Wet gum labelling of wine bottles

It is shown that bubbling on wine bottle labels is due to absorption of water from the glue, with subsequent hygroscopic expansion. Contrary to popular belief, most of the glue's water must be lost to the atmosphere rather than to the paper. A simple lubrication model is developed for spreading glue piles in the pressure chamber of the labelling machine. This model predicts a maximum rate for application of labels. Buckling theory shows that the current arrangement of periodic glue strips can indeed accommodate paper expansion. Some recommendations follow on the paper, the glue, the labelling rate and the drying environment

Gravastars and Black Holes of Anisotropic Dark Energy

Dynamical models of prototype gravastars made of anisotropic dark energy are constructed, in which an infinitely thin spherical shell of a perfect fluid with the equation of state $p = (1-\gamma)\sigma$ divides the whole spacetime into two regions, the internal region filled with a dark energy fluid, and the external Schwarzschild region. The models represent "bounded excursion" stable gravastars, where the thin shell is oscillating between two finite radii, while in other cases they collapse until the formation of black holes. Here we show, for the first time in the literature, a model of gravastar and formation of black hole with both interior and thin shell constituted exclusively of dark energy. Besides, the sign of the parameter of anisotropy ($p_t - p_r$) seems to be relevant to the gravastar formation. The formation is favored when the tangential pressure is greater than the radial pressure, at least in the neighborhood of the isotropic case ($\omega=-1$).Comment: 16 pages, 8 figures. Accepted for publication in Gen. Rel. Gra

Graphical method for analyzing digital computer efficiency

Analysis method utilizes graph-theoretic approach for evaluating computation cost and makes logical distinction between linear graph of a computation and linear graph of a program. It applies equally well to other processes which depend on quatitative edge nomenclature and precedence relationships between edges

On Polyakov's basic variational formula for loop spaces

We use the homological algebra context to give a more rigorous proof of Polyakov's basic variational formula for loop spaces.Comment: Latex, 17 pages, no figure

Fluctuations and universality in a catalysis model with long-range reactivity

The critical properties of the Ziff-Gulari-Barshad (ZGB) model with the addition of long-range reactivity [C.H. Chan and P.A. Rikvold, Phys. Rev. E 91, 012103 (2015)] are further investigated. The scaling behaviors of the order parameter, susceptibility, and correlation length provide addi- tional evidence that the universality class of the ZGB system changes from the two-dimensional Ising class to the mean-field class with the addition of even a weak long-range reactivity mechanism

Mechanisms for the Oxonolysis of Ethene and Propene: Reliability of Quantum Chemical Predictions

Reactions of ozone with ethene and propene leading to primary ozonide (concerted and stepwise ozonolysis) or epoxide and singlet molecular oxygen (partial ozonolysis) are studied theoretically. The mechanism of concerted ozonolysis proceeds via a single transition structure which is a partial diradical. The transition structures and intermediates in the stepwise ozonolysis and partial ozonolysis mechanisms are singlet diradicals. Spin-restricted and unrestricted density functional methods are employed to calculate the structures of the closed-shell and diradical species. Although the partial diradicals exhibit moderate to pronounced instability in their RDFT and RHF solutions, RDFT is required to locate the transition structure for concerted ozonolysis. Spin projected fourth-order Møller–Plesset theory (PMP4) was used to correct the DFT energies. The calculated pre-exponential factors and activation energies for the concerted ozonolysis of ethene and propene are in good agreement with experimental values. However, the PMP4//DFT procedure incorrectly predicts the stepwise mechanism as the favored channel. UCCSD(T) predicts the concerted mechanism as the favored channel but significantly overestimates the activation energies. RCCSD(T) is found to be more accurate than UCCSD(T) for the calculation of the concerted mechanism but is not applicable to the diradical intermediates. The major difficulty in accurate prediction of the rate constant data for these reactions is the wide range of spin contamination for the reference UHF wave functions and UDFT solutions across the potential energy surface. The possibility of the partial ozonolysis mechanism being the source of epoxide observed in some experiments is discussed

A topological approach to computer-aided sensitivity analysis

Sensitivities of any arbitrary system are calculated using general purpose digital computer with available software packages for transfer function analysis. Sensitivity shows how element variation within system affects system performance. Signal flow graph illustrates topological system behavior and relationship among parameters in system