472 research outputs found
NUMERICAL AND EXPERIMENTAL STEADY STATE FLOW AND HEAT TRANSFER IN A CONTINUOUS SPOUTED BED
Experimental measurements on heat transfer and flow properties and CFD simulations based on the two-fluid model (Eulerian-Eulerian approach) were performed in a draft tube continuous spouted bed system. The simulated results on the gas-particle flow patterns and the temperature distribution in the bed agreed well with our experimental data
NUMERICAL AND EXPERIMENTAL STEADY STATE FLOW AND HEAT TRANSFER IN A CONTINUOUS SPOUTED BED
Experimental measurements on heat transfer and flow properties and CFD simulations based on the two-fluid model (Eulerian-Eulerian approach) were performed in a draft tube continuous spouted bed system. The simulated results on the gas-particle flow patterns and the temperature distribution in the bed agreed well with our experimental data
The spin state transition in LaCoO; revising a revision
Using soft x-ray absorption spectroscopy and magnetic circular dichroism at
the Co- edge we reveal that the spin state transition in LaCoO
can be well described by a low-spin ground state and a triply-degenerate
high-spin first excited state. From the temperature dependence of the spectral
lineshapes we find that LaCoO at finite temperatures is an inhomogeneous
mixed-spin-state system. Crucial is that the magnetic circular dichroism signal
in the paramagnetic state carries a large orbital momentum. This directly shows
that the currently accepted low-/intermediate-spin picture is at variance.
Parameters derived from these spectroscopies fully explain existing magnetic
susceptibility, electron spin resonance and inelastic neutron data
Exchange bias in GeMn nanocolumns: the role of surface oxidation
We report on the exchange biasing of self-assembled ferromagnetic GeMn
nanocolumns by GeMn-oxide caps. The x-ray absorption spectroscopy analysis of
this surface oxide shows a multiplet fine structure that is typical of the Mn2+
valence state in MnO. A magnetization hysteresis shift |HE|~100 Oe and a
coercivity enhancement of about 70 Oe have been obtained upon cooling (300-5 K)
in a magnetic field as low as 0.25 T. This exchange bias is attributed to the
interface coupling between the ferromagnetic nanocolumns and the
antiferromagnetic MnO-like caps. The effect enhancement is achieved by
depositing a MnO layer on the GeMn nanocolumns.Comment: 7 pages, 5 figure
Transradial approach to lower extremity interventions
Percutaneous interventions of the coronary and peripheral vessels have historically been performed using a femoral artery approach. There has been increasing recognition of post-procedural bleeding complications and its impact on short- and long-term mortality. Because of its now recognized safety, the transradial approach has recently emerged as a preferred method compared to the transfemoral approach. The limitations associated with the distance from the puncture site to the lesion location are being addressed as new tools are developed for the endovascular treatment of peripheral arterial disease. In this review, we discuss the many facets of the transradial approach to lower extremity endovascular interventions, highlighting its safety and efficacy. Approaches to special populations including individuals with prior surgical bypass, Leriche’s syndrome, and those committed to chronic anticoagulation are also reviewed
Ising magnetism and ferroelectricity in CaCoMnO
The origin of both the Ising chain magnetism and ferroelectricity in
CaCoMnO is studied by electronic structure calculations
and x-ray absorption spectroscopy. We find that CaCoMnO has the
alternate trigonal prismatic Co and octahedral Mn sites in the
spin chain. Both the Co and Mn are in the high spin state. In
addition, the Co has a huge orbital moment of 1.7 which is
responsible for the significant Ising magnetism. The centrosymmetric crystal
structure known so far is calculated to be unstable with respect to exchange
striction in the experimentally observed
antiferromagnetic structure for the Ising chain. The calculated inequivalence
of the Co-Mn distances accounts for the ferroelectricity.Comment: 4 pages, 3 figures, PRL in press (changes made upon referees
comments
Orbital order in La0.5Sr1.5MnO4: beyond a common local Jahn-Teller picture
The standard way to find the orbital occupation of Jahn-Teller (JT) ions is
to use structural data, with the assumption of a one-to-one correspondence
between the orbital occupation and the associated JT distortion, e.g. in O6
octahedron. We show, however, that this approach in principle does not work for
layered systems. Specifically, using the layered manganite La0.5Sr1.5MnO4 as an
example, we found from our x-ray absorption measurements and theoretical
calculations, that the type of orbital ordering strongly contradicts the
standard local distortion approach for the Mn3+O6 octahedra, and that the
generally ignored long-range crystal field effect and anisotropic hopping
integrals are actually crucial to determine the orbital occupation. Our
findings may open a pathway to control of the orbital state in multilayer
systems and thus of their physical properties.Comment: 4+ pages, 4 figure
Orbital occupation and magnetic moments of tetrahedrally coordinated iron in CaBaFe4O7
CaBaFe4O7 is a mixed-valent transition metal oxide having both Fe2+ and Fe3+
ions in tetrahedral coordination. Here we characterize its magnetic properties
by magnetization measurements and investigate its local electronic structure
using soft x-ray absorption spectroscopy at the Fe L2,3 edges, in combination
with multiplet cluster and spin-resolved band structure calculations. We found
that the Fe2+ ion in the unusual tetrahedral coordination is Jahn-Teller active
with the high-spin e^2 (up) t2^3 (up) e^1 (down) configuration having a
x^2-y^2-like electron for the minority spin. We deduce that there is an
appreciable orbital moment of about L_z=0.36 caused by multiplet interactions,
thereby explaining the observed magnetic anisotropy. CaBaFe4O7, a member of the
'114' oxide family, offers new opportunities to explore charge, orbital and
spin physics in transition metal oxides
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