating. A high impact, easy to use, cross field technique for full profiling of the embedded Gaussian of probe beams using a non-redundant array of apertures is presented. The technique is experimentally verified in the highly absorbing EUV spectral regime, and is expected to play a significant role in other regimes, where experimental issues prevent the use of existing techniques

    Cyanobacterial Abundance and Microcystin Profiles in Two Southern British Lakes: The Importance of Abiotic and Biotic Interactions.

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    Freshwater cyanobacteria blooms represent a risk to ecological and human health through induction of anoxia and release of potent toxins; both conditions require water management to mitigate risks. Many cyanobacteria taxa may produce microcystins, a group of toxic cyclic heptapeptides. Understanding the relationships between the abiotic drivers of microcystins and their occurrence would assist in the implementation of targeted, cost-effective solutions to maintain safe drinking and recreational waters. Cyanobacteria and microcystins were measured by flow cytometry and liquid chromatography coupled to tandem mass spectrometry in two interconnected reservoirs varying in age and management regimes, in southern Britain over a 12-month period. Microcystins were detected in both reservoirs, with significantly higher concentrations in the southern lake (maximum concentration >7 µg L-1). Elevated microcystin concentrations were not positively correlated with numbers of cyanobacterial cells, but multiple linear regression analysis suggested temperature and dissolved oxygen explained a significant amount of the variability in microcystin across both reservoirs. The presence of a managed fishery in one lake was associated with decreased microcystin levels, suggestive of top down control on cyanobacterial populations. This study supports the need to develop inclusive, multifactor holistic water management strategies to control cyanobacterial risks in freshwater bodies

    Void elimination in screen printed thick film dielectric pastes

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    The problem is to understand the mechanisms for the formation and evolution of defects in wet screen printed layers. The primary objective is to know how best to alter the properties of the paste (rather than the geometry of the screen printing process itself) in order to eliminate the defects. With these goals in mind the work done during the Study Group reported here was as follows; to describe a simple model for the closure of craters, a model for the partial closure of vias, a possible mechanism for the formation of pinholes and finally a more detailed consideration of the screen printing process

    Self-organised criticality in base-pair breathing in DNA with a defect

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    We analyse base-pair breathing in a DNA sequence of 12 base-pairs with a defective base at its centre. We use both all-atom molecular dynamics (MD) simulations and a system of stochastic differential equations (SDE). In both cases, Fourier analysis of the trajectories reveals self-organised critical behaviour in the breathing of base-pairs. The Fourier Transforms (FT) of the interbase distances show power-law behaviour with gradients close to -1. The scale-invariant behaviour we have found provides evidence for the view that base-pair breathing corresponds to the nucleation stage of large-scale DNA opening (or 'melting') and that this process is a (second-order) phase transition. Although the random forces in our SDE system were introduced as white noise, FTs of the displacements exhibit pink noise, as do the displacements in the AMBER/MD simulations.Comment: 18 pages, 8 figure

    Effects of H2O2 on growth, metabolic activity and membrane integrity in three strains of Microcystis aeruginosa.

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    The application of hydrogen peroxide (H2O2) as a management tool to control Microcystis blooms has become increasingly popular due to its short lifetime and targeted action. H2O2 increases intracellular reactive oxygen species resulting in oxidative stress and subsequently cell death. H2O2 is naturally produced in freshwater bodies as a result of photocatalytic reactions between dissolved organic carbon and sunlight. Previously, some studies have suggested that this environmental source of H2O2 selectively targets for toxigenic cyanobacteria strains in the genus Microcystis. Also, past studies only focused on the morphological and biochemical changes of H2O2-induced cell death in Microcystis with little information available on the effects of different H2O2 concentrations on growth, esterase activity and membrane integrity. Therefore, this study investigated the effects of non-lethal (40-4000 nM) concentrations on percentage cell death; with a focus on sub-lethal (50 μM) and lethal (275 μM; 500 μM) doses of H2O2 on growth, cells showing esterase activity and membrane integrity. The non-lethal dose experiment was part of a preliminary study. Results showed a dose- and time-dependent relationship in all three Microcystis strains post H2O2 treatment. H2O2 resulted in a significant increase in intracellular reactive oxygen species, decreased chlorophyll a content, decreased growth rate and esterase activity. Interestingly, at sub-lethal (50 μM H2O2 treatment), percentage of dead cells in microcystin-producing strains was significantly higher (p < 0.05) than that in non-microcystin-producing strains at 72 h. These findings further cement our understanding of the influence of H2O2 on different strains of Microcystis and its impact on membrane integrity and metabolic physiology: important to future toxic bloom control programmes
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